Dalton Discussion 12: Catalytic C-H and C-X Bond Activation

The stunning city of Durham provided a picturesque setting for the 12th Dalton Discussion meeting (DD12) highlighting the highly topical field of Catalytic C-H and C-X Bond Activation. The meeting was a joint venture between the RSC’s Dalton and Organic Divisions. The organising committee for the discussion meeting, consisting of Phil Dyer, Ian Fairlamb, Sue Gibson (Organic Division), Peter Scott (Dalton Division) and chaired by Todd Marder, must be congratulated for a fantastic meeting rife with lively debate and high quality chemistry.  

The conference brought together the organic, organometallic, and inorganic (coordination chemistry) communities from academia and industry to consider the current state of the art, the development and future of late metal-catalysed cross-coupling strategies of C-X and C-H bonds. The conference dinner took place in the unique surroundings of Durham Castle and the discussion continued long into the night!

Obviously, discussion was a central element to this meeting both at the poster session and in the sessions themselves. Congratulations to Anne Germeroth (University of Edinburgh) for winning the Dalton Transactions Poster Prize with an excellent poster entitled ‘Reversible reactions across the M-C bond of lanthanide NHC complexes to form new N-E and C-E bonds’.

Congratulations also to the other poster prize winners at the meeting: Toritse Bob-Egbe (Imperial College London) who won the inaugural Catalysis Science & Technology Poster Prize, Julien A. Panetier (Heriot-Watt University) and Amanda Jarvis (University of York).

 Look out for the DD12 themed issue which will be published as issue 43 Dalton Transactions at the end of October 2010. More information about the meeting itself can be found at the RSC Events webpage.


Have you any ideas for possible future topics for Dalton Discussion meetings? If so we’d be delighted to hear them, you can email us at dalton-rsc@rsc.org.

Perhaps you attended the meeting yourself or have been to a previous Dalton Discussion? Do share your experience by adding a comment below with your thoughts!  

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Hot Article: phosphoric acid gets heavy

Wolfram Rudolph performs an in-depth study of phosphoric acid in water and heavy water using Raman- and infrared-spectroscopy:

Raman- and infrared-spectroscopic investigations of dilute aqueous phosphoric acid solutions
Wolfram W. Rudolph
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00417K, Paper

READ NOW! Free to access until the 6th of October.

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Hot Article: CO2 recycling

James Donahue and coworkers provide mechanistic insights into the reduction of CO2 to CO mediated by a variety of Tungsten (II) complexes, expanding on earlier work by Mayer et al.:

A tungsten-mediated closed cycle of reactivity for the reduction of CO2 to CO
Upul Jayarathne, Perumalreddy Chandrasekaran, Heiko Jacobsen, Joel T. Mague and James P. Donahue
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00489H , Paper

READ NOW! Free to access until The 6th of October

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Hot Article: potent new tailorable ligand for Au complexes

In this hot article Douglas Stephan and coworkers describe a tailorable new class of potent donor ligand that could be exploited in gold catalysis:

Ag(I) and Au(I) complexes of sterically crowded cyclic phosphinimine ligands
Christopher C. Brown, Christoph Glotzbach and Douglas W. Stephan
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00261E, Paper

READ NOW! Free to access until the 6th of October.

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Meet the team at Dalton Discussion 12

Ruth Doherty, Dalton Transactions Deputy Editor

Dalton Transactions  is proud to attending and publishing an associated Themed Issue with Dalton Discussion 12: Catalytic C-H and C-X Bond Activation (DD12), taking place at Durham University from 13th to the 15th of September 2010.

We are also delighted to be able to sponsor a Dalton Transactions poster prize to be awarded at the meeting.  There will also be a poster prize sponsored by our new journal, Catalysis Science & Technology .

DD12 is being jointly organised by the RSC Dalton and Organic Divisions and will bring together the organic, organometallic, and inorganic (coordination chemistry) communities from academia and industry to discuss the current state of the art, the development and future of late metal-catalysed cross-coupling strategies of C-X and C-H bonds.

I will be attending DD12 so please do have a chat with me if you are also there, I’d love to hear from you.

If you will be attending DD12 let me know by email to dohertyr@rsc.org or by leaving a comment below.

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Hot Article: hexacoordinate silicon complexes

In this hot article from Tacke and coworkers on the coordination chemistry of silicon, they describe new hexacoordinate silicon complexes including some scarcely reported silicon amidinate complexes:

Novel neutral hexacoordinate silicon(IV) complexes with two bidentate monoanionic benzamidinato ligands
Konstantin Junold, Christian Burschka, Rüdiger Bertermann and Reinhold Tacke 
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00391C, Paper

READ NOW! Free access until the 1st of October.

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OLEDs need gentle treatment

OLEDs have found use in mobile phones but researchers are still searching for better emitters

A popular fabrication technique for organic light emitting diodes (OLEDs) may be having a negative impact on performance, say European scientists.

Read Yuandi Li’s news article on this hot Dalton Transactions paper at Highlights in Chemical Science or access the full article:

An inconvenient influence of iridium(III) isomer on OLED efficiency
Etienne Baranoff, Henk J. Bolink, Filippo De Angelis, Simona Fantacci, Davide Di Censo, Karim Djellab, Michael Grätzel and Md. Khaja Nazeeruddin, Dalton Trans., 2010
DOI: 10.1039/c0dt00414f

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Hot Article: Pretty perovskite with potential multiferroic properties

Roland Tellgren and colleagues discuss the magnetic properties of the complex perovskite Pb2CoTeO6 in this Dalton Transactions Hot Article:

Structural and magnetic properties of the ordered perovskite Pb2CoTeO6
S. A. Ivanov, P. Nordblad, R. Mathieu, R. Tellgren and C. Ritter,
Dalton Trans., 2010, Advance Article
DOI: 10.1039/c0dt00558d, Paper

READ NOW! This article is free to access until the 28th of September.

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Hot Article: controversial carbene coordination chemistry

In this hot article Robert Mulvey and colleagues investigate the coordination chemistry of NHC with s-block elements and the structural chemistry of organomagnesium compounds leading to some interesting discoveries:

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs
Alan R. Kennedy, Robert E. Mulvey and Stuart D. Robertson
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00693A, Paper

READ NOW! This article is free to access until the 28th of September.

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Hot Article: new anticancer complex with unusual water cluster

In this hot article the authors investigate a new Pt(II) complex for its DNA binding and clevage properties and find considerable potential for the compound as an anticancer drug. Through detailed X-ray and thermal decomposition studies they also discovered a water cluster containing 20 water molecules in the framework of the Pt(II) host:

An unusual (H2O)20 discrete water cluster in the supramolecular host of a charge transfer platinum(II) complex: cytotoxicity and DNA cleavage activities
Sutanuva Mandal, Alfonso Castiñeiras, Tapan K. Mondal, Arindam Mondal, Dhrubajyoti Chattopadhyay and Sreebrata Goswami
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00527D, Paper

READ NOW! Free to access until September 28th

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