Dalton Transactions Blog

Electroanalytical characterization of Np(vi)/Np(v) redox in a pentadentate ligand environment and stabilization of [Np^VO₂]⁺ by hydrogen bonding (Open Access)

Emily R. Mikeska, T. Davis Curry, Richard E. Wilson* and James D. Blakemore*

Dalton Trans., 2024, 53, 19126-19142

Al(iii) and Ga(iii) triflate complexes as solvate ionic liquids: speciation and application as soluble and recyclable Lewis acidic catalysts (Open Access)

Justyna Więcławik, Alina Brzęczek-Szafran, Sebastian Jurczyk, Karolina Matuszek, Małgorzata Swadźba-Kwaśny* and Anna Chrobok*

Dalton Trans., 2024, 53, 19143-19152

Rhenium(i) and technetium(i) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease

Ana C. R. Gonçalves, Silvia H. Libardi, Júlio C. Borges, Ronaldo J. Oliveira, Carla Gotzmann, Olivier Blacque,  Sergio de Albuquerque, Carla D. Lopes*,  Roger Alberto and Pedro I. S. Maia*

Dalton Trans., 2024, 53, 19153-19165

Chemical and spectroscopic characterization of plutonium tetrafluoride

Jared S. Kinyon, Eliel Villa-Aleman*, Elodia Ciprian, Amy E. Hixon, Bryan J. Foley, Jonathan H. Christian, Jason R. Darvin, Don D. Dick, Amanda J. Casella, Lucas E. Sweet, Edgar C. Buck, Forrest D. Heller, Aaron D. Nicholas, Cody A. Nizinski and Richard A. Clark

Dalton Trans., 2024, 53, 19166-19178

Ru(ii)–arene azole complexes as anti-amyloid-β agents
Ryan M. Hacker, Daniela M. Grimard, Katie A. Morgan, Eaman Saleh, Morgan M. Wrublik, Cade J. Meiss, Caitlyn C. Kant, Marjorie A. Jones, William W. Brennessel and Michael I. Webb*

Dalton Trans., 2024, 53, 18845-18855

Synthesis and reduction of [(C₅H₄SiMe₃)₂Ln(μ-OR)]₂ (Ln = La, Ce) complexes: structural effects of bridging alkoxides (Open Access)

Adrian N. Brown, Jack N. Kelleher, Alexander M. Brown, Peter Saghy, Joshua J. Bohl, Jerome R. Robinson* and Daniel N. Huh*

Dalton Trans., 2024, 53, 18856-18864

A twist on a classic scaffold: rational design of a new bimetallic platform

Sultana P. Rumi, Lev N. Zakharov and Addison N. Desnoyer*

Dalton Trans., 2024, 53, 18420-18439

Energetic derivatives substituted with trinitrophenyl: improving the sensitivity of explosives (Open Access)

Qiong Yu*, Yu-cong Chen, Zihao Guo, Tao Li, Zunqi Liu, Wenbin Yi*, Richard J. Staples and Jean’ne M. Shreeve*

 Dalton Trans., 2024, 53, 18467-18472

Cation induced changes to the structure of cryptophane cages

Oscar H. Lloyd Williams, Claudia S. Cox, Meng Yuan Zhang, Martina Lessio, Olivia Rusli, William A. Donald, Lachlan Jekimovs, David L. Marshall, Michael C. Pfrunder, Berwyck L. J. Poad, Thierry Brotin and Nicole J. Rijs*

 Dalton Trans., 2024, 53, 18473-18483

Chemistry of organometallic nucleic acid components: personal perspectives and prospects for the future

Mateusz Klarek and Konrad Kowalski

Dalton Trans., 2024, 53, 18420-18439

Revitalisation of group IV metal-oxo clusters: synthetic approaches, structural motifs and applications Check for updates (Open Access)

Stamatis S. Passadis, Mark Gray,  Tatjana N. Parac-Vogt*, Anastasios D. Keramidas*, Haralampos N. Miras* and Themistoklis A. Kabanos*

Dalton Trans., 2024, 53, 18400-18419

Ferroelectricity in CsPb₂Nb₃O₁₀ and exfoliated 2D nanosheets

Yan Li, Masanari Shimada, Makoto Kobayashi, Eisuke Yamamoto, Ruben Canton-Vitoria, Xiaoyan Liu and Minoru Osada

Dalton Trans., 2024, 53, 18122-18127

Exploring the reductive CO₂ fixation with amines and hydrosilanes using readily available Cu(ii) NHC–phenolate catalyst precursors (Open Access)

Giammarco Meloni, Luca Morgan, David Cappelletti, Matteo Bevilacqua, Claudia Graiff, Piermaria Pinter,  Andrea Biffis, Cristina Tubaro and Marco Baron

Dalton Trans., 2024, 53, 18128-18140

Enhanced electrochemical nitrate reduction to ammonia with nanostructured Mo₂C on carbon nanotube-reduced graphene oxide hybrid support

So Eun Jang, Jae Young Kim and Duck Hyun Youn

Dalton Trans., 2024, 53, 18141-18147

Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level (Open Access)

Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozarya and Claude Piguet*

Dalton Trans., 2024, 53, 17756-17765

A grain-like cerium oxide nanostructure: synthesis and uric acid sensing application

