Author Archive

PCET2011 Conference sponsored by EES

Energy & Environmental Science was delighted to sponsor the 1st International Conference on Proton Coupled Electron Transfer (PCET2011) held in the Loire Valley, France from 9-13th October.

Energy & Environmental Science (EES) also plans to publish a collection of high-profile feature articles in a special issue to highlight some of the great research from this important first meeting bringing together the various disciplines involved with PCET.

Read some of the speakers recent articles published in EES:

“Fast food” energy
Daniel G. Nocera
DOI: 10.1039/C003891C

Water electrolysis and photoelectrolysis on electrodes engineered using biological and bio-inspired molecular systems
Phong D. Tran, Vincent Artero and Marc Fontecave
DOI: 10.1039/B926749B

EES themed issue, 2011, Issue 7
Biomimetic approaches to artificial photosynthesis
Guest Editors: Leif Hammarström and Michael Wasielewski

PCET

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Energy powered by a grape

A miniature biofuel cell can generate electricity using the sugars in grapes, according to researchers in Japan.

The device has a needle bioanode that can be inserted into the grape, and a gas diffusion biocathode that uses oxygen in the air to oxidise the sugars. The maximum power produced was 26.5µW at 0.34V, which was used to power a light emitting diode (LED), which indicated the level of sugar in the grape.

The device could be used in the same way to test blood sugar levels (a test was done by inserting the needle into an animal vein) to monitor health.

Read this exciting EES paper now:

Enzymatic biofuel cells designed for direct power generation from biofluids in living organisms
T Miyake, K Haneda, N Nagai, Y Yatagawa, H Onami, S Yoshino, T Abe and M Nishizawa,
Energy Environ. Sci., 2011
DOI: 10.1039/c1ee02200h

grape power

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Can we test geo-engineering?

Researchers in the US and Canada simulated solar radiation management (SRM), a form of geo-engineering that involves reflecting sunlight to reduce global warming.

Suggested approaches are to increase the amount of light-scattering stratospheric aerosols or increase the reflectivity of low-altitude marine clouds. The idea has attracted renewed interest but there are enormous uncertainties about the risks and effectiveness of SRM.

 The team used a HadCM3L programme for the simulations and came to the conclusion that solar geo-engineering could be tested to reduce uncertainty about climate response, but tests would require decades of modulated climate forcing.

 Read the EES article today hot off the press!

Can we test geoengineering?
D G MacMynowski, D W Keith, K Caldeira and H-J Shin,
Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01256h

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PCET 2011: off to a great start!

PCET 2011, the 1st International Conference on Proton-Coupled Electron Transfer, got off to an exciting and dynamic start yesterday.

This conference is the first of its kind; aiming to bring together all the different research areas that are working on proton and and electron transfer. So far it has sparked lively debate, with lectures going on until 11pm on the first evening!

The first two lectures aimed to give an insight into the diverse research areas which study proton-coupled electon transfer. Joanne Stubbe gave the opening lecture on the biological aspects of PCET and its role in enzyme activity. The next talk was by Jean-Michel Saveant, who discussed PCET and electochemistry.

EES are sponsoring PCET 2011 and we were delighted to host the Verre de l’amite last night where the debate and discussion went on late into the night! It’s going to be an exciting week…!

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Energy & Environmental Science Most-Read Articles for Q2 2011

Top 25 most-read Energy & Environmental Science articles for Q2

Low-platinum and platinum-free catalysts for the oxygen reduction reaction at fuel cell cathodes
Adina Morozan, Bruno Jousselme and Serge Palacin
DOI: 10.1039/C0EE00601G

Review of solutions to global warming, air pollution, and energy security
Mark Z. Jacobson
DOI: 10.1039/B809990C

Graphene based new energy materials
Yiqing Sun, Qiong Wu and Gaoquan Shi
DOI: 10.1039/C0EE00683A

