Dalton Transactions Blog

Controlled crystallisation of porous crystals of luminescent platinum(ii) complexes by electronic tuning of ancillary ligands

Takanari Mochizuki, Masaki Yoshida*, Atsushi Kobayashi and Masako Kato*

Dalton Trans., 2024, 53, 12064-12072

A highly anisotropic family of hexagonal bipyramidal Dy(iii) unsaturated 18-crown-6 complexes exceeding the blockade barrier over 2700 K: a computational exploration

Shruti Moorthy, Ibtesham Tarannum, Kusum Kumari and Saurabh Kumar Singh*

Dalton Trans., 2024, 53, 12073-12079

Tetracycline: structural characterization and antimicrobial properties of its water-soluble di-anionic bi-sodium salt (Open Access)

Afroditi S. Tsigara, Christina N. Banti*, Antonios Hatzidimitriou and Sotiris K. Hadjikakou*

Dalton Trans., 2024, 53, 12080-12089

Spin dynamics phenomena of a cerium(iii) double-decker complex induced by intramolecular electron transfer (Open Access)

Kana Kobayashi, Michiyuki Suzuki, Tetsu Sato, Yoji Horii, Takefumi Yoshida, Brian. K. Breedlove, Masahiro Yamashita and Keiichi Katoh*

Dalton Trans., 2024, 53, 11664-11677

The effect of ionic versus covalent functionalization of polyoxometalate hybrid materials with coordinating subunits on their stability and interaction with DNA

Daria Nowicka, Dawid Marcinkowski, Nahir Vadra, Martyna Szymańska, Maciej Kubicki, Giuseppe Consiglio, Wojciech Drożdż, Artur R. Stefankiewicz, Violetta Patroniak, Marta Fik-Jaskółka* and Adam Gorczyński*

Dalton Trans., 2024, 53, 11678-11688

Solvent vapour-responsive structural transformations in molecular crystals composed of a luminescent mononuclear aluminium(iii) complex (Open Access)

Fumiya Kobayashi*, Azuki Yoshida, Misato Gemba, Yuta Takatsu and Makoto Tadokoro*

Dalton Trans., 2024, 53, 11689-11696

The cubic structure of Li₃As stabilized by substitution – Li₈TtAs₄ (Tt = Si, Ge) and Li₁₄TtAs₆ (Tt = Si, Ge, Sn) and their lithium ion conductivity

Martin Schmid, Florian Wegner, Claudia De Giorgi, Florian Pielnhofer and Arno Pfitzner*

Dalton Trans., 2024, 53, 11257-11263

The effect of light irradiation on a nitro-ruthenium porphyrin complex in the induced death of lung cancer cells in two- and three-dimensional cultures: Insights into the effect of nitric oxide

Amanda Blanque Becceneri*, Matheus Torelli Martin, Angelica Ellen Graminha, Márcia Regina Cominetti, Peter C. Ford and Roberto Santana da Silva

Dalton Trans., 2024, 53, 11264-11275

1,2,3-Triazol-5-ylidene- vs. 1,2,3-triazole-based tricarbonylrhenium(i) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties (Open Access)

Corinne Vanucci-Bacqué, Mariusz Wolff, Béatrice Delavaux-Nicot, Abanoub Mosaad Abdallah, Sonia Mallet-Ladeira, Charles-Louis Serpentini, Florence Bedos-Belval, Kar Wai Fong, Xiao Ying Ng, May Lee Low, Eric Benoist* and Suzanne Fery-Forgues*

Dalton Trans., 2024, 53, 11276-11294

Influence of proline and hydroxyproline as antimicrobial and anticancer peptide components on the silver(i) ion activity: structural and biological evaluation with a new theoretical and experimental SAR approach

Gabriela Kuzderová, Simona Sovová, Michaela Rendošová, Róbert Gyepes, Danica Sabolová, Ivona Kožárová, Ľudmila Balážová, Mária Vilková, Martin Kello, Alan Liška and Zuzana Vargová*

Dalton Trans., 2024, 53, 10834-10850

Lattice solvent- and substituent-dependent spin-crossover in isomeric iron(ii) complexes (Open Access)

Senthil Kumar Kuppusamy*, Asato Mizuno, Lea Kämmerer, Soma Salamon, Benoît Heinrich, Corinne Bailly, Ivan Šalitroš*, Heiko Wende* and Mario Ruben*

