In this new article, Martin Schiller, Chad Paton and Martin Bizzarro of the Centre for Star and Planet Formation at the University of Copenhagen report a novel approach for the chemical purification of Ca from silicate rocks by ion-exchange chromatography, and a highly-precise method for the isotopic analysis of Ca by high-resolution multiple collector inductively coupled plasma source mass spectrometry (HR-MC-ICPMS), in combination with thermal ionization mass spectrometry (TIMS).
Read the article in full here:
Calcium isotope measurement by combined HR-MC-ICPMS and TIMS
Martin Schiller, Chad Paton and Martin Bizzarro
J. Anal. At. Spectrom., 2012, Advance Article
DOI: 10.1039/C1JA10272A
Take a look at this other paper from the same authors, published earlier in 2011:
High-precision Mg-isotope measurements of terrestrial and extraterrestrial material by HR-MC-ICPMS—implications for the relative and absolute Mg-isotope composition of the bulk silicate Earth
Martin Bizzarro, Chad Paton, Kirsten Larsen, Martin Schiller, Anne Trinquier and David Ulfbeck
J. Anal. At. Spectrom., 2011, 26, 565-577
DOI: 10.1039/C0JA00190B
You may also be interested in this article:
Separation of Mg, Ca and Fe from geological reference materials for stable isotope ratio analyses by MC-ICP-MS and double-spike TIMS
Frank Wombacher, Anton Eisenhauer, Alexander Heuser and Stefan Weyer
J. Anal. At. Spectrom., 2009, 24, 627-636
DOI: 10.1039/B820154