Highly active cobalt phosphate and borate based oxygen evolving catalysts operating in neutral and natural waters
Arthur J. Esswein, Yogesh Surendranath, Steven Y. Reece and Daniel G. Nocera
DOI: 10.1039/C0EE00518E

Organic tandem solar cells: A review
Tayebeh Ameri, Gilles Dennler, Christoph Lungenschmied and Christoph J. Brabec
DOI: 10.1039/B817952B

Prospective materials and applications for Li secondary batteries
Goojin Jeong, Young-Ugk Kim, Hansu Kim, Young-Jun Kim and Hun-Joon Sohn
DOI: 10.1039/C0EE00831A

Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
Liwen Ji, Zhan Lin, Mataz Alcoutlabi and Xiangwu Zhang
DOI: 10.1039/C0EE00699H

Graphene-based nanomaterials for energy storage
Martin Pumera
DOI: 10.1039/C0EE00295J

Nanostructured silicon for high capacity lithium battery anodes
Jeannine R. Szczech and Song Jin
DOI: 10.1039/C0EE00281J

Electrospun nanofibers in energy and environmental applications
V. Thavasi, G. Singh and S. Ramakrishna
DOI: 10.1039/B809074M

Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries
Da Deng, Min Gyu Kim, Jim Yang Lee and Jaephil Cho
DOI: 10.1039/B823474D

Development and challenges of LiFePO4 cathode material for lithium-ion batteries
Li-Xia Yuan, Zhao-Hui Wang, Wu-Xing Zhang, Xian-Luo Hu, Ji-Tao Chen, Yun-Hui Huang and John B. Goodenough
DOI: 10.1039/C0EE00029A

Bulk nanostructured thermoelectric materials: current research and future prospects
A. J. Minnich, M. S. Dresselhaus, Z. F. Ren and G. Chen
DOI: 10.1039/B822664B

Flexible energy storage devices based on graphene paper
Hyeokjo Gwon, Hyun-Suk Kim, Kye Ung Lee, Dong-Hwa Seo, Yun Chang Park, Yun-Sung Lee, Byung Tae Ahn and Kisuk Kang
DOI: 10.1039/C0EE00640H

Nanostructured carbon-based electrodes: bridging the gap between thin-film lithium-ion batteries and electrochemical capacitors
Seung Woo Lee, Betar M. Gallant, Hye Ryung Byon, Paula T. Hammond and Yang Shao-Horn
DOI: 10.1039/C0EE00642D

Photo-assisted water oxidation with cobalt-based catalyst formed from thin-film cobalt metal on silicon photoanodes
Elizabeth R. Young, Ronny Costi, Sarah Paydavosi, Daniel G. Nocera and Vladimir Bulović
DOI: 10.1039/C1EE01209F

Intercalation of mesoporous carbon spheres between reduced graphene oxide sheets for preparing high-rate supercapacitor electrodes
Zhibin Lei, Nikolay Christov and X. S. Zhao
DOI: 10.1039/C1EE01094H

Carbon nanotubes and their composites in electrochemical applications
Grzegorz Lota, Krzysztof Fic and Elzbieta Frackowiak
DOI: 10.1039/C0EE00470G

Organic photovoltaics
Bernard Kippelen and Jean-Luc Brédas
DOI: 10.1039/B812502N

Carbon nanotubes for lithium ion batteries
Brian J. Landi, Matthew J. Ganter, Cory D. Cress, Roberta A. DiLeo and Ryne P. Raffaelle
DOI: 10.1039/B904116H

Tandem polymer photovoltaic cells—current status, challenges and future outlook
Srinivas Sista, Ziruo Hong, Li-Min Chen and Yang Yang
DOI: 10.1039/C0EE00754D

CO2 capture by solid adsorbents and their applications: current status and new trends
Qiang Wang, Jizhong Luo, Ziyi Zhong and Armando Borgna
DOI: 10.1039/C0EE00064G

