ChemComm Emerging Investigator Lectureship

ChemComm is delighted to invite nominations for the very first ChemComm Emerging Investigator Lectureship. The lectureship, which will be awarded annually, will recognise an emerging scientist in the early stages of their independent academic career.

Deadline for nominations: 28th February 2011.

Visit the ChemComm blog for more information.

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Hot Article: Nanoparticle thermoelectric materials

Sabine Schlecht and colleagues have used mixed polymer/precursor films to produce films of nanoparticles of PbSe or PbTe thermoelectric materials.  Find out more in their Dalton Transactions Hot Article.

READ FOR FREE! Until November 25th.

Polymer-assisted preparation of nanoscale films of thermoelectric PbSe and PbTe and of lead chalcogenide-polymer composite films 
Christoph Erk, Andreas Berger, Joachim H. Wendorff and Sabine Schlecht

Dalton Trans., 2010, DOI: 10.1039/C0DT00745E

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Hot Article: Zig-zag magnets

In this Dalton Transactions article, Paul Kogerler and Xiao-Ming Chen discuss the first cobalt single molecule magnet with a linear core struture and featuring a zig-zag backbone.

 
READ FOR FREE! Until November 25th.

A tetranuclear cobalt(II) chain with slow magnetization relaxation 

Yan-Zhen Zheng, Manfred Speldrich, Helmut Schilder, Xiao-Ming Chen and Paul Kögerler
Dalton Trans., 2010, DOI: 10.1039/C0DT00935K

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Hot Article: Changing magnetic behaviours

Christian Nather and Jan Boeckmann from the Universitat zu Kiel, Germany show that removing pyridines from [Co(NCS)2(pyridine)4] in the solid state to form [Co(NCS)2(pyridine)2]n actually results in a change in magnetic behaviour. Read how in this Dalton Transactions Hot Article….
 

READ FOR FREE! Until November 25th

Solid-state transformation of [Co(NCS)2(pyridine)4] into [Co(NCS)2(pyridine)2]n: from Curie–Weiss paramagnetism to single chain magnetic behaviour
 
Jan Boeckmann and Christian Näther
Dalton Trans., 2010, DOI: 10.1039/C0DT00904K

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Hot Article: A new family of antimonides

Bayrammurad Saparov and Svilen Bobev, from the University of Delaware, USA, have synthesised a whole new familyof quaternary fluoro-antimonides A5Cd2Sb5F (A = Sr, Ba, Eu) and oxyantimonides
Ba5Cd2Sb5Ox (0.5<x<0.7).

READ FOR FREE! Until November 25th.

Synthesis, crystal and electronic structures of the new quaternary phases A5Cd2Sb5F (A = Sr, Ba, Eu), and Ba5Cd2Sb5Ox (0.5<x<0.7) 

Bayrammurad Saparov and Svilen Bobev
Dalton Trans., 2010, DOI: 10.1039/C0DT00595A

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Sex hormone in cancer warfare

Inactive platinum complexes can be transformed into exciting anticancer compounds by coupling them with testosterone using a quick and simple method, claim UK scientists. This could pave the way for new target specific anticancer drugs. 

Platinum compounds cisplatin, carboplatin and oxaliplatin are commonly used to treat cancer. But these drugs can only treat a limited number of tumours and some types of cancer are now showing resistance. The drugs are also highly toxic and cause unwanted side effects. Drugs that target the site of disease without harming healthy tissue are better and have been explored by using the sex hormone oestrogen attached to a Pt compound. These target oestrogen receptors which are over-expressed in most breast cancer tumours. 

Read more of Carl Saxton’s story on these exciting papers here.

Or read the Dalton Transactions articles for FREE!

An androgenic steroid delivery vector that imparts activity to a non-conventional platinum(II) metallo-drug
Martin Huxley, Carlos Sanchez-Cano, Michael J. Browning, Carmen Navarro-Ranninger, Adoracion G. Quiroga, Alison Rodger and Michael J. Hannon
Dalton Trans., 2010 DOI:
10.1039/c0dt00838a

Conjugation of testosterone modifies the interaction of mono-functional cationic platinum(II) complexes with DNA, causing significant alterations to the DNA helix
Carlos Sanchez-Cano, Martin Huxley, Cosimo Ducani, Amal E. Hamad, Michael J. Browning, Carmen Navarro-Ranninger, Adoracion G. Quiroga, Alison Rodger and Michael J. Hannon
Dalton Trans., 2010 DOI:
10.1039/c0dt00839g

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Dalton Transactions Poster Prize winner

Congratulations to Koji Yamamoto from the Osaka University in Japan– recent winner of the Dalton Transactions Poster Prize at the 60th JSCC Symposium and the 60th Anniversary Conference on Coordination Chemistry which both took place as parallel sessions in Osaka from the 27th-30th September!