Rafiq Ahmad*, Sakeena Masrat, Md. Tabish Rehman, Mohamed F. AlAjmi, Shamshad Alam, Prabhash Mishra and Byeong-Il Lee*

Dalton Trans., 2024, 53, 17794-17802

Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line (Open Access)

Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes* and José M. Vila*

Dalton Trans., 2024, 53, 17803-17818

Overview and perspectives on metalloid tin cluster chemistry (Open Access)

R. Kimmich and A. Schnepf*

Dalton Trans., 2024, 53, 17429-17436

Plasma-assisted fabrication of ultra-dispersed copper oxides in and on C-rich carbon nitride as functional composites for the oxygen evolution reaction (Open Access)

Mattia Benedet, Angelica Fasan, Davide Barreca, Chiara Maccato*, Cinzia Sada, Silvia Maria Deambrosis, Valentina Zin, Francesco Montagner, Oleg I. Lebedev, Evgeny Modin, Gian Andrea Rizzi and Alberto Gasparotto

Dalton Trans., 2024, 53, 17452-17464

Rationally designed porous self-assembled nanoparticles for combinational chemo-photodynamic therapy

Kanchan Negi, Ashok Kumar, Gourav Chakraborty, Sudhansubala Sahoo, Sushmita Patra, Niladri Patra, Sujit Kumar Bhutia and Sumanta Kumar Sahu*

Dalton Trans., 2024, 53, 17465-17479

Ligand-triggered antenna effect and dual emissions in Eu(iii) MOF and its application in multi-mode sensing of 1,4-dioxane

Madhulekha Gogoi, Sanmilan Jyoti Kalita, Jyotirmoy Deb, Ankur Gogoi and Lakshi Saikia*

Dalton Trans., 2024, 53, 17480-17497

Homoleptic hexa- and penta-coordinated gallium(i) amide complexes of ruthenium and molybdenum (Open Access)

Raphael Bühler, Richard J. J. Weininger, Johannes Stephan, Maximilian Muhr, Balasai M.-T. Bock, Christian Gemel and Roland A. Fischer*

Dalton Trans., 2024, 53, 17162-17168

Activation of uranyl peroxides by ionizing radiation prior to uranyl carbonate formation (Open Access)

Zoe C. Emory, Jay A. LaVerne and Peter C. Burns*

Dalton Trans., 2024, 53, 17169-17178

N-Methylene-C-linked nitropyrazoles and 1,2,4-triazol-3-one: thermally stable energetic materials with reduced sensitivity

Krishna Pandey, Priyanka Das, Meera Khatri and Dheeraj Kumar*

Dalton Trans., 2024, 53, 17179-17189

Electrochemically driven physical properties of solid-state materials: action mechanisms and control schemes

Takeshi Shimizu*, Heng Wang, Katsuhiro Wakamatsu, Shunsuke Ohkata, Naoki Tanifuji and Hirofumi Yoshikawa*

Dalton Trans., 2024, 53, 16772-16796

Electronic, optical and charge transport properties of Zn–porphyrin–C₆₀ MOFs: a combined periodic and cluster modeling

Kevin Granados-Tavera and Gloria Cárdenas-Jirón*

Dalton Trans., 2024, 53, 16830-16842

Grignard reagents as simple precatalysts for the dehydrocoupling of amines and silanes

Claire E. Bushey, Diego R. Javier-Jiménez, Matthew B. Reuter and Rory Waterman*

Dalton Trans., 2024, 53, 16843-16848

Exo- or endo-1H-pyrazole metal coordination modulated by the polyamine chain length in [1 + 1] condensation azamacrocycles. Binuclear complexes with remarkable SOD activity (Open Access)

Irene Bonastre-Sabater, Alberto Lopera, Álvaro Martínez-Camarena, Salvador Blasco, Antonio Doménech-Carbó, Hermas R. Jiménez, Begoña Verdejo, Enrique García-España* and M. Paz Clares*

Dalton Trans., 2024, 53, 16480-16494

Substituted fullerenes as a promising capping ligand towards stabilization of exohedral Dy(iii) based single-ion magnets: a theoretical study

Kusum Kumari and Saurabh Kumar Singh*

Dalton Trans., 2024, 53, 16495-16511

Dinuclear tricarbonylrhenium(i) complexes: impact of regioisomerism on the photoluminescence properties (Open Access)

Stéphen Le Garrec, David Martins-Bessa, Mariusz Wolff, Béatrice Delavaux-Nicot, Sonia Mallet-Ladeira, Charles-Louis Serpentini, Eric Benoist, Florence Bedos-Belval* and Suzanne Fery-Forgues*

Dalton Trans., 2024, 53, 16512-16529

Exploring the persistence of the fluorinated thiolate 2,3,5,6-S(C₆F₄H-4) motif to establish π_F–π_F stacking in metal complexes: a crystal engineering perspective (Open Access)

Everardo Jaime-Adán, Juan Manuel Germán-Acacio*, José Carlos Páez-Franco, Victor H. Lara, Viviana Reyes-Marquez and David Morales-Morales*

Dalton Trans., 2024, 53, 16090-16127

Synthesis and catalytic activity of heterobimetallic Au/M (M = Rh^III, Ir^III) complexes with ditopic mono- and triphosphane ligands (Open Access)

Ivana Predarska, Wieland Körber, Peter Lönnecke, Dmitri Gelman* and Evamarie Hey-Hawkins*

