Archive for January, 2018

Read our most impactful Inorganic Materials papers of 2017!

Inorganic materials and nanoparticles are being applied to many of the most pressing challenges facing humanity in the 21st century. They are currently being investigated for their applications in batteries, solar cells, photocatalysts for water splitting and pollutant degradation, and medical theragnostics. Here are some of the most impactful papers in solid state inorganic chemistry from Dalton Transactions in 2017.

 

Most Downloaded Reviews:

These Frontier and Perspective articles are receiving a lot of attention online, reviewing the advances and trends that are making waves in the solid-state inorganic chemistry community.

 

Thioborates: potential nonlinear optical materials with rich structural chemistry 

Yu-kun Lian, Li-Ming Wu and Ling Chen

Dalton Trans., 2017, 46, 4134-4147

DOI: 10.1039/C6DT04767J

 

This review summarizes thioborates and their structural motifs ranging from zero-dimension to three-dimension. The most commonly observed building units of these examples are planar-triangle BS3 and tetrahedron BS4. Thioborates possess advantages with respect to their structural diversity, optical nonlinearity, laser-induced damage threshold and transparency range, and represent potentially a rich supply of new nonlinear optical materials.

 

 

A chemical approach to perovskite solar cells: control of electron-transporting mesoporous TiO2 and utilization of nanocarbon materials

Tomokazu Umeyama and Hiroshi Imahori

Dalton Trans., 2017, 46, 15615-15627

DOI: 10.1039/C7DT02421E

 

This Perspective highlights recent chemical approaches to perovskite solar cells, including the control of electron-transporting mesoporous TiO2 and the utilization of nanocarbon materials.

   

 

Engineering transition metal phosphide nanomaterials as highly active electrocatalysts for water splitting

Yanmei Shi and Bin Zhang

Dalton Trans., 2017, 46, 16770-16773

DOI: 10.1039/C7DT03648E

 

This Frontier article will highlight recent advances in engineering the composition and structure of TMPs for higher water electrolysis performances.

   

 

Most Cited Articles:

This original research is off to a great start, as some of our most cited work these papers and communications are already being recognized by the nanomaterials and solid-state chemistry community.

 

Novel p–n heterojunction BiOI/CeO2photocatalyst for wider spectrum visible-light photocatalytic degradation of refractory pollutants

Xiao-Ju Wen, Cheng-Gang Niu, Lei Zhang and Guang-Ming Zeng

 

  Dalton Trans., 2017, 46, 4982-4993

DOI: 10.1039/C7DT00106A

 

A novel BiOI/CeO2 photocatalyst with high photocatalytic performance was successfully synthesized via a facile in situ precipitation method. The enhanced photocatalytic performance is ascribed to the formation of a p–n junction, which promotes carrier separation.

 

All-inorganic perovskite quantum dot/mesoporous TiO2 composite-based photodetectors with enhanced performance

Lin Zhou, Kai Yu, Fan Yang, Jun Zheng, Yuhua Zuo, Chuanbo Li, Buwen Cheng and Qiming Wang

  Dalton Trans., 2017, 46, 1766-1769

DOI: 10.1039/C6DT04758K

 

Herein, we evaluated an all-inorganic perovskite based MSM photodetector employing a bilayer composite film of mp-TiO2 and CsPbBr3 quantum dots as a photosensitizer.

 

 

 

Na2.32Co1.84(SO4)3 as a new member of the alluaudite family of high-voltage sodium battery cathodes

Debasmita Dwibedi, Ritambhara Gond, Allumolu Dayamani, Rafael B. Araujo, Sudip Chakraborty, Rajeev Ahuja and Prabeer Barpanda

  Dalton Trans., 2017,46, 55-63

DOI: 10.1039/C6DT03767D

 

A novel alluaudite, Na2+2xCo2−x(SO4)3, has been unveiled as a potential high-voltage (ca. 4.8–5.8 V) sodium battery cathode demonstrating antiferromagnetic ordering.

 

 

 

Submit your research or reviews on Solid State Inorganic Chemistry and Nanomaterials to Dalton Transactions – see our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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Top Inorganic Chemistry reviews of 2017!

It is that time again when we take a look back at the work published in the previous year and how it is being received by the Inorganic Chemistry community. These Perspective and Frontier articles are among our top cited and downloaded review articles of 2017 providing valuable insight into the latest advances and trends for the community.

The full list of Perspective and Frontier articles published in 2017 can be found here.

Luminescent rare-earth-based MOFs as optical sensors

Partha Mahata, Sudip Kumar Mondal, Debal Kanti Singha and Prakash Majee

Dalton Trans., 2017,46, 301-328

This perspective article highlights the basics and applications of luminescence-based sensing of hazardous chemicals, pH, and temperature using rare-earth-based metal–organic frameworks.

Functional metallosupramolecular architectures using 1,2,3-triazole ligands: it’s as easy as 1,2,3 “click”

Roan A. S. Vasdev, