A new class of variational states based on a tensor network approach is examined for application in transition metal chemistry.
New electron correlation theories for transition metal chemistry
Konrad H. Marti and Markus Reiher
Phys. Chem. Chem. Phys., 2011, DOI: 10.1039/C0CP01883J
Electronic structure theory faces many computational challenges in transition metal chemistry. Usually, density functional theory is the method of choice for theoretical studies on transition metal complexes and clusters mostly because it is the only feasible one, although its results are not systematically improvable. By contrast, multireference ab initio methods could provide a correct description of the electronic structure, but are limited to small molecules because of the tremendous computational resources required. In recent years, conceptually new ab initio methods emerged that turned out to be promising for theoretical coordination chemistry.
Two efficient parametrization schemes are discussed for the electronic wave function, the matrix product states and the complete-graph tensor network states. Their advantages are demonstrated at example transition metal complexes. Especially, tensor network states might provide the key to accurately describe strongly correlated and magnetic molecular systems in transition metal chemistry.
Comparing the experimental emission bands with those predicted by the model, a semi-quantitative picture of the magnetic field effect has been developed.
The hydrogen exchange reaction H + H2 -> H2 + H is the simplest neutral bimolecular reaction and for nearly a century has been a benchmark for studying reaction dynamics.
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