Posts Tagged ‘Dalton’

Introducing our newest Associate Editor, Maarit Karppinen

We would like to offer a very warm welcome to our new Dalton Transactions Associate Editor Professor Maarit Karppinen!

Maarit Karppinen received her doctoral degree in inorganic chemistry from Helsinki University of Technology in 1993. After holding shorter-term teaching and research fellow positions in Finland, she accepted first a one-year visiting professorship and later in 2001 a regular associate professor chair in Japan at the Materials and Structures Laboratory, Tokyo Institute of Technology, where she brought the deep chemistry contribution to the strong multidisciplinary research group focusing on functional oxide materials. In 2006 she returned back to Alma Mater as a full professor to combine her expertise in fundamental new-material research to the long traditions of the laboratory in leading ALD thin-film research. In 2008 she became the head of the Chemistry Department; this leadership was then transformed to the newly established Aalto University, formed by merging Helsinki University of Technology with two other universities from the Helsinki area. For 2009-2013 she was also holding the prestigious Academy Professor position in Finland. Currently she is internationally renowned for her pioneering research on complex perovskite oxides and ALD/MLD fabricated inorganic-organic thin films; for this latter field she received her ERC Advanced grant in 2013, followed by two ERC Proof-of-Concept grants. Her group’s work is truly interdisciplinary, covering both the design and synthesis of new materials and their characterization for a variety of functionalities. She was nominated as a VIP Visiting International Professor at Ruhr-University Bochum in 2016, and Aalto Distinguished Professor in 2017.

Maarit has given her insight and thoughts on the field of inorganic materials chemistry and the role of Dalton Transactions:

I have always been fascinated by new materials – materials never synthesized or even imagined before. Such increasingly complex on-demand designed multifunctional new materials are continuously searched for to solve the grand societal challenges related to energy, environment and wellbeing.”

“As inorganic chemists, we have the entire Periodic Table of Elements at our disposal. For science, we are free to play with all elements, but for practical use issues such as the abundance, accessibility, recyclability, safety and environmental impact of the elements need to be taken into account. Synthesis is another chemistry asset in new-material research: a unique synthesis method most likely leads us to unique materials, not to forget modelling and sample characterization.”

“Dalton Transactions is a journal for diverse areas of inorganic chemistry, and thus an ideal platform for discussing the most intriguing challenges in the broad and impactful field of inorganic (materials) chemistry.“

Editor’s Choice: Maarit’s favourite Dalton Transactions articles

Below are three recent publications that Maarit has chosen as her favourite Dalton Transactions articles. All articles listed here are free to access for a limited time.

Xenon in oxide frameworks: at the crossroads between inorganic chemistry and planetary science

Sergey N. Britvin
Dalton Trans. 2020, Advance Article
https://doi.org/10.1039/d0dt00318b

“This Frontier article by Britvin is an example of the exciting insights in chemistry achieved when a researcher challenges a rare or otherwise difficult or forgotten element.”

 

Fluorination and reduction of CaCrO3 by topochemical methods

Christian A. Juillerat, Yoshihiro Tsujimoto, Akira Chikamatsu, Yuji Masubuchi, Tetsuya Hasegawa and Kazunari Yamaura
Dalton Trans., 2020, 49, 1997-2003
https://doi.org/10.1039/C9DT04321G

This paper by Juillerat, Tsujimoto et al. combines, in an innovative manner, two synthesis methods, ultra-high-pressure and topochemical methods, to realize a series of novel Ca-Cr-(O,F) compounds.”

 

All-gas-phase synthesis of amino-functionalized UiO-66 thin films

Kristian Blindheim Lausund, Veljko Petrovic and Ola Nilsen
Dalton Trans., 2017, 46, 16983-16992
https://doi.org/10.1039/C7DT03518G

“This paper by Lausund, Petrovic and Nilsen  is another intriguing example of utilizing innovative synthesis approaches, in this case the strongly emerging atomic/molecular layer deposition (ALD/MLD) thin-film technique, for fabricating metal-organic framework (MOF) through gas-phase synthesis.

 

Read a selection of Marrit Karppinen’s latest work published by the Royal Society of Chemistry:

Atomic/molecular layer deposition and electrochemical performance of dilithium 2-aminoterephthalate
Juho Heiska, Mikko Nisula, Eeva-Leena Rautama, Antti J. Karttunen and Maarit Karppinen
Dalton Trans., 2020, 49, 1591-1599
DOI: 10.1039/C9DT04572D, Paper

Atomic/molecular layer deposition of Cu–organic thin films
D. J. Hagen, L. Mai, A. Devi, J. Sainio and M. Karppinen
Dalton Trans., 2018, 47, 15791-15800
DOI: 10.1039/C8DT03735C, Paper

Dalton Transactions, Royal Society of Chemistry

 

Submit your research or reviews to Maarit today, she will be delighted to receive them! – see our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal. Don’t forget to keep up to date with us on Twitter @DaltonTrans !