Dalton Trans., 2024, 53, 16159-16169

Taming 2,2′-biimidazole ligands in trivalent chromium complexes (Open Access)

Julien Chong, Amina Benchohra, Céline Besnard, Laure Guénée, Arnulf Rosspeintner, Carlos M. Cruz, Juan-Ramón Jiménez and Claude Piguet*

Dalton Trans., 2024, 53, 15801-15814

MIL-101(Cr)/aminoclay nanocomposites for conversion of CO₂ into cyclic carbonates

Jyoti, Sarita Kumari, Samiran Chakraborty, Prakash Kanoo, Vinod Kumar and Anindita Chakraborty*

Dalton Trans., 2024, 53, 15815-15825

C–H bond activation at antimony(III): synthesis and reactivity of Sb(III)–oxyaryl species (Open Access)

Gabriel Duneş, Marie Cordier, Samia Kahlal, Alpar Pöllnitz, Jean-Yves Saillard*, Cristian Silvestru* and Yann Sarazin*

Dalton Trans., 2024, 53, 15427-15440

Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and unusual transient dialumene (Open Access)

Xiaobai Wang, Raphael F. Ligorio, Franziska Rüttger, David M. J. Krengel, Nico Graw, Regine Herbst-Irmer, Anna Krawczuk and Dietmar Stalke*

Dalton Trans., 2024, 53, 15441-15450

A sustainable CVD approach for ZrN as a potential catalyst for nitrogen reduction reaction (Open Access)

Jean-Pierre Glauber, Julian Lorenz, Ji Liu, Björn Müller, Sebastian Bragulla, Aleksander Kostka, Detlef Rogalla, Michael Wark, Michael Nolan, Corinna Harms and Anjana Devi*

Dalton Trans., 2024, 53, 15451-15464

Synthesis of a series of octaalkoxy-substituted cage silsesquioxanes catalyzed by zinc acetate

Naoki Watanabe, Hiroaki Imoto and Kensuke Naka*

Dalton Trans., 2024, 53, 14986-14994

Photoluminescence and magnetic properties of isostructural europium(iii), gadolinium(iii) and terbium(iii) oxamate-based coordination polymers

Cleverton O. C. da Silveira, Willian X. C. Oliveira, Eufrânio N. da Silva Júnior, Meiry E. Alvarenga, Felipe T. Martins, Claudia C. Gatto, Carlos B. Pinheiro, Emerson F. Pedroso, Júlia P. O. Silva, Lippy F. Marques, Moliria V. Santos, Francisco R. Torres, Rividy Euclides, Ricardo O. Freire, Wallace C. Nunes, Adriele A. de Almeida, Marcelo Knobel and Cynthia L. M. Pereira*

Dalton Trans., 2024, 53, 14995-15009

Temperature-dependent photoluminescence down to 77 K of organotin molecular rotors: eco-friendly synthesis, photophysical characterization, X-ray structures, and DFT studies

Arelly M. Cantón-Díaz, Blanca M. Muñoz-Flores, Luis F. Macías-Gamboa, Ivana Moggio, Eduardo Arias, Gleb Turlakov, H. V. Rasika Dias, Gioele Colombo, Stefano Brenna and Víctor M. Jiménez-Pérez*

Dalton Trans., 2024, 53, 15010-15031

Recent advances and perspectives on intercalation layered compounds part 1: design and applications in the field of energy (Open Access)

Chiara Bisio*, Jocelyne Brendlé*, Sébastien Cahen, Yongjun Feng, Seong-Ju Hwang, Klara Melanova, Morena Nocchetti*, Dermot O’Hare, Pierre Rabu and Fabrice Leroux*

Dalton Trans., 2024, 53, 14525-14550

Tuning the spin-crossover properties of [Fe₂] metal–organic cages

Laia Navarro, Arnau Garcia-Duran and Jordi Cirera*

Dalton Trans., 2024, 53, 14592-14601

Ligand exchange induced crystal structure and morphology evolution of copper–tin–sulfur binary and ternary compounds

Suqin Chen, Ying Xu, Yangyang Weng, Pengfei Lou, Xiaoyan Zhang* and Ningzhong Bao*

Dalton Trans., 2024, 53, 14602-14609

Spin crossover of a Fe(II) mononuclear complex induced by intermolecular factors involving chloride and solvent ordering

Kenneth Zhang, Matthew J. Wallis, Alexander R. Craze, Shinya Hayami, Hyunsung Min, Daniel J. Fanna, Mohan M. Bhadbhade, Ruoming Tian, Christopher E. Marjo, Leonard F. Lindoy and Feng Li*

Dalton Trans., 2024, 53, 14144-14152

A novel borate phosphor Lu₅Ba₆B₉O₂₇:Ce³⁺ codoped with Sr²⁺/Tb³⁺ for NUV-white light emitting diode application

Chenggang Ma, Hailiang Chen, Min Luo, Fuyun Duan, Yun Ding, Yihang Han, Tianxiang Zheng, Xun Yang and Yu Xiao*

Dalton Trans., 2024, 53, 14153-14162

Octacalcium phosphate with incorporated terephthalate ion derivatives: novel guest molecules and unique fluorescence properties

