Archive for the ‘Nanoscale’ Category

Origami electronics for foldable devices

Researchers from Osaka University, Japan, have developed foldable nanopaper antennas by fabricating a cellulose nanofiber substrate and imprinting silver nanowires on the surface.

The authors compiled nanopaper sheets from nanofibrillated pulp fibers, without conventional high pressure processing, to produce sheets with diameters ranging from 15 to 60 nm and a high smoothness of 0.16 μm.  The nanopaper surfaces were found to be 15-80 times smoother than pulp papers – a quality required for effective electrical properties in devices.  The silver nanowires were synthesized by reducing silver nitrate in the presence of PVP in ethylene glycol.  This produced silver nanowires 100 nm in diameter with lengths of between 5-10 μm.  The nanowires were mixed with ethylene glycol to produce pastes, which were subsequently mask-printed onto the nanopaper substrate.

To test the durability of the nanopaper-silver nanowire devices, the authors folded the paper into origami cranes, which was used to power an LED light.  This demonstrated that, even with multiple folding, the nanopaper devices retain their electrical properties more consistently than folded pulp papers.  This research has demonstrated, for the first time, that durable folded nanopaper devices with printed silver nanowire antennas can be easily and reproducibly fabricated.  The authors envisage these antennas could herald a new wave of foldable electronic devices, such as those used in smart phones and laptop computers.

by Dr Lee Barrett

Read this HOT Nanoscale article in full:

Foldable nanopaper antennas for origami electronics
Masaya Nogi, Natsuki Komoda, Kanji Otsuka and Katsuaki Suganuma
DOI: 10.1039/C3NR00231D

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Formamide used to directly synthesis hydrophilic nanocrystals

Scientists from Tsinghua University in China have found a way to synthesis water soluble nanocrystals with sizes smaller than 10nm using a formamide solvent-system.

So far, many groups have been successful in synthesising hydrophobic nanocrystals, but their inability to disperse in water has hindered their applications in electronics, catalysis and biomedicine. Hydrophobic nanocrystals can be made hydrophilic by using ligands to modify the surface, although these post-synthesis treatments are usually time-consuming and not environmentally friendly.  Wang and co-workers have solved these problems with their direct synthesis of water-soluble nanocrystals, which does not use toxic solvents and has no need for post-modifications.

Read this HOT article today:

Formamide: an efficient solvent to synthesize water-soluble, sub-10-nanometer nanocrystals
Xun Wang, Biao Xu and Zhi Cheng Zhang
DOI: 10.1039/C3NR00643C

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Nanoscale article in Chemistry World: Biomimetic bricks inspired by mother of pearl

© Shutterstock

Chinese chemists have developed a new nacre-like material which is stronger than natural nacre and most other composites.

Nacre, which is also known as mother of pearl, is a naturally occurring composite formed from calcium carbonate and biopolymers that create a brickwork structure. It is also nearly a thousand times stronger than any of its component parts and a major target for biomimetic synthesis.

Design of the brickwork structure is central to developing nacre-like materials with enhanced properties. Gaoquan Shi, and colleagues, at Tsinghua University, Beijing, began by making a hydrogel from graphene and a silk protein, called fibroin.

Read the article in Nanoscale:

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels
Liang Huang ,  Chun Li ,  Wenjing Yuan and Gaoquan Shi
DOI: 10.1039/C3NR00196B

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Parallelogram shaped nanowires control light in two dimensions

Table of contents imageA novel zinc oxide microwire optical resonator with parallelogram-shaped cross section has been made by chemists based in China and Taiwan. The material can effectively control light in two dimensions, and could play the part of a building block in the development of optoelectronic devices.

Read this HOT Nanoscale communication today:

Optical modulation of ZnO microwire optical resonators with a parallelogram cross-section
Yang Liu, Hongxing Dong, Shulin Sun, Wenhui Liu, Jinxin Zhan, Zhanghai Chen, Jun Wang and Long Zhang
DOI: 10.1039/C3NR00700F

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New Nanoscale Associate Editor: Prof. Dirk Guldi

Dirk Guldi Nanoscale Associate Editor

We are delighted to welcome Professor Dirk Guldi as a new Associate Editor for Nanoscale. Professor Guldi is one of the world-leading scientists in the field of charge transfer/nanocarbons. In particular, he is well-known for his contributions to the areas of charge-separation in donor-acceptor materials and construction of nanostructured thin films for solar energy conversion.Nanoscale

His research at the Friedrich Alexander University of Erlangen-Nuremberg involves the application of an arsenal of spectroscopic and microscopic techniques to a variety of molecular systems designed specifically to explore the nature of the chemical, physical and photophysical properties of new molecular hybrids, quantum dots, quantum rods and nanoparticles. He is also interested in designing and synthesising novel nanometer scale structures in combination with electron donors as integrative components for electron-donor-acceptor ensembles.

Prof. Guldi is handling papers and so we encourage you to submit to his editorial office.

