Archive for June, 2013

Highly efficient catalyst for sun-powered hydrogen production

In their Energy & Environmental Science Garcia et al. report a highly efficient catalyst that enables an industrial reaction to produce hydrogen to be carried out at ambient temperature using only the power of sunlight. Hydrogen has generated a great deal of interest as a clean and efficient energy alternative to fossil fuels.

The authors showed that gold nanoparticles supported on TiO2 could efficiently catalyse the water gas shift reaction, which converts carbon monoxide and water from steam reformation of methane into hydrogen and carbon dioxide, using light irradiation. The scientists tested a variety of TiO2 and CeO2 catalysts and showed that the TiO2/Au catalyst produced more than 10,500 µmol hydrogen per gram – more than twice the amount of the next most efficient catalyst.

Read this exciting article today:

Photocatalytic Water Gas Shift using visible or simulated solar light for the efficient, room-temperature hydrogen generation
Francesc Sastre, Marica Oteri, Avelino Corma and Hermenegildo Garcia
DOI: 10.1039/C3EE40656C

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Very HOT recent articles in EES

We encourage you to take a look at these two very exciting articles recently published in EES:

Sr- and Mn-doped LaAlO3-δ for Solar Thermochemical H2 and CO Production
Anthony H. McDaniel, Elizabeth C. Miller, Darwin Arifin, Andrea Ambrosini, Eric Coker, Ryan O’Hayre, William Chueh and Jianhua Tong
DOI: 10.1039/C3EE41372A

Hybrid Energy Cell for Self-Powered Water Splitting
Ya Yang, Hulin Zhang, Zong-Hong Lin, Yan Liu, Jun Chen, Ziyin Lin, Yusheng Zhou, C P Wong and Zhonglin Wang
DOI: 10.1039/C3EE41485J

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Professor Liao wins the ENI “Renewable and Non-conventional Energy” award

The ENI “Renewable and Non-conventional Energy” award has been presented ex aequo to Frances Arnold, Professor of Chemical Engineering, Biochemistry and Bioengineering at the California Institute of Technology, and James Liao, Parson Foundation Professor and head of the Chemical and Biomolecular Engineering Department at the University of California.

Professor Liao has selected microorganisms for converting wood cellulose biomass, waste proteins and carbon dioxide into useful chemical compounds and fuels using modified forms of E. coli bacteria, achieving high conversion and energy efficiency.

See Prof. Liao’s recent article in EES:

Photosynthetic production of 2-methyl-1-butanol from CO2 in cyanobacterium Synechococcus elongatus PCC7942 and characterization of the native acetohydroxyacid synthase
Claire R. Shen and James C. Liao
DOI: 10.1039/C2EE23148D

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Soybean catalyst for hydrogen evolution: EES article in Chemistry World

A catalyst made from soybeans could overcome a major barrier to cheap hydrogen fuel by replacing the platinum catalyst used in the electrocatalytic production of hydrogen, claim scientists in the US. 

For hydrogen to be competitive with petroleum fuels, the US Department of Energy has estimated that its cost must be reduced from $4–5/kg to $2–3/kg. The platinum catalyst used to make hydrogen via water electrolysis is a significant part of the cost, so the search is on for cheaper catalysts that are just as efficient.

Now, James Muckerman, Wei-Fu Chen and colleagues at Brookhaven National Laboratory, New York, have produced a catalyst made from molybdenum – an abundant transition metal, around 1500 times cheaper than platinum – and ground soybeans.

 

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Interested to know more?

Read the full article by Helen Potter in Chemistry World here…

Read the article from EES:

Biomass-derived electrocatalytic composites for hydrogen evolution
Wei-Fu Chen, Shilpa Iyer, Shweta Iyer, Kotaro Sasaki, Chiu-Hui Wang, Yimei Zhu, James T. Muckerman and Etsuko Fujitaa  
Energy Environ. Sci., 2013,6, 1818-1826
DOI: 10.1039/C3EE40596F

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