Taishi Yokoi*, Masahiro Watanabe and Masakazu Kawashita

Dalton Trans., 2024, 53, 14163-14170

Novel ternary Ag^IICo^IIIF₅ fluoride: synthesis, structure and magnetic characteristics

Daniel Jezierski*, Zoran Mazej* and Wojciech Grochala*

Dalton Trans., 2024, 53, 13731-13742

The role of stereochemistry in the anticancer activity of Re(i) tricarbonyl complexes (Open Access)

Atena B. Solea*, Gozde Demirci, Freya M. Harvey, Aurelien Crochet, Fabio Zobi* and Olimpia Mamula Steiner*

Dalton Trans., 2024, 53, 13743-13755

Stabilisation of molecular TiO₄ species on the pore surface of mesoporous silica for photocatalytic H₂ evolution

Hikaru Inada, Masashi Morita* and Kazuyuki Maeda*

Dalton Trans., 2024, 53, 13756-13763

Alpha-metalated N,N-dimethylbenzylamine rare-earth metal complexes and their catalytic applications

Yesmin Akter Rina and Joseph A. R. Schmidt*

Dalton Trans., 2024, 53, 13232-13247

Mechanistic study on the reductive elimination of (aryl)(fluoroaryl)palladium complexes: a key step in regiospecific dehydrogenative cross-coupling

Tomoki Iida, Ryota Sato, Yusuke Yoshigoe, Takaki Kanbara* and Junpei Kuwabara*

Dalton Trans., 2024, 53, 13340-13347

Influence of oxygen distribution on the Li-ion conductivity in oxy-sulfide glasses – taking a closer look (Open Access)

Ramon Zimmermanns, Xianlin Luo, Anna-Lena Hansen*, Marcel Sadowski, Qiang Fu, Karsten Albe, Sylvio Indris, Michael Knapp and Helmut Ehrenberg

Dalton Trans., 2024, 53, 13348-13363

Control of the geometry and anisotropy driven by the combination of steric and anion coordination effects in Co^II complexes with N₆-tripodal ligands: the impact of the size of the ligand on the magnetization relaxation time (Open Access)

Aritz Landart, María Mar Quesada-Moreno, María A. Palacios*, Yanling Li, Mykhaylo Ozerov, J. Krzystek and Enrique Colacio*

Dalton Trans., 2024, 53, 12876-12892

Structural subtleties and catalytic activity of sodium aminophenolate complexes in polylactide degradation: towards sustainable waste management solutions

Edyta Nizioł, Aleksandra Marszałek-Harych, Wiktor Zierkiewicz, Łukasz John and Jolanta Ejfler*

Dalton Trans., 2024, 53, 12893-12904

Hydrogen production by a fully de novo enzyme (Open Access)

Sigrid Berglund, Clara Bassy, Ibrahim Kaya, Per E. Andrén, Vitalii Shtender, Mauricio Lasagna, Cecilia Tommos, Ann Magnuson and Starla D. Glover*

Dalton Trans., 2024, 53, 12905-12916

Fluorescence properties of novel deep-red phosphor LiMg₄SbO₇:Mn⁴⁺ with excellent quantum efficiency and color purity for warm white LEDs

Fei Wang*, Huihui Chen, Shiwei Zhang* and Huiqing Jin*

Dalton Trans., 2024, 53, 12465-12476

Cyclometalated luminescent platinum(ii) complexes of dissymmetrical 2,2′:4′,2′′-terpyridine and its self-assembled dimer presenting Pt–Ag dative bonds

Lorien Benda, Louise Miton, Nihal Hadj Seyd, Lise-Marie Chamoreau, Gediminas Jonusauskas, Nathan D. McClenaghan, Bernold Hasenknopf, Valérie Marvaud and Guillaume Vives*

Dalton Trans., 2024, 53, 12477-12485

Boosting the oxygen reduction activity of non-metallic catalysts via geometric and electronic engineering through nitrogen and chlorine dual-doping

Dong-Li Meng*, Tao-Tao Liu, Ming-Hui Wu, Jing-Wen He, Shao-Wu Du and Yuan-Biao Huang*

Dalton Trans., 2024, 53, 12486-12493

Controlled crystallisation of porous crystals of luminescent platinum(ii) complexes by electronic tuning of ancillary ligands

Takanari Mochizuki, Masaki Yoshida*, Atsushi Kobayashi and Masako Kato*

Dalton Trans., 2024, 53, 12064-12072

A highly anisotropic family of hexagonal bipyramidal Dy(iii) unsaturated 18-crown-6 complexes exceeding the blockade barrier over 2700 K: a computational exploration

Shruti Moorthy, Ibtesham Tarannum, Kusum Kumari and Saurabh Kumar Singh*

Dalton Trans., 2024, 53, 12073-12079

Tetracycline: structural characterization and antimicrobial properties of its water-soluble di-anionic bi-sodium salt (Open Access)

Afroditi S. Tsigara, Christina N. Banti*, Antonios Hatzidimitriou and Sotiris K. Hadjikakou*

Dalton Trans., 2024, 53, 12080-12089

Spin dynamics phenomena of a cerium(iii) double-decker complex induced by intramolecular electron transfer (Open Access)

Kana Kobayashi, Michiyuki Suzuki, Tetsu Sato, Yoji Horii, Takefumi Yoshida, Brian. K. Breedlove, Masahiro Yamashita and Keiichi Katoh*