Dalton Trans., 2024, 53, 10851-10865

Activation of carbon disulfide by a hypersilyl germylene

V. S. Ajithkumar, Nripen Khilari, Pratiksha B. Ghanwat, Geethu Venugopal, Debasis Koley* and Sakya S. Sen*

Dalton Trans., 2024, 53, 10814-10818

Coinage metal-ethylene complexes of sterically demanding 1,10-phenanthroline ligands

Deepika V. Karade, Vo Quang Huy Phan and H. V. Rasika Dias*

Dalton Trans., 2024, 53, 10426-10433

Review on synthetic approaches and PEC activity performance of bismuth binary and mixed-anion compounds for potential applications in marine engineering

Jiaji Zhang, Bingchu Mei, Huiyu Chen and Zaichun Sun*

Dalton Trans., 2024, 53, 10376-10402

Deciphering the structure and potassium-ion transport mechanism of potassium borate glass

Lulu Song, Alex C. Hannon, Steve Feller, Ruirui Liu, Peyton McGuire, Bo Zhang, Yongquan Zhou, Wu Li* and Fayan Zhu*

Dalton Trans., 2024, 53, 10434-10445

Contrasting impact of coordination polyhedra and site symmetry on the electronic energy levels in nine-coordinated Eu(iii) and Sm(iii) crystals structures determined from single crystal luminescence spectra

Sabina Svava Mortensen, Villads R. M. Nielsen and Thomas Just Sørensen*

Dalton Trans., 2024, 53, 10079-10092

Elevating the energetic capabilities of metal coordination compounds by incorporating nitrate anions

Abhishek Kumar Yadav, Richa Rajak  and Srinivas Dharavath*

Dalton Trans., 2024, 53, 10093-10098

Extremely stable system of 1-haloselanyl-anthraquinones: experimental and theoretical investigations

Naoki Ogawa, Nobuhiro Suzuki, Yoshifumi Katsura, Mao Minoura, Waro Nakanishi and Satoko Hayashi*

Dalton Trans., 2024, 53, 10099-10112

Exploring the impact of various reducing agents on Cu nanocluster synthesis (Open Access)

Sourav Biswas and Yuichi Negishi*

Dalton Trans., 2024, 53, 9657-9663

Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd₃W₂ coordinated complexes (Open Access)

Francisco Reigosa, Paula M. Polo, M. Teresa Pereira and José M. Vila*

Dalton Trans., 2024, 53, 9680-9691

Coordinating nature of M₆L₁₂ double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(ii) ions

Seonghyeon An, Jihun Han, Dongwon Kim, Haeri Lee* and Ok-Sang Jung*

Dalton Trans., 2024, 53, 9692-9699

Transition metal complexes of the (2,2,2-trifluoroethyl)phosphinate NOTA analogue as potential contrast agents for ¹⁹F magnetic resonance imaging (Open Access)

Filip Koucký, Tereza Dobrovolná, Jan Kotek*, Ivana Císařová, Jana Havlíčková, Alan Liška, Vojtěch Kubíček and Petr Hermann

Dalton Trans., 2024, 53, 9267-9285

Impact of o-aryl halogen effects on ethylene polymerization: steric vs. electronic effects

Jianjian Dai and Shengyu Dai*

Dalton Trans., 2024, 53, 9286-9293

Soma–Iwamoto-type SCO complex Fe(quinazoline)₂[Au(CN)₂]₂ using the quinazoline-type ligand (Open Access)

Kosuke Kitase*, Daisuke Akahoshi and Takafumi Kitazawa

Dalton Trans., 2024, 53, 9248-9251

Towards structurally versatile mesoionic N-heterocyclic olefin ligands and their coordination to palladium, gold, and boron hydride (Open Access)

Tisa Ževart, Balazs Pinter, Matic Lozinšek, Damijana Urankar, Ross D. Jansen-van Vuuren and Janez Košmrlj*

Dalton Trans., 2024, 53, 8915-8925

Aggregation-induced enhanced fluorescence emission of chiral Zn(ii) complexes coordinated by Schiff-base type binaphthyl ligands

Daiki Tauchi, Katsuya Kanno, Masashi Hasegawa, Yasuhiro Mazaki, Kazunori Tsubaki, Ken-ichi Sugiura, Takuya Shiga, Seiji Mori and Hiroyuki Nishikawa*

Dalton Trans., 2024, 53, 8926-8933

Self-assembly of Ni(ii) with a chiral ligand pair vs. mixture of the chiral ligand pair: structural features and recognition ability of Ni₂L₄ cages

Jihun Han, Hyo Jeong Back, Mohammad M. Hossain, Ok-Sang Jung* and Young-A. Lee* 

Dalton Trans., 2024, 53, 8934-8939

Effective photosensitized emission of a Tb(iii) complex using a β-diketonate photosensitizer and an oxygen barrier system in a thermally populated triplet state (Open Access)