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Themed Web Collection: Inorganic Reaction Mechanisms

Guest edited by Sam de Visser (University of Manchester), Jonathan Rourke (University of Cardiff) and Kylie Vincent (University of Oxford) we recently published a special collection of Dalton Transactions which celebrates 50 years of the Inorganic Reaction Mechanisms Discussion Group and highlights the breadth and depth of the area, paying particular interest to areas of contemporary relevance.

 

Browse the collection

 

Check out a selection of the articles below:

Inorganic reaction mechanisms. A personal journey
Colin D. Hubbard, Debabrata Chatterjee, Maria Oszajca, Justyna Polaczek, Olga Impert, Marta Chrzanowska, Anna Katafias, Ralph Puchta and Rudi van Eldik
Dalton Trans., 2020, 49, 4599-4659
DOI: 10.1039/C9DT04620H, Perspective

A subtle structural change in the distal haem pocket has a remarkable effect on tuning hydrogen peroxide reactivity in dye decolourising peroxidases from Streptomyces lividans
Marina Lučić, Amanda K. Chaplin, Tadeo Moreno-Chicano, Florian S. N. Dworkowski, Michael T. Wilson, Dimitri A. Svistunenko, Michael A. Hough and Jonathan A. R. Worrall
Dalton Trans., 2020, 49, 1620-1636
DOI: 10.1039/C9DT04583J, Paper

Tandem deoxygenative hydrosilation of carbon dioxide with a cationic scandium hydridoborate and B(C6F5)3
Daniel W. Beh, Warren E. Piers, Benjamin S. Gelfand and Jian-Bin Lin
Dalton Trans., 2020, 49, 95-101
DOI: 10.1039/C9DT04323C, Paper

Photoactivated silicon–oxygen and silicon–nitrogen heterodehydrocoupling with a commercially available iron compound
Matthew B. Reuter, Michael P. Cibuzar, James Hammerton and Rory Waterman
Dalton Trans., 2020, 49, 2972-2978
DOI: 10.1039/C9DT04870G, Paper

Dalton Transactions, Royal Society of Chemistry

Submit your research or reviews to Dalton Transactions today! – see our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

Keep up to date with our latest HOT articles, Reviews, Collections & more by following us on Twitter. You can also keep informed by signing up to our E-Alerts.

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Outstanding Reviewers for Dalton Transactions in 2019

We would like to highlight the Outstanding Reviewers for Dalton Transactions in 2019, as selected by the editorial team, for their significant contribution to the journal. The reviewers have been chosen based on the number, timeliness and quality of the reports completed over the last 12 months.

We would like to say a big thank you to those individuals listed here as well as to all of the reviewers that have supported the journal. Each Outstanding Reviewer will receive a certificate to give recognition for their significant contribution.

Dr Claudia Bizzarri, Karlsruhe Institute of Technology, ORCID: 0000-0002-4077-2553

Dr Eszter Borbas, Uppsala University, ORCID: 0000-0003-2449-102X

Dr David Harding, Walailak University, ORCID: 0000-0001-8866-2401

Dr Atsushi Kobayashi, Hokkaido University, ORCID: 0000-0002-1937-7698

Dr Haralampos Miras, University of Glasgow, ORCID: 0000-0002-0086-5173

Dr Marta Mosquera, University of Alcalá, ORCID: 0000-0003-2248-3050

Dr Alexander Ovchinnikov, Stockholm University, ORCID: 0000-0002-0537-4234

Professor Eric Rivard, University of Alberta, ORCID:0000-0002-0360-0090

Professor Wen-Juan Ruan, Nankai University, ORCID: 0000-0001-5889-1043

Dr Eringathodi Suresh, Central Salt and Marine Chemicals Research Institute, ORCID: 0000-0002-1934-6832

Professor Jinkui Tang, Changchun Institute of Applied Chemistry, ORCID: 0000-0002-8600-7718

Dr Thomas Teets, University of Houston, ORCID: 0000-0002-7471-8467

 

We would also like to thank the Dalton Transactions board and the inorganic chemistry community for their continued support of the journal, as authors, reviewers and readers.

