Parallelogram shaped nanowires control light in two dimensions

Table of contents imageA novel zinc oxide microwire optical resonator with parallelogram-shaped cross section has been made by chemists based in China and Taiwan. The material can effectively control light in two dimensions, and could play the part of a building block in the development of optoelectronic devices.

Read this HOT Nanoscale communication today:

Optical modulation of ZnO microwire optical resonators with a parallelogram cross-section
Yang Liu, Hongxing Dong, Shulin Sun, Wenhui Liu, Jinxin Zhan, Zhanghai Chen, Jun Wang and Long Zhang
DOI: 10.1039/C3NR00700F

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New Nanoscale Associate Editor: Prof. Dirk Guldi

Dirk Guldi Nanoscale Associate Editor

We are delighted to welcome Professor Dirk Guldi as a new Associate Editor for Nanoscale. Professor Guldi is one of the world-leading scientists in the field of charge transfer/nanocarbons. In particular, he is well-known for his contributions to the areas of charge-separation in donor-acceptor materials and construction of nanostructured thin films for solar energy conversion.Nanoscale

His research at the Friedrich Alexander University of Erlangen-Nuremberg involves the application of an arsenal of spectroscopic and microscopic techniques to a variety of molecular systems designed specifically to explore the nature of the chemical, physical and photophysical properties of new molecular hybrids, quantum dots, quantum rods and nanoparticles. He is also interested in designing and synthesising novel nanometer scale structures in combination with electron donors as integrative components for electron-donor-acceptor ensembles.

Prof. Guldi is handling papers and so we encourage you to submit to his editorial office.

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Get Funded To Visit Chinese Universities

If you wish to create new research collaborations with Chinese Universities, you can now apply for the RSC-SAFEA visiting researcher programme.

Call for applications are open until the 20th May 2013.

Please email: international@rsc.org to register your interest in participating in the programme. Read more from previous researchers who have participated in this programme in 2010-2012 http://my.rsc.org/blogs/74.

RSC Visiting Researcher Programme ChinaThe State Administration for Foreign Experts Affairs (SAFEA) is a division of the Chinese Government with which RSC has a cooperation agreement. Under this agreement the RSC and SAFEA will jointly fund researchers from the UK to visit Chinese Universities. The purpose of the visits is to stimulate collaboration between UK and Chinese institutions. They will allow the visitor to contribute their experience towards the development of excellent emerging science and build links with the Chinese Chemistry community.

In addition, the visitor will advise Chinese research groups on all aspects of presenting their research to an international audience. The programme will strengthen links between the UK and Chinese Science and between the RSC and our partners in China.

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Nanoscale article in Chemistry World: Nanopaper light scattering under control

Transparent nanopaper with tailored optical propertiesCollaborators in the US and China have demonstrated that by changing the diameter of cellulose fibres in nanopaper they can tailor its optical properties for use in optoelectronics.

In this work, Zhichao Ruan from Zhejiang University and Liangbing Hu from the University of Maryland have looked at the effect of changing the fibre diameter and packing density in transparent nanopaper. ‘Specular transmittance measures light in the normal direction, whereas diffusive transmittance refers to the forward direction’ explains Hu. ‘As the fibre diameter decreases, the overall transmittance, including both specular and diffusive transmittance, increases. But the difference between the two, which is related to the haze of the nanopaper, starts to decrease.’

Read the full article in Chemistry World!

Read the article in Nanoscale:

Transparent nanopaper with tailored optical properties
Hongli Zhu, Sepideh Parvinian, Colin Preston, Oeyvind Vaaland, Zhichao Ruan and Liangbing Hu
DOI: 10.1039/C3NR00520H

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Strong composite films from silk fibroin and graphene oxide

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels

Gaoquan Shi and co-workers have made composite films comprising graphene oxide sheets and silk fibroin in a layered structure, which mimic natural nacre. They demonstrate a facile solution-casting method for incorporating the fibroin into graphene oxide.

The impressive mechanical properties of their material, surpassing those of natural nacre in some ways, make it potentially useful as a high-strength structural material. The biocompatibility of the material components also makes the composite promising for biological applications, such as tissue engineering.