Kota Inage, Mengfei Wang, Yasuchika Hasegawa* and Yuichi Kitagawa*

Dalton Trans., 2024, 53, 8555-8562

Co₃O₄/activated carbon nanocomposites as electrocatalysts for the oxygen evolution reaction

Andrei F. V. de Lima, Annaíres de A. Lourenço, Vinícius D. Silva, André L. Menezes de Oliveira, Arpad M. Rostas, Lucian Barbu-Tudoran, Cristian Leostean, Ovidiu Pana, Rodolfo B. da Silva, Daniel A. Macedo and Fausthon F. da Silva*

Dalton Trans., 2024, 53, 8563-8575

Factors governing the protonation of Keggin-type polyoxometalates: influence of the core structure in clusters (Open Access)

Hiroshi Sampei, Hiromu Akiyama, Koki Saegusa, Masahiro Yamaguchi, Shuhei Ogo, Hiromi Nakai, Tadaharu Ueda* and Yasushi Sekine*

Dalton Trans., 2024, 53, 8576-8583

Low-temperature synthesis of porous high-entropy (CoCrFeMnNi)₃O₄ spheres and their application to the reverse water–gas shift reaction as catalysts (Open Access)

Ayano Taniguchi, Takeshi Fujita and Kazuya Kobiro*

Dalton Trans., 2024, 53, 8124-8134

Synthesis of amorphic and hexagonal boron nitride via high temperature treatment of NH₃BH₃ and Li(BH₃NH₂BH₂NH₂BH₃) 

A. Prus, R. Owarzany, D. Jezierski, K. Perkowski and K. J. Fijalkowski*

Dalton Trans., 2024, 53, 8135-8140

Enabling a bioinspired N,N,N-copper coordination motif through spatial control in UiO-67: synthesis and reactivity (Open Access)

Isabelle Gerz, Erlend S. Aunan, Valeria Finelli, Mouhammad Abu Rasheed, Gabriele Deplano, Rafael Cortez S. P., Inga L. Schmidtke, David S. Wragg, Matteo Signorile, Knut T. Hylland, Elisa Borfecchia, Karl Petter Lillerud, Silvia Bordiga*, Unni Olsbye* and Mohamed Amedjkouh*

Dalton Trans., 2024, 53, 8141-8153

Dual FGFR-targeting and pH-activatable ruthenium–peptide conjugates for targeted therapy of breast cancer (Open Access)

João Franco Machado, Marco Sá, Inês Pires, Miguel Tarita da Silva, Fernanda Marques, Jaime A. S. Coelho, Filipa Mendes, M. Fátima M. Piedade, Miguel Machuqueiro, María Angeles Jiménez, Maria Helena Garcia, João D. G. Correia* and Tânia S. Morais*

Dalton Trans., 2024, 53, 7682-7693

Interfacial engineering of a multijunctional In₂O₃/WO₃@Ti₄N₃T_x S-scheme photocatalyst with enhanced photoelectrochemical properties (Open Access)

Antony Okinyi Onjwaya, Majahekupheleni Livileyise Malati, Jane Catherine Ngila and Langelihle Nsikayezwe Dlamin*

Dalton Trans., 2024, 53, 7694-7710

Direct C–H electrophilic borylation with (C₆F₅)₂B–NTf₂ to generate B–N dibenzo[a,h]pyrenes

Tony Nguyen, Jason L. Dutton, Chia Yun Chang, Wen Zhou and  Warren E. Piers*

Dalton Trans., 2024, 53, 7273-7281

Iridium(iii)-based minor groove binding complexes as DNA photocleavage agents (Open Access)

Stephen O. Aderinto, Torsten John, Abdulmujeeb Onawole, Raphael Peter Galleh and Jim A. Thomas*

Dalton Trans., 2024, 53, 7282-7291

Effect of f-element complexation on the radiolysis of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP])

Stephen P. Mezyk*, Makayla Baxter, Cristian Celis-Barros, Travis S. Grimes, Peter R. Zalupski, Cathy Rae, Christopher A. Zarzana, Andrew R. Cook and Gregory P. Horne*

Dalton Trans., 2024, 53, 6881-6891

Barium phosphidoboranes and related calcium complexes (Open Access)

Gabriel Duneş, Peter M. Chapple, Samia Kahlal, Thierry Roisnel, Jean-François Carpentier, Jean-Yves Saillard* and Yann Sarazin*

