Archive for the ‘News’ Category

EES biofuel article featured in The Times

An exciting Energy Environmental Science Anaylsis article about algae-derived biodiesel which ‘could be the answer to the fossil fuel crisis’ has been featured in The Times newspaper today.

Using a life-cycle analysis, King and colleagues evaluate whether algal biodiesel production can be a viable fuel source in the near future.

biofuel analysisRead the Energy Environmental Science article:

Life cycle energy and greenhouse gas analysis for algae-derived biodiesel
Tara Shirvani, Xiaoyu Yan, Oliver R. Inderwildi, Peter P. Edwards and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01791H

Or read more about it on the Chemistry World Blog

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Algae-derived biodiesel flying high

Chemistry World Blog
Algae-derived biodiesel flying high
Posted by Elinor on Thu 11 Aug 2011

Two weeks ago, we read about agave as an alternative feedstock to corn or sugarcane in the production of bioethanol fuel in Mike’s story Tequila for your fuel tank. In it, Mike describes research by David King from the Low Carbon Mobility Centre at the University of Oxford and his team.

At the same time, King’s team has been busy putting research together to show that algae-derived biodiesel ‘could be the answer to the fossil fuel crisis’. Indeed, airlines have already been testing a range of biofuels in their planes, including algal-derived biofuels.

…Read the rest on the Chemistry World Blog

Journal Article:
Life cycle energy and greenhouse gas analysis for algae-derived biodiesel
Tara Shirvani, Xiaoyu Yan, Oliver R. Inderwildi, Peter P. Edwards and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01791H

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Renewable energy could replace fossil fuels to heat US homes

US energy consumption study reveals that using renewable energy instead of fossil fuels to heat homes is viable.

An analysis on how the US uses thermal energy has revealed a perfect opportunity for renewable energy from geothermal and solar resources, say US scientists.

The study shows how renewable energy could provide a large fraction of the energy used for heating water and space at home that is currently supplied by high grade fossil fuels.

Read the Energy & Environmental Science article:

The thermal spectrum of low-temperature energy use in the United States
D B Fox, D Sutter and J W Tester
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee01722e

thermal spectrum

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A solar torch to fit in your back pocket

In a real life display of the use of photovoltaics, a solar powered torch the size of a credit card has been developed by a team of scientists from Denmark, the Netherlands and the US. 

Organic and polymer solar cells (OPV) have reached a technological level where they can be produced commercially using roll-to-roll methods that are cost effective. Frederik Krebs, from the Technical University of Denmark, Roskilde, and colleagues have made a new device that combines 16 solar cells connected in series that are used to charge a battery that powers a white light emitting diode.    

Solar powered torch  Production required 35 steps, and combined the polymer solar cell with printed circuitry and flexible lithium polymer batteries. Tests were run on the lamp to determine its efficiency and study the effects of humidity and design on performance. 

This new pocket-sized flashlight was able to get a yield of 89 per cent and operated for hours at a time. Krebs explains: ‘Even if the flashlight is far from solving the world’s energy problem, it clearly demonstrates that polymer solar cells are capable of fairing outside the laboratory and can be made available to the public in an operational device.’ 

Until now, very few examples have been manufactured beyond a few units. This is the first time that a complex device has been commercialised at this scale – 10,000 units have already been made. Examples were even handed out at the most recent Large area Organic and Printed Electronics Conference (LOPE-C).

‘While the OPV powered lamp demonstrated in this work shows how this technology can be used in regions of the world where direct access to electricity by conventional sources is difficult, the methods developed will have a broader impact in the field of printable organic electronics in general,’ comments John Reynolds, an expert in conducting polymers from the University of Florida, US.

Krebs and his team are now tackling the next challenge, which is to make polymer solar cells with longer operational lifespans capable of working for years at a time in outdoor conditions.

Rebecca Brodie 

Read the journal article:

The OE-A OPV demonstrator anno domini 2011
Frederik C. Krebs, Jan Fyenbo, David M. Tanenbaum, Suren A. Gevorgyan, Ronn Andriessen, Bart van Remoortere, Yulia Galagan and Mikkel Jørgensen
Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01891d

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Overcoming a challenge in lithium–air battery function – inspired by artificial blood

Lithium–air batteries’ discharge rates can be increased substantially by using perfluorinated compounds as oxygen carriers, say scientists from the US. They were inspired to make oxygen carriers similar to artificial blood substitutes.

One of the challenges of making Li–air batteries viable is down to increasing oxygen solubility and diffusion coefficient, which should increase the discharge rate.

The perfluorinated compounds increase the oxygen’s solubility in non-aqueous electrolytes, which leads to an increase in the diffusion-limited current of oxygen reduction on the gas diffusion electrode in the battery.

A 5 mA.cm-2 discharge rate was achieved, an improvement over previous devices, which were limited to 0.01–5 mA.cm-2.

Reference:
High Rate Oxygen Reduction in Non-aqueous Electrolyte with the Addition of Perfluorinated Additives
Y Wang, D Zheng, X-Q Yang and D Qu,
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee01556g

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HOT article: extracting pure CO2 from air

Using a combined temperature-vacuum swing (TVS) process which separates CO2 from atmospheric air, scientists from Switzerland have shown a stable performance over 40 consecutive adsorption/desorption cycles.

The adsorption/desorption cycles use a sorbent material made of diamine-functionalized commercial silica gel, and are performed under equilibrium and non-equilibrium (short-cycle) conditions. Therefore the CO2 capture capacity of the material can be determined over a wide range of pressures and temperatures.