An overview of CO2 capture technologies
Niall MacDowell, Nick Florin, Antoine Buchard, Jason Hallett, Amparo Galindo, George Jackson, Claire S. Adjiman, Charlotte K. Williams, Nilay Shah and Paul Fennell
DOI: 10.1039/C004106H

Thermodynamic analysis on energy densities of batteries
Chen-Xi Zu and Hong Li
DOI: 10.1039/C0EE00777C

A review of water treatment membrane nanotechnologies
MaryTheresa M. Pendergast and Eric M.V. Hoek
DOI: 10.1039/C0EE00541J

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Roof tiles to generate power

Scientists are attempting to reduce the costs of harnessing the sun’s energy by creating ceramic tiles that can perform photovoltaic action, so-called “solar tiles” that can be used to tile roofs.

Hugo Aguas, Rodrigo Martins and their research group at Universidade NOVA de Lisboa and UNINOVA have successfully fabricated solar tiles and demonstrated market viability with a cost estimation.

Their new solar tiles were able to achieve a 5% conversion efficiency and 80% quantum efficiency.

Read the EES article today:

Silicon thin film solar cells on commercial tiles
H Aguas, S K Ram, A Araujo, D Gaspar, A Vicente, S A Filonovich, E Fortunato, R Martins and I Ferreira
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee02303a

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Fire safety tests for lithium ion batteries

Scientists are looking into the safety of lithium ion batteries so that they can be used to power large devices such as cars or power grids.

Lithium ions are OK for use in small devices, such as laptops and phones, but there is a risk of fire if they need to power devices with higher energies.

Scientists from France have used a fire calorimeter – a device recognised by US and EU regulating bodies – to get an insight into the fire behaviour of these batteries.

The apparatus provides online analysis of mass loss and combustion gas production (O2, CO, CO2, hydrogen halides, HCN, NOx, SOx, aldehydes, THC). From these data, the rate of heat release, heat of combustion and the mass of burnt products from the combustion tests could be deduced. The data could help in fire simulation tests, say the researchers. They add that the identification and quantification of toxic emissions from combustion gases can be estimated.

As a result, the data could play a part in improving the safety of batteries, they conclude.

Read the Energy & Environmental Science paper today:

Investigation on the Fire-Induced Hazards of Li-ion Battery Cells by Fire Calorimetry
P Ribiere, S Grugeon, M Morcrette, S Boyanov, S Laruelle and G Marlair
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee02218k

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Plasmon resonant enhancement of dye sensitized solar cells

This paper reports improved efficiency of dye sensitized solar cells (DSSCs) by exploiting the plasmonic resonance of Au nanoparticles. By incorporating plasmon resonant nanoparticles into a TiO2 photoanode, enhanced photocurrent in DSSCs is observed extending from 460 nm to 730 nm.

enhanced photocurrentRead this ‘HOT’ EES article today:

Plasmon resonant enhancement of dye sensitized solar cells
Wenbo Hou, Prathamesh Pavaskar, Zuwei Liu, Jesse Theiss, Mehmet Aykol and Stephen B. Cronin
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE02120F

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Electrical conductivity of microbial nanowires and biofilms

‘HOT’ EES Perspective

This feature article reviews the theory developed to describe the electrical conductivity of redox polymers, applying it here to individual microbial nanowires and microbial biofilms.

Take a look at this Perspective today:

On the electrical conductivity of microbial nanowires and biofilms
Sarah M. Strycharz-Glaven, Rachel M. Snider, Anthony Guiseppi-Elie and Leonard M. Tender
DOI: 10.1039/C1EE01753E

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Fall ACS Update: climate change and chemistry

Today, EES author, Mark Jacobson gave an exciting press conference at the ACS in Denver on his latest research into climate change.

Jacobson answered questions about new research investigating the link between black carbon pollutants and its effect on climate change and global warming. You can read some of his exciting research from EES, including the popular review on solutions to global warming:

Review of solutions to global warming, air pollution, and energy security
Mark Z. Jacobson
DOI: 10.1039/B809990C

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