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Top Ten most-read Dalton Transactions articles in September

Read the most-read Dalton Transactions articles of September 2010, listed below:

C. N. R. Rao, S. R. C. Vivekchand, Kanishka Biswas and A. Govindaraj, Dalton Trans., 2007, 3728-3749
DOI: 10.1039/B708342D

Michael F. Lappert and John N. Murrell, Dalton Trans., 2003, 3811-3820
DOI: 10.1039/B307622A
 
Nial J. Wheate, Shonagh Walker, Gemma E. Craig and Rabbab Oun, Dalton Trans., 2010, 39, 8113-8127
DOI: 10.1039/C0DT00292E
 
P. P. Edwards, A. Porch, M. O. Jones, D. V. Morgan and R. M. Perks, Dalton Trans., 2004, 2995-3002
DOI: 10.1039/B408864F
 
Himanshu Arora, Christian Philouze, Olivier Jarjayes and Fabrice Thomas, Dalton Trans., 2010, 39, 10088-10098
DOI: 10.1039/C0DT00342E
 
Bart M. J. M. Suijkerbuijk, Bas N. H. Aerts, Harm P. Dijkstra, Martin Lutz, Anthony L. Spek, Gerard van Koten and Robertus J. M. Klein Gebbink, Dalton Trans., 2007, 1273-1276
DOI: 10.1039/B701978P
 
Christoph Janiak, Dalton Trans., 2003, 2781-2804
DOI: 10.1039/B305705B
 
Maria Vallet-Regí, J. Chem. Soc., Dalton Trans., 2001, 97-108
DOI: 10.1039/B007852M
 
Etienne Baranoff, Henk J. Bolink, Filippo De Angelis, Simona Fantacci, Davide Di Censo, Karim Djellab, Michael Grätzel and Md. Khaja Nazeeruddin, Dalton Trans., 2010, 39, 8914-8918
DOI: 10.1039/C0DT00414F
 
Constantinos G. Efthymiou, Anastasia N. Georgopoulou, Constantina Papatriantafyllopoulou, Aris Terzis, Catherine P. Raptopoulou, Albert Escuer and Spyros P. Perlepes, Dalton Trans., 2010, 39, 8603-8605
DOI: 10.1039/C0DT00493F
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2nd Dalton Transactions International Symposium

I am delighted to announce details of the 2nd Dalton Transactions International Symposium to be held in Shanghai and Hong Kong in November 2010.  This 2010 Symposium follows the very successful Symposium held in China in October 2009.  9 world class presentations (6 at each venue) will be given.

The 2nd Dalton Transactions International Symposium will take place in two venues.  16th November will see the Symposium hosted in Shanghai, as part of the 11th Conference on Solid State Chemistry and Inorganic Synthesis. The Symposium will then move to Hong Kong on 18th November.

Speaker details of both days of the Symposium are:

16th November 2010, in Shanghai:

  • Lee Cronin – University of Glasgow, UK 
  • Song Gao – Peking University, China    
  • Maochun Hong – Fujian Institute of the Research on the Structure of Matter, China
  • Lei Jiang – Chinese Academy of Sciences, Beijing, China
  • Hiroki Oshio – University of Tsukuba, Japan
  • Annie Powell – Karlsruhe Institute of Technology, Germany            

18th November 2010, in Hong Kong:

  • Lee Cronin – University of Glasgow, UK
  • Hiroki Oshio – University of Tsukuba, Japan
  • Annie Powell – Karlsruhe Institute of Technology, Germany 
  • Wai Yeung Wong – Hong Kong Baptist University, China  
  • Zuowei Xie – Chinese University of Hong Kong, China
  • Vivian Yam – University of Hong Kong, China  

More information about the two days of the Symposium can be found here.

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IUPAC define hydrogen bond

An IUPAC task group has recently published their recommendations for the definition for the hydrogen bond.

“The hydrogen bond is an attractive interaction between a hydrogen atom from a molecule or a molecular fragment X–H in which X is more electronegative than H, and an atom or a group of atoms in the same or a different molecule, in which there is evidence of bond formation.”

The recommendations continue with a list of experimental and theoretical criteria that can be used as evidence for the presence of the hydrogen bond, and finish with characteristics that are typical of hydrogen bonded systems.

For more information on the task group and to view the provisional recommendation see the IUPAC report.

Follow the links below to read two Dalton Transactions articles with a focus on bonding:

and
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