Dalton Trans., 2024, 53, 6892-6905

Analyses of the electronic structures of FeFe-cofactors compared with those of FeMo- and FeV-cofactors and their P-clusters (Open Access)

Zhen-Lang Xie, Wan-Ting Jin and Zhao-Hui Zhou

Dalton Trans., 2024, 53, 6529-6536

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Steven R. Kidd, Wen Zhou, Jeffrey J. Warren* and Daniel B. Leznoff*

Dalton Trans., 2024, 53, 6537-6546

Amplified photomodulation of a bis(dithienylethene)-substituted phosphine (Open Access)

Anastasiia Sherstiuk, Marc Villabona, Agustí Lledós, Jordi Hernando*, Rosa María Sebastián and Evamarie Hey-Hawkins*

Dalton Trans., 2024, 53, 6190-6199

Hybridization of layered double hydroxides with functional particles

Rattanawadee Ploy Wijitwongwan, Soontaree Grace Intasa-ard and Makoto Ogawa*

Dalton Trans., 2024, 53, 6144-6156

Switching of magnetic properties by topotactic reaction in a 1D CN-bridged Ni(ii)–Nb(iv) system (Open Access)

Michał Heczko and Beata Nowicka*

Dalton Trans., 2024, 53, 5788-5795

Molybdenum-maltolate as a molybdopterin mimic for bioinspired oxidation reaction

Swapnil S. Pawar, Rohit N. Ketkar, Pranav B. Gaware, Kaustubh U. Jagushte, Divyani Dhawne, Shreyada N. Save, Shilpy Sharma, Ganga Periyasamy, Niyamat Chimthanawala, Sadhana Sathaye, Shreerang V. Joshi and Nabanita Sadhukhan*

Dalton Trans., 2024, 53, 5770-5774

Formation of N,N,N′,N′-tetramethylethylene diamine via coupling of the two charge reversed C–N bonds of Me3NO in the presence of an Eu(ii) bis(trimethylsilyl)amide complex

Yangjuan Li and Yu Gong*

Dalton Trans., 2024, 53, 5342-5345

Highly stable CsPbBr₃ perovskite phases from new lead β-diketonate glyme adducts (Open Access)

Lorenzo Sirna, Anna Lucia Pellegrino*, Salvatore Pio Sciacca, Martina Lippi, Patrizia Rossi, Carmela Bonaccorso, Giuseppe Bengasi, Marina Foti and Graziella Malandrino*

Dalton Trans., 2024, 53, 5360-5372

Bimetallic CPM-37(Ni,Fe) metal–organic framework: enhanced porosity, stability and tunable composition (Open Access)

Soheil Abdpour, Marcus N. A. Fetzer, Robert Oestreich, Thi Hai Yen Beglau, István Boldog* and Christoph Janiak*

Dalton Trans., 2024, 53, 4937-4951

Synthesis, characterization, and cancer cell-selective cytotoxicity of mixed-ligand cobalt(iii) complexes of 8-hydroxyquinolines and phenanthroline bases

Banashree Deka, Tukki Sarkar, Arnab Bhattacharyya*, Ray J. Butcher*, Samya Banerjee*, Sasanka Deka, Kandarpa K. Saikia* and Akhtar Hussain*

Dalton Trans., 2024, 53, 4952-4961

Recent developments in piezo-photocatalytic CO₂ reduction: concepts, mechanism, and advances

Atul Verma and Yen-Pei Fu*

Dalton Trans., 2024, 53, 4890-4899

A karst-inspired hierarchical Mg/Al layered double hydroxide with a high entropy-driven process for interception and storage

Hongyu Shi, Jun Qin*, Qing Lv, Lijin Zhang, Qingxin Li, Bin Ou and Xiaolang Chen*

Dalton Trans., 2024, 53, 4412-4425

Mana Ogawa, Sayaka Usami, Ryo Takahama, Kazuko Iwamoto, Tomomi Nabeta, Shin Kawashima, Ryoichi Kojima, Junya Ohyama, Teruaki Hayakawa, Yuta Nabae* and Makoto Moriya*

Dalton Trans., 2024, 53, 4426-4431

Intensity and lifetime ratiometric luminescent thermometer based on a Tb(iii) coordination polymer

Augusto Iwashita Costa, Rafaela M. R. da Silva, Luckerman D. G. Botelho, Sergio F. N. Coelho, Fernando A. Sigoli, João Honorato, Javier Ellena, Felipe T. Martins, Angelo M. Gomes, Wallace C. Nunes, Francesc Lloret, Miguel Julve and Maria Vanda Marinho*