If you would like to become a reviewer for our journal, just email us with details of your research interests and an up-to-date CV or résumé. You can find more details in our author and reviewer resource centre

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Introducing our new Chair, Russell Morris

 

 

 

Read a selection of Russell’s latest work published by the Royal Society of Chemistry:

Insight into the ADOR zeolite-to-zeolite transformation: the UOV case
Valeryia Kasneryk, Mariya Shamzhy, Maksym Opanasenko, Paul S. Wheatley, Russell E. Morris and Jiří Čejka
Dalton Trans., 2018, 47, 3084-3092
DOI: 10.1039/C7DT03751A, Paper

A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release
Susan E. Henkelis, Simon M. Vornholt, David B. Cordes, Alexandra M. Z. Slawin, Paul S. Wheatley and Russell E. Morris
CrystEngComm, 2019, 21, 1857-1861
DOI: 10.1039/C9CE00098D, Communication

 

Dalton Transactions, Royal Society of Chemistry

 

Submit your research or reviews to Russell today, he will be delighted to receive them! – see our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal. Don’t forget to keep up to date with us on Twitter @DaltonTrans!

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Hot Articles – Online now and free to access

Dalton Transactions, Royal Society of Chemistry

We have updated our ‘HOT articles’ for the last quarter of 2019.

We update our HOT articles collection quarterly and make the selected articles free to access until 11 March 2020! This collection represents the top 10% of research published in Dalton Transactions between October – December 2019.

Make the most of the free to access period by browsing the collection today!

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A golden future for hydrogen bonding

Two-dimensional contour plot of [Me2Au]− adduct with HCN.

Source: © Royal Society of Chemistry Two-dimensional contour plot of [Me2Au]− adduct with HCN. Red areas identify the stabilising interactions and blue destabilising interactions

Gold has surprised chemists by showing that a formally positively charged Au(I) ion can be a hydrogen bond acceptor.1 This discovery challenges the traditional view that hydrogen bond acceptors are negatively charged.

Catharine Esterhuysen and her colleagues at the University of Stellenbosch, South Africa, used theoretical calculations to study how dimethylaurate interacted with six hydrogen bond donors including HF, HCN and NH3.This study expands their previous work showing that Au(I) can be a hydrogen bond acceptor for water.2 Strong or moderate hydrogen bonds were found for five of the pairs. As expected, the Au(I)···H–X bonds were weaker than those formed with the negative auride ion, but surprisingly the bonds with HF and HCN were more stabilising than their analogues with [(CO)4Co], which contains a negatively charged Co centre.

Interested? The full article can be read in Chemistry World.

The original article can be read below and is free to access until 27th April 2017.

Gold setting the “gold standard” among transition metals as a hydrogen bond acceptor – a theoretical investigation
Ferdinand Groenewald, Helgard G. Raubenheimer, Jan Dillen and Catharine Esterhuysen*
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C7DT00329C

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Outstanding Reviewers for Dalton Transactions in 2016

Following the success of Peer Review Week in September 2016 (dedicated to reviewer recognition) during which we published a list of our top reviewers, we are delighted to announce that we will continue to recognise the contribution that our reviewers make to the journal by announcing our Outstanding Reviewers each year.

We would like to highlight the Outstanding Reviewers for Dalton Transactions in 2016, as selected by the editorial team, for their significant contribution to the journal. The reviewers have been chosen based on the number, timeliness and quality of the reports completed over the last 12 months.

We would like to say a big thank you to those individuals listed here as well as to all of the reviewers that have supported the journal. Each Outstanding Reviewer will receive a certificate to give recognition for their significant contribution.

Marius Andruh, University of Bucharest
Peter Budzelaar, University of Manitoba
Malcolm Halcrow, University of Leeds
Atsushi Kobayashi, Hokkaido University
George Kostakis, University of Sussex
Dong-Sheng Li, China Three Gorges University
Chengyu Mao, University of California at Riverside
Dawid Pinkowicz, Jagiellonian University
Di Sun, Shandong University

We would also like to thank the Dalton Transactions board and the Inorganic community for their continued support of the journal, as authors, reviewers and readers.

If you would like to become a reviewer for our journal, just email us with details of your research interests and an up-to-date CV or résumé.  You can find more details in our author and reviewer resource centre

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First uranium–rhodium bond shows that shorter is not stronger

Researchers in the UK have made the first two uranium–rhodium complexes and found their uranium–rhodium bonds to be among the shortest heterometallic uranium bonds ever reported.1

Source: © Royal Society of Chemistry The uranium–rhodium distances in these two complexes are among the shortest between f-elements and transition metals reported to date

Building on their recent success forming uranium complexes with nickel, palladium and platinum,2 Polly Arnold’s group at the University of Edinburgh used a carefully designed bidentate phosphinoaryloxide ligand (ArPO) to create two distinct uranium–rhodium complexes: a tetrametallic dimer, [I2U(OArP)2RhI]2, and a monomeric complex with three phosphinoaryloxide ligands and a bridging iodide. Although the two uranium–rhodium bonds are of similar length (2.760Å in the dimeric complex and 2.763Å in the monomeric one), electrochemical studies show that the bond stabilities are very different.

Interested? The full story can be read in Chemistry World.