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Get Funded To Visit Chinese Universities

If you wish to create new research collaborations with Chinese Universities, you can now apply for the RSC-SAFEA visiting researcher programme.

Call for applications are open until the 20th May 2013.

Please email: international@rsc.org to register your interest in participating in the programme. Read more from previous researchers who have participated in this programme in 2010-2012 http://my.rsc.org/blogs/74.

RSC Visiting Researcher Programme ChinaThe State Administration for Foreign Experts Affairs (SAFEA) is a division of the Chinese Government with which RSC has a cooperation agreement. Under this agreement the RSC and SAFEA will jointly fund researchers from the UK to visit Chinese Universities. The purpose of the visits is to stimulate collaboration between UK and Chinese institutions. They will allow the visitor to contribute their experience towards the development of excellent emerging science and build links with the Chinese Chemistry community.

In addition, the visitor will advise Chinese research groups on all aspects of presenting their research to an international audience. The programme will strengthen links between the UK and Chinese Science and between the RSC and our partners in China.

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Nanoscale article in Chemistry World: Nanopaper light scattering under control

Transparent nanopaper with tailored optical propertiesCollaborators in the US and China have demonstrated that by changing the diameter of cellulose fibres in nanopaper they can tailor its optical properties for use in optoelectronics.

In this work, Zhichao Ruan from Zhejiang University and Liangbing Hu from the University of Maryland have looked at the effect of changing the fibre diameter and packing density in transparent nanopaper. ‘Specular transmittance measures light in the normal direction, whereas diffusive transmittance refers to the forward direction’ explains Hu. ‘As the fibre diameter decreases, the overall transmittance, including both specular and diffusive transmittance, increases. But the difference between the two, which is related to the haze of the nanopaper, starts to decrease.’

Read the full article in Chemistry World!

Read the article in Nanoscale:

Transparent nanopaper with tailored optical properties
Hongli Zhu, Sepideh Parvinian, Colin Preston, Oeyvind Vaaland, Zhichao Ruan and Liangbing Hu
DOI: 10.1039/C3NR00520H

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Strong composite films from silk fibroin and graphene oxide

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels

Gaoquan Shi and co-workers have made composite films comprising graphene oxide sheets and silk fibroin in a layered structure, which mimic natural nacre. They demonstrate a facile solution-casting method for incorporating the fibroin into graphene oxide.

The impressive mechanical properties of their material, surpassing those of natural nacre in some ways, make it potentially useful as a high-strength structural material. The biocompatibility of the material components also makes the composite promising for biological applications, such as tissue engineering.

Read this HOT article today:

Strong composite films with layered structures prepared by casting silk fibroin–graphene oxide hydrogels
Liang Huang, Chun Li, Wenjing Yuan and Gaoquan Shi
DOI: 10.1039/C3NR00196B

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Full camouflage for stealth nanoparticles

‘Marker-of-self’ functionalization of nanoscale particles through a top-down cellular membrane coating approachCamouflaging nanoparticles so that they are not attacked by the immune system is a major challenge in developing long-circulating, effective drug-delivery vehicles. Attaching CD47, a transmembrane protein that serves as a universal molecular ‘marker-of-self’, to the surface of nanoparticles is one way to enable active immune evasion. However, functionalising the particle surface evenly and with uniformly oriented protein is very difficult.

Liangfang Zhang et al. show that their membrane translocation approach is very effective for functionalizing nanoparticles with molecules of CD47 in their recent Nanoscale Communication. They were able to coat nanoparticles with immunomodulatory proteins at an equivalent density to those on red blood cells, and in the correct orientation.

Read this HOT article today:

‘Marker-of-self’ functionalization of nanoscale particles through a top-down cellular membrane coating approach
Che-Ming J. Hu, Ronnie H. Fang, Brian T. Luk, Kevin N. H. Chen, Cody Carpenter, Weiwei Gao, Kang Zhang and Liangfang Zhang
DOI: 10.1039/C3NR00015J

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An exciting new anode material with impressive properties for high-performance lithium-ion batteries

Lixia Yuan, Yunhui Huang and co-workers report a simple one-pot method to synthesize a nanocluster composite assembled by interconnected ultrafine  SnO2@C nanospheres in their recent Nanoscale paper. They found that with a mixture of sodium carboxyl methyl cellulose and styrene butadiene rubber as a binder, the SnO2@C nanocluster anode exhibits superior cycling stability and rate capability.

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries

Electrode materials are crucial for the overall performance of lithium ion batteries. Graphite is a traditionally used anode material, and tin dioxide is one promising alternative with a higher theoretical lithium storage capacity. However, the practical use of tin dioxide is limited by its rapid capacity fading, low initial coulombic efficiency and poor rate performance. Scientists from China have recently come up with a clever solution to these problems by skilfully combining SnO2@C nanoclusters with a suitable binder.

Read this HOT article today:

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries
Min He, Lixia Yuan, Xianluo Hu, Wuxing Zhang, Jie Shu and Yunhui Huang
DOI: 10.1039/C3NR34133J

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