Organic Chemistry Frontiers Blog

Organic Chemistry Frontiers is delighted to share with you the HOT articles of October 2016!

You can access these publications for free till 15^th Dec by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion
Zhen Liu, Ying Xia, Sheng Feng, Yan Zhang and Jianbo Wang
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00453A, Research Article

[2.2]Paracyclophane-based N-heterocyclic carbene as efficient catalyst or as ligand for copper catalyst for asymmetric α-silylation of N-tosylaldimines
Zhen Chen, Yuwen Huo, Ping An, Xichao Wang, Chun Song and Yudao Ma
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00386A, Research Article

Suzuki coupling for preparation of allenes – ligand effects and chirality transfer
Hongwen Luo, Yihua Yu and Shengming Ma
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00489J, Research Article

The facile and stereoselective synthesis of pyrrolidine β-amino acids via copper(I)-catalyzed asymmetric 1,3-dipolar cycloaddition
Fu-Sheng He, Cong-Shan Li, Hua Deng, Xing Zheng, Zhong-Tao Yang and Wei-Ping Deng
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00512H, Research Article

Organic Chemistry Frontiers is delighted to share with you the HOT articles of September 2016!

You can access these publications for free till 30^th Nov by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Facile synthesis of annulated heterocyclic benzo[kl]acridine derivatives via one-pot N–H/C–H coupling
Yulian Zagranyarski, Artem Skabeev, Yingjie Ma, Klaus Müllen and Chen Li
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00371K, Tutorial Account

Organic Chemistry Frontiers is delighted to share with you the HOT articles of August 2016!

You can access these publications for free till 31^st Oct by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Switching between intermolecular and intramolecular reactions using flow microreactors: lithiation of 2-bromo-2′-silylbiphenyls
A. Nagaki, S. Kim, N. Miuchi, H. Yamashita, K. Hirose and J. Yoshida
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00257A, Research Article

A new approach toward the synthesis of 2,4-bis(fluoroalkyl)-substituted quinoline derivatives using fluoroalkyl amino reagent chemistry
Fallia Aribi, Etienne Schmitt, Armen Panossian, Jean-Pierre Vors, Sergiy Pazenok and Frédéric R. Leroux
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00319B, Research Article

Synthesis of 2,3-dihydrobenzofurans via the palladium catalyzed carboalkoxylation of 2-allylphenols
Johnathon T. Hutt and John P. Wolfe
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00215C, Research Article

Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions
Daisuke Yamamoto, Masayuki Soga, Hiromasa Ansai and Kazuishi Makino
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00318D, Research Article

Organic Chemistry Frontiers is delighted to share with you the HOT articles of July 2016!

You can access these publications for free till 14^th Sep by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Catalytic asymmetric direct-type 1,4-addition reactions of simple esters
Io Sato, Hirotsugu Suzuki, Yasuhiro Yamashita and Shū Kobayashi
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00242K, Research Article

Considering organic mechanisms and the optimization of current flow in an electrochemical oxidative condensation reaction
Derek T. Rensing, Bichlien H. Nguyen and Kevin D. Moeller
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00248J, Research Article

Iterative catalyst controlled diastereodivergent synthesis of polypropionates
D. Roke, M. Fañanás-Mastral and B. L. Feringa
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00199H, Research Article

Approach to the synthesis of the C1–C11 and C14–C18 portion of Leucascandrolide A
T. J. Hunter, J. Zheng and G. A. O’Doherty
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00284F, Research Article

Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions
Zhongzheng Gao, Jing Zhang, Nana Sun, Ying Huang, Zhu Tao, Xin Xiao and Jianzhuang Jiang
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00310A, Research Article 

Organic Chemistry Frontiers is delighted to share with you the HOT articles of June 2016!

