Archive for April, 2025

Turning Plastic Waste into Hydrogen: Clean and Green

To combat climate change, we must reduce carbon footprints either through waste reduction or renewable energy. Plastic waste is a significant challenge, with millions of tons ending up in landfills and oceans each year. Thus, it is of immense importance to reduce or recycle plastic waste, or even convert it to useful materials. In a recent study, Z. Qiang et al. show how upcycled plastics, like polyethylene and polypropylene, can be converted into energy-efficient heating elements for clean hydrogen production, tackling both waste reduction and recycling issues simultaneously (Illustrated in Figure 1A). The key innovation in this study lies in transforming discarded plastic into a special kind of carbon material by a combination of techniques, including 3D printing, crosslinking, and pyrolysis (a high-heat process that breaks down materials) to turn plastics into a highly efficient heating element (Figure 1B). The plastic waste is first printed into 3D structures, then chemically treated to make it stronger. Finally, it’s heated to the point where it becomes carbon. This carbon material can then be used as both a catalyst support and a heater in ammonia decomposition for producing hydrogen without harmful emissions (Figure 1C). This simple carbon-based Joule heater heats up when electricity passes through it and is a more efficient method than traditional convection heaters, while offering quicker start-up and shutdown times. That’s a game-changer when it comes to making hydrogen production faster and more energy-efficient.

Figure 1: (A) Illustration demonstrating the upcycling of recycled mixed polyolefin waste to carbon-based Joule heaters for hydrogen production. (B) Mixed waste compounded into 3D-printing filament, and FFF-printed into structured parts turning into structured carbon and connected to a power source to demonstrate Joule heating capabilities. (C) Waste-derived carbons impregnated with Ru-based catalysts for Joule heating-enabled NH3 decomposition for hydrogen production. (D) The global warming impact of furnace heating and Joule heating for ammonia decomposition at different temperatures. (E) The global warming impact of ammonia decomposition by Joule heating (blue bars) versus conventional furnace heating (red line) for various energy sources. Reproduced from DOI: 10.1039/d4mh01755b with permission from the Royal Society of Chemistry.

So basically, the Joule heating isn’t just about generating heat—it’s about doing it in a cleaner, smarter way. Traditional methods of heating can be energy-hungry and slow but using electricity to directly heat materials through Joule heating is much more efficient. In the study, this improved heating method sped up the ammonia decomposition process, allowing for faster hydrogen production. Even better, the process also reduces carbon emissions and energy use compared to conventional methods (Figure 1D, E). That means we can make hydrogen in a cleaner, more sustainable way, helping to reduce our reliance on fossil fuels. The exciting thing about this study is a double win for the planet. On one side, it helps address the massive problem of plastic waste by turning it into something useful. On the other side, it helps create hydrogen, a clean energy source to power everything from vehicles to industrial processes, without any harmful emissions, which paves the way towards zero carbon footprint.

It will be more interesting to see if this approach could also be used in other industries beyond hydrogen production. For instance, replacing the old, carbon-intensive heating systems used in manufacturing with these waste-derived Joule heaters could save massive energy consumption and reduce enormous emissions. Therefore, this research is a big step to address the real-world problem of waste, which will be no longer a problem, but a resource. By linking energy production with material recycling, we can close the loop on waste and make industries cleaner and more efficient. However, it would be preliminary to expect its use at larger scale in various energy sectors. Challenges like ensuring consistent carbon material properties at large scale, long-term thermal stability under high temperatures, and seamless integration with existing hydrogen production systems could be challenging.

To find out more, please read:

Upcycling of mixed polyolefin wastes to 3D structured carbon Joule heaters for decarbonized hydrogen production
Anthony Griffin, Jiachun Wu, Adam Smerigan, Paul Smith, Gbadeoluwa Adedigba, Rui Shi, Yizhi Xiang and Zhe Qiang
Mater. Horiz., 2025, Advance Article


About the blogger


 

Dr. Shahid Zaman is postdoctoral fellow at the Hydrogen Research Institute, University of Quebec Trois-Rivières (UQTR), Canada, and a member of the Materials Horizons Community Board. He completed his Ph.D. in Material Physics and Chemistry from Huazhong University of Science and Technology in 2021. His research focuses on the development of nanomaterials for electrocatalysis, particularly in proton exchange membrane fuel cells and water electrolyzers.

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Welcoming John A Rogers to the Materials Horizons Advisory Board

New Advisory Board member

Materials Horizons welcomes John A Rogers

 

Materials Horizons is pleased to welcome Professor John A Rogers from Northwestern University, USA to the Advisory Board.