Read this HOT article today:

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels
Liang Huang, Chun Li, Wenjing Yuan and Gaoquan Shi
DOI: 10.1039/C3NR00196B

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Full camouflage for stealth nanoparticles

‘Marker-of-self’ functionalization of nanoscale particles through a top-down cellular membrane coating approachCamouflaging nanoparticles so that they are not attacked by the immune system is a major challenge in developing long-circulating, effective drug-delivery vehicles. Attaching CD47, a transmembrane protein that serves as a universal molecular ‘marker-of-self’, to the surface of nanoparticles is one way to enable active immune evasion. However, functionalising the particle surface evenly and with uniformly oriented protein is very difficult.

Liangfang Zhang et al. show that their membrane translocation approach is very effective for functionalizing nanoparticles with molecules of CD47 in their recent Nanoscale Communication. They were able to coat nanoparticles with immunomodulatory proteins at an equivalent density to those on red blood cells, and in the correct orientation.

Read this HOT article today:

‘Marker-of-self’ functionalization of nanoscale particles through a top-down cellular membrane coating approach
Che-Ming J. Hu, Ronnie H. Fang, Brian T. Luk, Kevin N. H. Chen, Cody Carpenter, Weiwei Gao, Kang Zhang and Liangfang Zhang
DOI: 10.1039/C3NR00015J

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An exciting new anode material with impressive properties for high-performance lithium-ion batteries

Lixia Yuan, Yunhui Huang and co-workers report a simple one-pot method to synthesize a nanocluster composite assembled by interconnected ultrafine  SnO2@C nanospheres in their recent Nanoscale paper. They found that with a mixture of sodium carboxyl methyl cellulose and styrene butadiene rubber as a binder, the SnO2@C nanocluster anode exhibits superior cycling stability and rate capability.

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries

Electrode materials are crucial for the overall performance of lithium ion batteries. Graphite is a traditionally used anode material, and tin dioxide is one promising alternative with a higher theoretical lithium storage capacity. However, the practical use of tin dioxide is limited by its rapid capacity fading, low initial coulombic efficiency and poor rate performance. Scientists from China have recently come up with a clever solution to these problems by skilfully combining SnO2@C nanoclusters with a suitable binder.

Read this HOT article today:

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries
Min He, Lixia Yuan, Xianluo Hu, Wuxing Zhang, Jie Shu and Yunhui Huang
DOI: 10.1039/C3NR34133J

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Nanoparticle system for simultaneous drug delivery and biomedical imaging

Lee Barrett is a guest web-writer for Nanoscale. He is currently a post-doctoral researcher at the University of Strathclyde, UK.

Huanxin Cai and Ping Yao, from Fudan University, have developed a facile and green approach for the synthesis of gold nanoparticle conjugates prepared from a lys-dex nangel, comprising a lysozyme core with a dextran shell. The Au@lys-dex nangels loaded with doxorubicin show the same antitumour activity as free doxorubicin, showing the potential of the nanogels for drug delivery applications.

Table of contents imageThe lys-dex conjugates were spherical in shape with a hydrodynamic radius of 200 nm.  Due to the stability of the lys-dex nanogels against changes in pH and ionic strength, in addition to the net positive charge of the lys core produced at pH < 10.7, the nanogels are a suitable substrate for the synthesis of gold nanoparticles.

By mixing the lys-dex nanogel and chloroauric acid at pH 4, gold nanoparticles can be synthesized by inducing the reduction of Au3+ using UV photo-irradiation.  The synthesis process was monitored by UV-Vis spectroscopy indicating that 2 hours of UV-irradiation is sufficient to produce gold nanoparticles with a surface plasmon band centered at 536 nm.   The authors report that the gold nanoparticle morphology can be controlled by altering the pH of the reaction, thereby leading to nanoparticles with sizes of 11, 8 and 4 nm at pH 2, 4 and 6, respectively.