You can access these publications for free till 14^th Aug by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Stimuli-responsive supramolecular gel constructed by pillar[5]arene-based pseudo[2]rotaxanes via orthogonal metal–ligand coordination and hydrogen bonding interaction
Xuan Wu, Ying Yu, Lei Gao, Xiao-Yu Hu and Leyong Wang
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00197A, Research Article

Reaction of alkenecarboxylic acids with isocyanates via rhodium(III)-catalyzed C–H activation: a versatile route to cyclic imides
You-Quan Zhu, Yun Liu, Hai ning Wang, Wen bo Liu and Chao-Jun Li
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00119J, Research Article

Bismuth(III) triflate-catalysed tandem cyclisations towards complex polycyclic ethers
Pierrick Ondet, Luisa Lempenauer, Elisabet Duñach and Gilles Lemière
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00212A, Research Article

Pd(II)-catalyzed direct functionalization of C–H bonds of benzamides for synthesis of 1,1-difluoro-1-alkenes
Chunpu Li, Dengyou Zhang, Wei Zhu, Penghui Wan and Hong Liu
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00178E, Research Article

Organic Chemistry Frontiers is delighted to share with you the HOT articles of May 2016!

You can access these publications for free till 31th July by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with N-allenyl oxazolidinone
Haoxiang Hu, Yidong Wang, Deyun Qian, Zhan-Ming Zhang, Lu Liu and Junliang Zhang
Org. Chem. Front., 2016,3, 759-763
DOI: 10.1039/C6QO00087H

Catalytic asymmetric α-amination of β-keto esters and β-keto amides with a chiral N,N′-dioxide–copper(I) complex
Xiao Xiao, Lili Lin, Xiangjin Lian, Xiaohua Liu and Xiaoming Feng
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00095A

Synthesis of 2,5-disubstituted pyrroles via dehydrogenative condensation of secondary alcohols and 1,2-amino alcohols by supported platinum catalysts
S. M. A. H. Siddiki, Abeda S. Touchy, Chandan Chaudhari, Kenichi Kon, Takashi Toyao and Ken-ichi Shimizu
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00165C

A general photoinduced electron transfer-directed chemoselective perfluoroalkylation of N,N-dialkylhydrazones
Jin Xie, Jian Li, Thomas Wurm, Vanessa Weingand, Hui-Ling Sung, Frank Rominger, Matthias Rudolph and A. Stephen K. Hashmi
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00158K

Metal-free borylation of electron-rich aryl (pseudo)halides under continuous-flow photolytic conditions
Kai Chen, Man Sing Cheung, Zhenyang Lin and Pengfei Li
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00109B

Synthesis of trifluoromethylthiolated azacalix[1]arene[3]pyridines from the Cu(II)-mediated direct trifluoromethylthiolation reaction of arenes via reactive arylcopper(III) intermediates
Fei Wang, Liang Zhao, Jingsong You and Mei-Xiang Wang
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00161K

Organic Chemistry Frontiers is delighted to share with you the HOT articles of April 2016!

You can access these publications for free till 30^th June by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Copper(I)-catalyzed sulfonylation of (2-alkynylaryl)boronic acids with DABSO
Runyu Mao, Danqing Zheng, Hongguang Xia and Jie Wu
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00070C

Synthesis of carbamates from amines and N-tosylhydrazones under atmospheric pressure of carbon dioxide without an external base
Ji Young Hong, Ue Ryung Seo and Young Keun Chung
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00111D

Organic Chemistry Frontiers is delighted to share with you the HOT articles of March 2016!

You can access these publications for free till 31^st May by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Generation of N-aminosulfonamides via a photo-induced fixation of sulfur dioxide into aryl/alkyl halides
Yuewen Li, Danqing Zheng, Zhenhua Li and Jie Wu
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00060F, Research Article

C(sp³)–H bond functionalization by sequential hydride transfer/cyclization: electronic effect and steric effect controlled regioselectivity
Liang Wang and Jian Xiao
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C6QO00043F, Highlight

Organic Chemistry Frontiers is delighted to share with you the HOT articles of February 2016!

Visible-light promoted intermolecular halofunctionalization of alkenes with N-halogen saccharins
Lu Song, Sanzhong Luo and Jin-Pei Cheng
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C5QO00432B

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Epoxy and aziridinyl enolsilanes in diastereoselective inter- and intramolecular Friedel–Crafts alkylations
Jesse Ling, Sze Kui Lam, Brian Lo, Sarah Lam, Wing-Tak Wong, Jian Sun, Guanhua Chen and Pauline Chiu
Org. Chem. Front., 2016, Advance Article
DOI: 10.1039/C5QO00333D