Exploring exciplex forming donor–acceptor systems

‘HOT’ paper – magnetic field effects

In this paper, the magnetic field effects on the exciplex and locally excited fluorophore emission are explored. The results confirm reversibility in the excited state and the novel three-state model is also used to rationalize the extent of the magnetic field effects for different energetic situations.

magnetic field effectsComparing the experimental emission bands with those predicted by the model, a semi-quantitative picture of the magnetic field effect has been developed.

Magnetic field effects on exciplex-forming systems: the effect on the locally excited fluorophore and its dependence on free energy
Daniel R. Kattnig, Arnulf Rosspeintner and Günter Grampp
Phys. Chem. Chem. Phys., 2011, DOI: 10.1039/C0CP01517B

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