Dalton Trans., 2024, 53, 11664-11677

The effect of ionic versus covalent functionalization of polyoxometalate hybrid materials with coordinating subunits on their stability and interaction with DNA

Daria Nowicka, Dawid Marcinkowski, Nahir Vadra, Martyna Szymańska, Maciej Kubicki, Giuseppe Consiglio, Wojciech Drożdż, Artur R. Stefankiewicz, Violetta Patroniak, Marta Fik-Jaskółka* and Adam Gorczyński*

Dalton Trans., 2024, 53, 11678-11688

Solvent vapour-responsive structural transformations in molecular crystals composed of a luminescent mononuclear aluminium(iii) complex (Open Access)

Fumiya Kobayashi*, Azuki Yoshida, Misato Gemba, Yuta Takatsu and Makoto Tadokoro*

Dalton Trans., 2024, 53, 11689-11696

The cubic structure of Li₃As stabilized by substitution – Li₈TtAs₄ (Tt = Si, Ge) and Li₁₄TtAs₆ (Tt = Si, Ge, Sn) and their lithium ion conductivity

Martin Schmid, Florian Wegner, Claudia De Giorgi, Florian Pielnhofer and Arno Pfitzner*

Dalton Trans., 2024, 53, 11257-11263

The effect of light irradiation on a nitro-ruthenium porphyrin complex in the induced death of lung cancer cells in two- and three-dimensional cultures: Insights into the effect of nitric oxide

Amanda Blanque Becceneri*, Matheus Torelli Martin, Angelica Ellen Graminha, Márcia Regina Cominetti, Peter C. Ford and Roberto Santana da Silva

Dalton Trans., 2024, 53, 11264-11275

1,2,3-Triazol-5-ylidene- vs. 1,2,3-triazole-based tricarbonylrhenium(i) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties (Open Access)

Corinne Vanucci-Bacqué, Mariusz Wolff, Béatrice Delavaux-Nicot, Abanoub Mosaad Abdallah, Sonia Mallet-Ladeira, Charles-Louis Serpentini, Florence Bedos-Belval, Kar Wai Fong, Xiao Ying Ng, May Lee Low, Eric Benoist* and Suzanne Fery-Forgues*

Dalton Trans., 2024, 53, 11276-11294

Influence of proline and hydroxyproline as antimicrobial and anticancer peptide components on the silver(i) ion activity: structural and biological evaluation with a new theoretical and experimental SAR approach

Gabriela Kuzderová, Simona Sovová, Michaela Rendošová, Róbert Gyepes, Danica Sabolová, Ivona Kožárová, Ľudmila Balážová, Mária Vilková, Martin Kello, Alan Liška and Zuzana Vargová*

Dalton Trans., 2024, 53, 10834-10850

Lattice solvent- and substituent-dependent spin-crossover in isomeric iron(ii) complexes (Open Access)

Senthil Kumar Kuppusamy*, Asato Mizuno, Lea Kämmerer, Soma Salamon, Benoît Heinrich, Corinne Bailly, Ivan Šalitroš*, Heiko Wende* and Mario Ruben*

Dalton Trans., 2024, 53, 10851-10865

Activation of carbon disulfide by a hypersilyl germylene

V. S. Ajithkumar, Nripen Khilari, Pratiksha B. Ghanwat, Geethu Venugopal, Debasis Koley* and Sakya S. Sen*

Dalton Trans., 2024, 53, 10814-10818

Coinage metal-ethylene complexes of sterically demanding 1,10-phenanthroline ligands

Deepika V. Karade, Vo Quang Huy Phan and H. V. Rasika Dias*

Dalton Trans., 2024, 53, 10426-10433

Review on synthetic approaches and PEC activity performance of bismuth binary and mixed-anion compounds for potential applications in marine engineering

Jiaji Zhang, Bingchu Mei, Huiyu Chen and Zaichun Sun*

Dalton Trans., 2024, 53, 10376-10402

Deciphering the structure and potassium-ion transport mechanism of potassium borate glass

Lulu Song, Alex C. Hannon, Steve Feller, Ruirui Liu, Peyton McGuire, Bo Zhang, Yongquan Zhou, Wu Li* and Fayan Zhu*

Dalton Trans., 2024, 53, 10434-10445

Contrasting impact of coordination polyhedra and site symmetry on the electronic energy levels in nine-coordinated Eu(iii) and Sm(iii) crystals structures determined from single crystal luminescence spectra

Sabina Svava Mortensen, Villads R. M. Nielsen and Thomas Just Sørensen*

Dalton Trans., 2024, 53, 10079-10092

Elevating the energetic capabilities of metal coordination compounds by incorporating nitrate anions

Abhishek Kumar Yadav, Richa Rajak  and Srinivas Dharavath*

Dalton Trans., 2024, 53, 10093-10098

Extremely stable system of 1-haloselanyl-anthraquinones: experimental and theoretical investigations

Naoki Ogawa, Nobuhiro Suzuki, Yoshifumi Katsura, Mao Minoura, Waro Nakanishi and Satoko Hayashi*

Dalton Trans., 2024, 53, 10099-10112

Exploring the impact of various reducing agents on Cu nanocluster synthesis (Open Access)

Sourav Biswas and Yuichi Negishi*

Dalton Trans., 2024, 53, 9657-9663

Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd₃W₂ coordinated complexes (Open Access)