The original article can be read below and is free to access until 30th March 2017:

Uranium rhodium bonding in heterometallic complexes
J. A. Hlina, J. A. L. Wells, J. R. Pankhurst, Jason B. Love and P. L. Arnold
Dalton Trans., 2017, Advance Article
DOI: 10.1039/C6DT04570G

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Call for papers: 2017 themed issue

We are delighted to announce a new Dalton Transactions themed issue to be published in 2017:

Frontiers in Radionuclide Imaging and Therapy, “A chemical journey from naturally radioactive elements to targeted theranostic agents” Guest Editors: Professors Angela Casini (Cardiff University), João D. G. Correia (Universidade de Lisboa) and Chris Orvig (University of British Columbia). Deadline: 19th May 2017

Does your research fit into this subject area? If so, we would welcome your contribution. For further details on issue scope and on how to submit, see below:

How to submit

All types of manuscript – communications, full papers, frontiers and perspectives, will be considered for publication. The manuscript should be prepared according to our article guidelines and submitted via our online system.

All manuscripts will be subject to normal peer review and inclusion in the themed issue will be at the discretion of the Guest Editors. Please indicate in your submission the themed issue you would like to be considered for.

Issue scope

This special issue of Dalton Transactions will highlight emerging trends in the use of radionuclides, namely radiometals, for molecular imaging and systemic radiotherapy. It intends to cover all aspects of the use of radionuclides in biomedical/clinical applications, including:

  • Updates on the chemistry of d- (e.g. Tc and Re) and f-elements, namely actinides and lanthanides (e.g. Lu and Ho), and their applications in molecular imaging and targeted radionuclide therapy. Metal-based complexes such as those with Ru, Ir or Au may also be included as targeted chemical probes for imaging in biological systems (e.g. cells).
  • Multimodal imaging agents with at least one modality being radioactive (e.g. PET- or SPECT-MRI probes; Pet- or SPECT- optical imaging, etc.).
  • Radiometal-containing nanoparticles for application in cancer theranostics; image-guided drug delivery in vivo.
  • Production and application of alpha emitters (e.g. 212Pb, 213Bi, 223Ra or 211At); new trends and applications.
  • Isotopes that are only beginning to become available (by generators, rather than made in cyclotrons or nuclear reactors), such as 68Ga or 213Bi (for alpha therapy).
  • Use of “new” or “so far neglected” radioisotopes of the f elements (Lanthanides) for medicinal applications.

Considering the multidisciplinary nature of the topics mentioned, contributions from frontier subjects are welcome. As regards the clinical applications of the above mentioned molecular compounds and nanoparticles, translational aspects should also be addressed in this special issue in addition to chemical design. Thus, contributions related to pharmacological and clinical studies are also welcome.

Interested in submitting a paper? Please contact us (Dalton-RSC@rsc.org) for more information.

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Welcoming our newest Editorial Board member: Marinella Mazzanti

Welcome to Professor Marinella Mazzanti who joins us as Editorial Board member for Dalton Transactions. Professor Mazzanti is currently the Head and founder of the Group of Coordination Chemistry at EPFL (Ecole Polytechnique Fédérale de Lausanne) in Switzerland.

Her research interests include: Lanthanides and Actinides Coordination Chemistry; Lanthanides and Actinides Supramolecular Chemistry; Redox Reactivity of Low Valent f Elements; Gadolinium Based MRI Contrast Agents; Lanthanide Based Luminescent Architectures; Single Molecule Magnets; Small Molecule Activation.

Professor Mazzanti has also participated in more than 30 invited seminars at International conferences and Universities in Europe and the USA.

Below is a selection of articles Professor Mazzanti has published with us:

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site
Clément Camp, Oliver Cooper, Julie Andrez, Jacques Pécaut and Marinella Mazzanti
Dalton Trans., 2015, 44, 2650-2656
DOI: 10.1039/C4DT02585G, Paper
From themed collection Dalton Discussion 14: Advancing the chemistry of the f-elements

Crystal structure diversity in the bis[hydrotris(3,5-dimethylpyrazolyl)borate]iodouranium(III) complex: from neutral to cationic forms
Maria Augusta Antunes, Isabel C. Santos, Hélène Bolvin, Laura C. J. Pereira, Marinella Mazzanti, Joaquim Marçalo and Manuel Almeida
Dalton Trans., 2013, 42, 8861-8867
DOI: 10.1039/C3DT50753J, Paper

Optimizing the relaxivity of Gd(III) complexes appended to InP/ZnS quantum dots by linker tuning
Graeme J. Stasiuk, Sudarsan Tamang, Daniel Imbert, Christelle Gateau, Peter Reiss, Pascal Fries and Marinella Mazzanti
Dalton Trans., 2013, 42, 8197-8200
DOI: 10.1039/C3DT50774B, Communication

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