Due to the plasmonic properties of the nanoparticles, the Au@lys-dex nanogels can also be used as contrast agents for optical microscopy imaging.  The authors have therefore devised a nanoparticle system for simultaneous drug delivery and biomedical imaging applications.

by Dr Lee Barrett

Read the full details of this HOT Nanoscale paper today:

In situ preparation of gold nanoparticle-loaded lysozyme–dextran nanogels and applications for cell imaging and drug delivery
Huanxin Cai and Ping Yao
DOI: 10.1039/C3NR00178D

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Top 10 most-read Nanoscale articles in January

This month sees the following articles in Nanoscale that are in the top ten most accessed for January:

Nanostructured carbon–metal oxide composite electrodes for supercapacitors: a review 
Mingjia Zhi ,  Chengcheng Xiang ,  Jiangtian Li ,  Ming Li and Nianqiang Wu  
Nanoscale, 2013,5, 72-88 
DOI: 10.1039/C2NR32040A 

Graphene transfer: key for applications 
Junmo Kang ,  Dolly Shin ,  Sukang Bae and Byung Hee Hong 
Nanoscale, 2012,4, 5527-5537 
DOI: 10.1039/C2NR31317K 

Recent advances in the efficient reduction of graphene oxide and its application as energy storage electrode materials 
Tapas Kuila ,  Ananta Kumar Mishra ,  Partha Khanra ,  Nam Hoon Kim and Joong Hee Lee  
Nanoscale, 2013,5, 52-71 
DOI: 10.1039/C2NR32703A 

Graphene synthesis: relationship to applications 
Rebecca S. Edwards and Karl S. Coleman  
Nanoscale, 2013,5, 38-51 
DOI: 10.1039/C2NR32629A 

Upconversion nanoparticles and their composite nanostructures for biomedical imaging and cancer therapy 
Liang Cheng ,  Chao Wang and Zhuang Liu  
Nanoscale, 2013,5, 23-37 
DOI: 10.1039/C2NR32311G 

Core–shell sulfur@polypyrrole composites as high-capacity materials for aqueous rechargeable batteries 
Jie Shao ,  Xinyong Li ,  Li Zhang ,  Qunting Qu and Honghe Zheng  
Nanoscale, 2013,5, 1460-1464 
DOI: 10.1039/C2NR33590E 

Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene 
Yi Lin and John W. Connell  
Nanoscale, 2012,4, 6908-6939 
DOI: 10.1039/C2NR32201C 

Magnetic Fe3O4–graphene composites as targeted drug nanocarriers for pH-activated release 
Xiujuan Fan ,  Guozheng Jiao ,  Wei Zhao ,  Pengfei Jin and Xin Li  
Nanoscale, 2013,5, 1143-1152 
DOI: 10.1039/C2NR33158F 

Dopamine as the coating agent and carbon precursor for the fabrication of N-doped carbon coated Fe3O4 composites as superior lithium ion anodes 
Cheng Lei ,  Fei Han ,  Duo Li ,  Wen-Cui Li ,  Qiang Sun ,  Xiang-Qian Zhang and An-Hui Lu  
Nanoscale, 2013,5, 1168-1175 
DOI: 10.1039/C2NR33043A 

Self-assembly of hierarchical star-like Co3O4 micro/nanostructures and their application in lithium ion batteries 
Li Li ,  Kuok Hau Seng ,  Zhixin Chen ,  Zaiping Guo and Hua Kun Liu  
Nanoscale, 2013,5, 1922-1928 
DOI: 10.1039/C2NR33223J 

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Nanoscale? Then why not submit to us today!

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Making temperature sensitive porous nanolayers

A method of manufacturing porous nanolayers using temperature sensitive substrates has been developed by scientists working in Germany.

Traditionally such materials are made using flame spray pyrolysis (FSP), but this process is limited by the thermal sensitivity of the substrate onto which the nanoparticles are coated. Furthermore the mechanical stability of the layers is often weak in liquid environments.

The new process involves separating the pyrolysis step from the introduction of the final substrate material. In stage one the nanoparticles (eg titanium dioxide) are coated onto an initial substrate, using FSP, to create an intermediate porous nanolayer material. In stage two a new substrate is applied to the intermediate material to create a ‘nanoparticle sandwich’, which is passed through rollers under pressure and at low temperature. The nanoparticle layer transfers to the new substrate to yield the final material.

The technique produces materials that have superior mechanical stability, and opens up the possibility of using different substrates, such as polypropylene foil.

Read this HOT Nanoscale article today:

Transfer of highly porous nanoparticle layers to various substrates through mechanical compression
Sven Oliver Schopf, Samir Salameh and Lutz Mädler
DOI: 10.1039/C3NR34235B

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