Francisco Reigosa, Paula M. Polo, M. Teresa Pereira and José M. Vila*

Dalton Trans., 2024, 53, 9680-9691

Coordinating nature of M₆L₁₂ double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(ii) ions

Seonghyeon An, Jihun Han, Dongwon Kim, Haeri Lee* and Ok-Sang Jung*

Dalton Trans., 2024, 53, 9692-9699

Transition metal complexes of the (2,2,2-trifluoroethyl)phosphinate NOTA analogue as potential contrast agents for ¹⁹F magnetic resonance imaging (Open Access)

Filip Koucký, Tereza Dobrovolná, Jan Kotek*, Ivana Císařová, Jana Havlíčková, Alan Liška, Vojtěch Kubíček and Petr Hermann

Dalton Trans., 2024, 53, 9267-9285

Impact of o-aryl halogen effects on ethylene polymerization: steric vs. electronic effects

Jianjian Dai and Shengyu Dai*

Dalton Trans., 2024, 53, 9286-9293

Soma–Iwamoto-type SCO complex Fe(quinazoline)₂[Au(CN)₂]₂ using the quinazoline-type ligand (Open Access)

Kosuke Kitase*, Daisuke Akahoshi and Takafumi Kitazawa

Dalton Trans., 2024, 53, 9248-9251

Towards structurally versatile mesoionic N-heterocyclic olefin ligands and their coordination to palladium, gold, and boron hydride (Open Access)

Tisa Ževart, Balazs Pinter, Matic Lozinšek, Damijana Urankar, Ross D. Jansen-van Vuuren and Janez Košmrlj*

Dalton Trans., 2024, 53, 8915-8925

Aggregation-induced enhanced fluorescence emission of chiral Zn(ii) complexes coordinated by Schiff-base type binaphthyl ligands

Daiki Tauchi, Katsuya Kanno, Masashi Hasegawa, Yasuhiro Mazaki, Kazunori Tsubaki, Ken-ichi Sugiura, Takuya Shiga, Seiji Mori and Hiroyuki Nishikawa*

Dalton Trans., 2024, 53, 8926-8933

Self-assembly of Ni(ii) with a chiral ligand pair vs. mixture of the chiral ligand pair: structural features and recognition ability of Ni₂L₄ cages

Jihun Han, Hyo Jeong Back, Mohammad M. Hossain, Ok-Sang Jung* and Young-A. Lee* 

Dalton Trans., 2024, 53, 8934-8939

Effective photosensitized emission of a Tb(iii) complex using a β-diketonate photosensitizer and an oxygen barrier system in a thermally populated triplet state (Open Access)

Kota Inage, Mengfei Wang, Yasuchika Hasegawa* and Yuichi Kitagawa*

Dalton Trans., 2024, 53, 8555-8562

Co₃O₄/activated carbon nanocomposites as electrocatalysts for the oxygen evolution reaction

Andrei F. V. de Lima, Annaíres de A. Lourenço, Vinícius D. Silva, André L. Menezes de Oliveira, Arpad M. Rostas, Lucian Barbu-Tudoran, Cristian Leostean, Ovidiu Pana, Rodolfo B. da Silva, Daniel A. Macedo and Fausthon F. da Silva*

Dalton Trans., 2024, 53, 8563-8575

Factors governing the protonation of Keggin-type polyoxometalates: influence of the core structure in clusters (Open Access)

Hiroshi Sampei, Hiromu Akiyama, Koki Saegusa, Masahiro Yamaguchi, Shuhei Ogo, Hiromi Nakai, Tadaharu Ueda* and Yasushi Sekine*

Dalton Trans., 2024, 53, 8576-8583

Low-temperature synthesis of porous high-entropy (CoCrFeMnNi)₃O₄ spheres and their application to the reverse water–gas shift reaction as catalysts (Open Access)

Ayano Taniguchi, Takeshi Fujita and Kazuya Kobiro*

Dalton Trans., 2024, 53, 8124-8134

Synthesis of amorphic and hexagonal boron nitride via high temperature treatment of NH₃BH₃ and Li(BH₃NH₂BH₂NH₂BH₃) 

A. Prus, R. Owarzany, D. Jezierski, K. Perkowski and K. J. Fijalkowski*

Dalton Trans., 2024, 53, 8135-8140

Enabling a bioinspired N,N,N-copper coordination motif through spatial control in UiO-67: synthesis and reactivity (Open Access)

Isabelle Gerz, Erlend S. Aunan, Valeria Finelli, Mouhammad Abu Rasheed, Gabriele Deplano, Rafael Cortez S. P., Inga L. Schmidtke, David S. Wragg, Matteo Signorile, Knut T. Hylland, Elisa Borfecchia, Karl Petter Lillerud, Silvia Bordiga*, Unni Olsbye* and Mohamed Amedjkouh*

Dalton Trans., 2024, 53, 8141-8153

Dual FGFR-targeting and pH-activatable ruthenium–peptide conjugates for targeted therapy of breast cancer (Open Access)

João Franco Machado, Marco Sá, Inês Pires, Miguel Tarita da Silva, Fernanda Marques, Jaime A. S. Coelho, Filipa Mendes, M. Fátima M. Piedade, Miguel Machuqueiro, María Angeles Jiménez, Maria Helena Garcia, João D. G. Correia* and Tânia S. Morais*