Dalton Trans., 2024, 53, 3994-4004

Diversity of oxidation state in copper complexes with phenolate ligands

Tomoyuki Takeyama* and Yuichi Shimazaki*

Dalton Trans., 2024, 53, 3911-3929

On the mechanism of action of arsenoplatins: arsenoplatin-1 binding to a B-DNA dodecamer (Open Access)

Romualdo Troisi, Gabriella Tito, Giarita Ferraro, Filomena Sica, Lara Massai, Andrea Geri, Damiano Cirri, Luigi Messori and Antonello Merlino*

Dalton Trans., 2024, 53, 3476-3483

Fluoro-bridged rare-earth metal–organic frameworks

Muhammad Abbas, Simin Sheybani, Marie L. Mortensen and Kenneth J. Balkus, Jr.*

Dalton Trans., 2024, 53, 3445-3453

Diphosphene with a phosphineborane tether and its rhodium complex (Open Access)

Akihiro Tsurusaki*, Shingo Takechi and Ken Kamikawa*

Dalton Trans., 2024, 53, 2929-2936

Effect of substituents on the ¹O₂ production and biological activity of (N^N^N)Pt(py) complexes (Open Access)

Guillermo Romo-Islas, María Gil-Moles, Arnav Saxena, Antonio Frontera, M. Concepción Gimeno* and Laura Rodríguez*

Dalton Trans., 2024, 53, 2475-2486

X-ray crystallographic analysis of the antiferromagnetic low-temperature phase of galvinoxyl: investigating magnetic duality in organic radicals

Rie Suizu, Yoshiaki Shuku, Vincent Robert, Pablo Roseiro, Nadia Ben Amor, Zain Khawar, Neil Robertson and Kunio Awaga*

Dalton Trans., 2024, 53, 1961-1965

Synthesis of N-heterocyclic carbene gold(i) complexes from the marine betaine 1,3-dimethylimidazolium-4-carboxylate (Open Access)

Seyedeh Mahbobeh Mahdavi, Dirk Bockfeld, Rolf Büssing, Bianka Karge, Thomas Bannenberg, René Frank, Mark Brönstrup, Ingo Ott and Matthias Tamm*

Dalton Trans., 2024, 53, 1942-1946

Spin-state versatility in Fe ^II₄L₆ supramolecular cages with a pyridyl-hydrazone ligand scaffold modulated by solvents and counter anions

Weiyang Li, Xiaochun Li, Koen Robeyns, Mariusz Wolff, Joseph Kfoury, Julianna Oláh, Radovan Herchel, Serhiy Demeshko, Franc Meyer and Yann Garcia*

Dalton Trans., 2024, 53, 1449-1459

Ye Olde supramolecular chemistry, its modern rebranding and overarching trends in chemistry

Matteo Savastano

Dalton Trans., 2024, 53, 1373-1392

Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center

Yuto Suga and Yusuke Sunada*

Dalton Trans., 2024, 53, 862-865

Ordering by cation replacement in the system Na_2−xLi_xGa₇ (Open Access)

Chia-Chi Yu, Yurii Prots, Alim Ormeci, Mitja Krnel, Marcus Schmidt, Lev Akselrud, Frank R. Wagner, Yuri Grin and Michael Baitinger*

Dalton Trans., 2024, 53, 908-916

An effective visible-light driven fumarate production from gaseous CO₂ and pyruvate by the cationic zinc porphyrin-based photocatalytic system with dual biocatalysts (Open Access)

Mika Takeuchi and Yutaka Amao*

Dalton Trans., 2024, 53, 418-422

Fluorescence sensing and device fabrication with luminescent metal–organic frameworks

Ding-Gui Cai, Teng-Fei Zheng*, Sui-Jun Liu* and He-Rui Wen

Dalton Trans., 2024, 53, 394-409

Oxidation-derived anticancer potential of sumanene–ferrocene conjugates (Open Access)

Artur Kasprzak*, Agnieszka Zuchowska, Pawel Romanczuk, Agata Kowalczyk, Ireneusz P. Grudzinski, Anna Malkowska, Anna M. Nowicka and Hidehiro Sakurai

Dalton Trans., 2024, 53, 56-64

Lanthanide complexes facilitate wound healing by promoting fibroblast viability, migration and M2 macrophage polarization

Wajid Ali, Fatemeh Jamshidi-Adegani, Zahra Mirsanei, Juhaina Al-Kindi, Saeid Vakilian, Mohammed Al-Broumi, Sulaiman Al-Hashmi, Jeremy M. Rawson*, Ahmed Al-Harrasi* and Muhammad Usman Anwar*

Dalton Trans., 2024, 53, 65-73