Read this ‘HOT’ Energy & Environmental Science article today:

Separation of CO2 from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel
Jan Andre Wurzbacher, Christoph Gebald and Aldo Steinfeld
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01681D

CO2 separation

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Tequila for your fuel tank

Researchers in the UK show that Agave – a plant used to make tequila and fibres for rope – is a handy alternative feedstock to corn or sugarcane in the production of bioethanol fuel.  

Bioethanol is a good clean fuel candidate as it only forms carbon dioxide and water during combustion and can be easily blended with crude oil to produce other fuels. However, the sustainability of large-scale biofuel production has recently been called into question because of mounting concerns over the impact on land and water resources. 

Now a team led by David King from the Low Carbon Mobility Centre at the University of Oxford has studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment. 

In the US, bioethanol is produced from corn, which is very water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production. In Brazil, bioethanol is produced using sugarcane. But again, land that could be used to grow food is needed to grow this and the question is: which is more important, food or fuel? 

Agave plants
‘Agave is a sort of cactus that grows in water restricted arid areas,’ says Oliver Inderwildi, one of the researchers. ‘This is essentially what we want – to produce fuel away from arable land.’ Inderwildi explains that the Agave feedstock, after harvesting, will be milled, cooked, fermented and then distilled – essentially using the same process as other ethanol production procedures. 

‘This is academic research in the very early stages,’ says Inderwildi. ‘However, there is no real shortage of desert land and lots of deprived areas are located on the edge of deserts, so this could be a method to utilise unused land and help rejuvenate deprived areas,’ he adds. 

‘There is no question this is a valuable first attempt at predicting the benefits of Agave-based biofuels,’ says Stephen Long, an expert in bioenergy from the University of Illinois at Urbana-Champaign, in the US. ‘But without systematic trials and measurements, the scale of the opportunity is unclear,’ he adds.

Inderwildi admits that there are still a few problems to iron out before Agave will be a commercially viable feedstock. ‘They are slow growing crops and up until now they have been harvested manually,’ he tells Chemistry World. ‘What you have at the moment is a labour issue and a yield issue, but we can work on increasing yields and automating the harvesting.’

The team at the Low Carbon Mobility Centre are also looking at other ways to produce biofuels from algae. ‘Fuels from algae can be used as diesel type fuels or kerosene,’ says Inderwildi. ‘Air New Zealand has already carried out a test flight using these fuels and performance is outstanding,’ he adds.

Even if Agave is used to produce our fuels in the future, tequila production or prices will be unaffected, according to Inderwildi.   ‘I’m not at all worried about the tequila supply in bars,’ he says.

Mike Brown

Read the Energy & Environmental Science article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01107c

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Tequila biofuel: EES paper featured in The Guardian

An Energy & Environmental Science article which analyses the use of agave (tequila) plants as a source of bio-ethanol has been featured in The Guardian today: Tequila gives new biofuel crops a shot

The work by scientists at the University of Oxford and The University of Sydney have shown that Agave – a plant used to make tequila – is an alternative feedstock to corn or sugarcane in the production of bioethanol fuel. They have studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment, away from arable land.

Bioethanol produced from corn and sugarcane is water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production.

Read the Energy & Environmental Science Analysis article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01107C

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The rise of the sodium ion battery: EES in C&EN

An Energy & Environmental Science Communication by Philipp Adelhelm and co-workers has been featured in an C&EN article Making Better Sodium-Ion Batteries.

The rise of the sodium ion battery: A nanostructured material has been used as an anode in a sodium ion battery for the first time and its performance is better than all carbon materials tested so far, say researchers from Germany.

Read the paper:

Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies
S Wenzel, T Hara, J Janek and P Adelhelm, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01744f

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Poster Prizes at ICCDU XI

ICCDU winnerRSC Publishing was delighted to award three PhD Poster Prizes at the recent International Conference on Carbon Dioxide Utilization (ICCDU XI) held in June 2011, Dijon, France.

The winners were presented with RSC Prize certificates and either a free subscription to the journal or a financial award.

RSC Publishing journals will be awarding further Poster Prizes over the summer so watch this space!

The prize winners at ICCDU were:

Energy & Environmental Science Award:
Isabel VILLAFÁN-VIDALES
Title: THERMOCHEMICAL CO2 SPLITTING BASED ON FE3O4/FEO REDOX REACTIONS USING CONCENTRATED SOLAR ENERGY
Stéphane ABANADES and H. Isabel VILLAFÁN-VIDALES (CNRS-PROMES, France)

Green Chemistry Award:
Stephanie WILSON
Title: COUPLING REACTIONS OF CO2 AND UNEXPLORED EPOXIDES : POLYCARBONATE VS. CYCLIC CARBONATE FORMATION
Stephanie WILSON and Donald J. DARENSBOURG (Department of Chemistry, Texas A&M University, USA)

Journal of Materials Chemistry Award:
Mohd Bismillah ANSARI
Ttle: TRIAZINE BASED POROUS FRAMEWORKS FOR METAL FREE CO2 ACTIVATION
Mohd Bismillah ANSARI and Sang-Eon PARK (Department of Chemistry, Inha University, Republic of Korea)

Energy & Environmental Science and Green Chemistry will also be publishing a special web-theme collection of articles from the ICCDU conference.

Sign-up to the free e-alerts and newsletter to hear about the latest research published on CO2 utilization.

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