The most stable crystal structures of different TCN compounds are investigated in this Dalton Transactions Hot article.
Philippe F. Weck and colleagues from the University of Nevada-Las Vegas, USA, use gradient-corrected density functional theory to look at the structures and properties of technetium nitride phases.
Technetium nitride is used in nuclear waste management, as nitride forms are a good way of storing technetium isotopes, a common by product of the nuclear fuel cycle, and also in nuclear medicine, where it acts a a radiopharmaceutical (if you are interested in radiopharmaceuticals, check out our recent themed issue)
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Interplay between structure, stoichiometry and properties of technetium nitrides
Philippe F. Weck, Eunja Kim and Kenneth R. Czerwinski
Dalton Trans., 2011, DOI: 10.1039/C1DT10334B