 

Professor John A. Rogers obtained BA and BS degrees in chemistry and in physics from the University of Texas, Austin, in 1989.  From MIT, he received SM degrees in physics and in chemistry in 1992 and a PhD degree in physical chemistry in 1995.  From 1995 to 1997, Rogers was a Junior Fellow in the Harvard University Society of Fellows.  He joined Bell Laboratories as a Member of Technical Staff in 1997 and then served as Director of the Condensed Matter Physics Research Department from the end of 2000 to 2002.  He then spent thirteen years on the faculty at the University of Illinois, most recently as the Swanlund Chair Professor and Director of the Seitz Materials Research Laboratory.  In the Fall of 2016, he moved to Northwestern University where he is Director of the Querrey-Simpson Institute for Bioelectronics.  He has co-authored nearly 1000 papers and he is co-inventor on more than 100 patents, more than 70 or which are licensed to large companies or to startups that have emerged from his labs.  He is co-founder of several biotech companies, currently including Sibel Health, Epicore Biosystems, Rhaeos, Neurolux and Wearifi.  He is most proud, however, that more than 150 former members of his group are currently in faculty positions at top institutions around the world, including MIT, Princeton, Stanford, Dartmouth, Duke, Cornell, Vanderbilt, Northwestern, University of Southern California, University of Illinois at Urbana/Champaign, University of North Carolina at Chapel Hill, Purdue University, University of California at San Diego, University of California at Santa Barbara, University of Texas at Austin, Texas A&M University and many others in the US, along with a large collection of universities in Europe and Asia, including TU Delft, ETH, Tsinghua, Fudan, Peking, SNU, KAIST, Univ. of Toronto and many others.

 His research has been recognized by many awards, including the Monie Ferst for research mentorship, from Sigma Xi (2021).  Others are a MacArthur Fellowship (2009), the Lemelson-MIT Prize (2011), the Smithsonian Award for American Ingenuity in the Physical Sciences (2013), the MRS Medal (2018), the Benjamin Franklin Medal from the Franklin Institute (2019), a Guggenheim Fellowship (2021), the James Prize for Science and Technology Integration from the NAS (2022) and the IEEE Biomedical Engineering Award (2024).  He is a member of the National Academy of Engineering, the National Academy of Sciences, the National Academy of Medicine, the National Academy of Inventors and the American Academy of Arts and Sciences. 

John’s research seeks to understand and exploit interesting characteristics of ‘soft’ materials, such as polymers, liquid crystals, and biological tissues as well as hybrid combinations of them with unusual classes of micro/nanomaterials, in the form of ribbons, wires, membranes, tubes or related. The aim is to control and induce novel electronic and photonic responses in these materials; his group also develop new ‘soft lithographic’ and biomimetic approaches for patterning them and guiding their growth. This work combines fundamental studies with forward-looking engineering efforts in a way that promotes positive feedback between the two. Current research focuses on soft materials for conformal electronics, nanophotonic structures, microfluidic devices, and microelectromechanical systems, all lately with an emphasis on bio-inspired and bio-integrated technologies. These efforts are highly multidisciplinary, and combine expertise from nearly every traditional field of technical study.

 

Discover some of John’s recent work in RSC journals

 

Soft, Wearable, Microfluidic System for Fluorometric Analysis of Loss of Amino Acids Through Eccrine Sweat

Seunghee H. Cho, Soongwon Cho, Zengyao Lv, Yurina Sekine, Shanliangzi Liu, Mingyu Zhou, Ravi F. Nuxoll, Evangelos E. Kanatzidis, Roozbeh Ghaffari, Donghwan Kim, Yonggang Huang and John A. Rogers

Lab Chip, 2025,25, 1647-1655

 

Skin-interfaced microfluidic biosensors for colorimetric measurements of the concentrations of ketones in sweat

Yunyun Wu, Xinming Li, Kenneth E. Madsen, Haohui Zhang, Soongwon Cho, Ruihao Song, Ravi F. Nuxoll, Yirui Xiong,   Jiaqi Liu, Jingyuan Feng,abf   Tianyu Yang, Kaiqing Zhang, Alexander J. Aranyosi, Donald E. Wright, Roozbeh Ghaffari, Yonggang Huang, Ralph G. Nuzzo and  John A. Rogers

Lab Chip, 2024,24, 4288-4295

3D-printed epidermal sweat microfluidic systems with integrated microcuvettes for precise spectroscopic and fluorometric biochemical assays

Da Som Yang, Yixin Wu, Evangelos E. Kanatzidis, Raudel Avila, Mingyu Zhou,  Yun Bai, Shulin Chen, Yurina Sekine, Joohee Kim, Yujun Deng, Hexia Guo, Yi Zhang, Roozbeh Ghaffari, Yonggang Huang and  John A. Rogers

Mater. Horiz., 2023,10, 4992-5003

 

 

Do join us in welcoming Prof. John A Rogers to the Materials Horizons Advisory Board!

Materials Horizons is a leading journal for the publication of exceptionally high quality, innovative materials science. The journal places an emphasis on original research that demonstrates a novel concept and also publishes outstanding articles featuring true breakthrough developments. Consider submitting your next work to Materials Horizons! Find out more about the journal requirements here.

 

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