Dalton Trans., 2024, 53, 7682-7693

Interfacial engineering of a multijunctional In₂O₃/WO₃@Ti₄N₃T_x S-scheme photocatalyst with enhanced photoelectrochemical properties (Open Access)

Antony Okinyi Onjwaya, Majahekupheleni Livileyise Malati, Jane Catherine Ngila and Langelihle Nsikayezwe Dlamin*

Dalton Trans., 2024, 53, 7694-7710

Direct C–H electrophilic borylation with (C₆F₅)₂B–NTf₂ to generate B–N dibenzo[a,h]pyrenes

Tony Nguyen, Jason L. Dutton, Chia Yun Chang, Wen Zhou and  Warren E. Piers*

Dalton Trans., 2024, 53, 7273-7281

Iridium(iii)-based minor groove binding complexes as DNA photocleavage agents (Open Access)

Stephen O. Aderinto, Torsten John, Abdulmujeeb Onawole, Raphael Peter Galleh and Jim A. Thomas*

Dalton Trans., 2024, 53, 7282-7291

Effect of f-element complexation on the radiolysis of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP])

Stephen P. Mezyk*, Makayla Baxter, Cristian Celis-Barros, Travis S. Grimes, Peter R. Zalupski, Cathy Rae, Christopher A. Zarzana, Andrew R. Cook and Gregory P. Horne*

Dalton Trans., 2024, 53, 6881-6891

Barium phosphidoboranes and related calcium complexes (Open Access)

Gabriel Duneş, Peter M. Chapple, Samia Kahlal, Thierry Roisnel, Jean-François Carpentier, Jean-Yves Saillard* and Yann Sarazin*

Dalton Trans., 2024, 53, 6892-6905

Analyses of the electronic structures of FeFe-cofactors compared with those of FeMo- and FeV-cofactors and their P-clusters (Open Access)

Zhen-Lang Xie, Wan-Ting Jin and Zhao-Hui Zhou

Dalton Trans., 2024, 53, 6529-6536

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Steven R. Kidd, Wen Zhou, Jeffrey J. Warren* and Daniel B. Leznoff*

Dalton Trans., 2024, 53, 6537-6546

Amplified photomodulation of a bis(dithienylethene)-substituted phosphine (Open Access)

Anastasiia Sherstiuk, Marc Villabona, Agustí Lledós, Jordi Hernando*, Rosa María Sebastián and Evamarie Hey-Hawkins*

Dalton Trans., 2024, 53, 6190-6199

Hybridization of layered double hydroxides with functional particles

Rattanawadee Ploy Wijitwongwan, Soontaree Grace Intasa-ard and Makoto Ogawa*

Dalton Trans., 2024, 53, 6144-6156

Switching of magnetic properties by topotactic reaction in a 1D CN-bridged Ni(ii)–Nb(iv) system (Open Access)

Michał Heczko and Beata Nowicka*

Dalton Trans., 2024, 53, 5788-5795

Molybdenum-maltolate as a molybdopterin mimic for bioinspired oxidation reaction

Swapnil S. Pawar, Rohit N. Ketkar, Pranav B. Gaware, Kaustubh U. Jagushte, Divyani Dhawne, Shreyada N. Save, Shilpy Sharma, Ganga Periyasamy, Niyamat Chimthanawala, Sadhana Sathaye, Shreerang V. Joshi and Nabanita Sadhukhan*

Dalton Trans., 2024, 53, 5770-5774

Formation of N,N,N′,N′-tetramethylethylene diamine via coupling of the two charge reversed C–N bonds of Me3NO in the presence of an Eu(ii) bis(trimethylsilyl)amide complex

Yangjuan Li and Yu Gong*

Dalton Trans., 2024, 53, 5342-5345

Highly stable CsPbBr₃ perovskite phases from new lead β-diketonate glyme adducts (Open Access)

Lorenzo Sirna, Anna Lucia Pellegrino*, Salvatore Pio Sciacca, Martina Lippi, Patrizia Rossi, Carmela Bonaccorso, Giuseppe Bengasi, Marina Foti and Graziella Malandrino*

Dalton Trans., 2024, 53, 5360-5372

Bimetallic CPM-37(Ni,Fe) metal–organic framework: enhanced porosity, stability and tunable composition (Open Access)

Soheil Abdpour, Marcus N. A. Fetzer, Robert Oestreich, Thi Hai Yen Beglau, István Boldog* and Christoph Janiak*

Dalton Trans., 2024, 53, 4937-4951

Synthesis, characterization, and cancer cell-selective cytotoxicity of mixed-ligand cobalt(iii) complexes of 8-hydroxyquinolines and phenanthroline bases

Banashree Deka, Tukki Sarkar, Arnab Bhattacharyya*, Ray J. Butcher*, Samya Banerjee*, Sasanka Deka, Kandarpa K. Saikia* and Akhtar Hussain*

Dalton Trans., 2024, 53, 4952-4961

Recent developments in piezo-photocatalytic CO₂ reduction: concepts, mechanism, and advances

Atul Verma and Yen-Pei Fu*

Dalton Trans., 2024, 53, 4890-4899

A karst-inspired hierarchical Mg/Al layered double hydroxide with a high entropy-driven process for interception and storage

Hongyu Shi, Jun Qin*, Qing Lv, Lijin Zhang, Qingxin Li, Bin Ou and Xiaolang Chen*

Dalton Trans., 2024, 53, 4412-4425

Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae* and Makoto Moriya*

Dalton Trans., 2024, 53, 4426-4431

Intensity and lifetime ratiometric luminescent thermometer based on a Tb(iii) coordination polymer

Augusto Iwashita Costa, Rafaela M. R. da Silva, Luckerman D. G. Botelho, Sergio F. N. Coelho, Fernando A. Sigoli, João Honorato, Javier Ellena, Felipe T. Martins, Angelo M. Gomes, Wallace C. Nunes, Francesc Lloret, Miguel Julve and Maria Vanda Marinho*

Dalton Trans., 2024, 53, 3994-4004

Diversity of oxidation state in copper complexes with phenolate ligands

Tomoyuki Takeyama* and Yuichi Shimazaki*

Dalton Trans., 2024, 53, 3911-3929

On the mechanism of action of arsenoplatins: arsenoplatin-1 binding to a B-DNA dodecamer (Open Access)

Romualdo Troisi, Gabriella Tito, Giarita Ferraro, Filomena Sica, Lara Massai, Andrea Geri, Damiano Cirri, Luigi Messori and Antonello Merlino*

Dalton Trans., 2024, 53, 3476-3483

Fluoro-bridged rare-earth metal–organic frameworks

Muhammad Abbas, Simin Sheybani, Marie L. Mortensen and Kenneth J. Balkus, Jr.*

Dalton Trans., 2024, 53, 3445-3453

Diphosphene with a phosphineborane tether and its rhodium complex (Open Access)

Akihiro Tsurusaki*, Shingo Takechi and Ken Kamikawa*

Dalton Trans., 2024, 53, 2929-2936

Effect of substituents on the ¹O₂ production and biological activity of (N^N^N)Pt(py) complexes (Open Access)

Guillermo Romo-Islas, María Gil-Moles, Arnav Saxena, Antonio Frontera, M. Concepción Gimeno* and Laura Rodríguez*

Dalton Trans., 2024, 53, 2475-2486

X-ray crystallographic analysis of the antiferromagnetic low-temperature phase of galvinoxyl: investigating magnetic duality in organic radicals

Rie Suizu, Yoshiaki Shuku, Vincent Robert, Pablo Roseiro, Nadia Ben Amor, Zain Khawar, Neil Robertson and Kunio Awaga*

Dalton Trans., 2024, 53, 1961-1965

Synthesis of N-heterocyclic carbene gold(i) complexes from the marine betaine 1,3-dimethylimidazolium-4-carboxylate (Open Access)

Seyedeh Mahbobeh Mahdavi, Dirk Bockfeld, Rolf Büssing, Bianka Karge, Thomas Bannenberg, René Frank, Mark Brönstrup, Ingo Ott and Matthias Tamm*

Dalton Trans., 2024, 53, 1942-1946

Spin-state versatility in Fe ^II₄L₆ supramolecular cages with a pyridyl-hydrazone ligand scaffold modulated by solvents and counter anions

Weiyang Li, Xiaochun Li, Koen Robeyns, Mariusz Wolff, Joseph Kfoury, Julianna Oláh, Radovan Herchel, Serhiy Demeshko, Franc Meyer and Yann Garcia*

Dalton Trans., 2024, 53, 1449-1459

Ye Olde supramolecular chemistry, its modern rebranding and overarching trends in chemistry

Matteo Savastano

Dalton Trans., 2024, 53, 1373-1392

Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center

Yuto Suga and Yusuke Sunada*

Dalton Trans., 2024, 53, 862-865

Ordering by cation replacement in the system Na_2−xLi_xGa₇ (Open Access)

Chia-Chi Yu, Yurii Prots, Alim Ormeci, Mitja Krnel, Marcus Schmidt, Lev Akselrud, Frank R. Wagner, Yuri Grin and Michael Baitinger*

Dalton Trans., 2024, 53, 908-916

An effective visible-light driven fumarate production from gaseous CO₂ and pyruvate by the cationic zinc porphyrin-based photocatalytic system with dual biocatalysts (Open Access)

Mika Takeuchi and Yutaka Amao*

Dalton Trans., 2024, 53, 418-422

Fluorescence sensing and device fabrication with luminescent metal–organic frameworks

Ding-Gui Cai, Teng-Fei Zheng*, Sui-Jun Liu* and He-Rui Wen

Dalton Trans., 2024, 53, 394-409

Oxidation-derived anticancer potential of sumanene–ferrocene conjugates (Open Access)

Artur Kasprzak*, Agnieszka Zuchowska, Pawel Romanczuk, Agata Kowalczyk, Ireneusz P. Grudzinski, Anna Malkowska, Anna M. Nowicka and Hidehiro Sakurai

Dalton Trans., 2024, 53, 56-64

Lanthanide complexes facilitate wound healing by promoting fibroblast viability, migration and M2 macrophage polarization

Wajid Ali, Fatemeh Jamshidi-Adegani, Zahra Mirsanei, Juhaina Al-Kindi, Saeid Vakilian, Mohammed Al-Broumi, Sulaiman Al-Hashmi, Jeremy M. Rawson*, Ahmed Al-Harrasi* and Muhammad Usman Anwar*

Dalton Trans., 2024, 53, 65-73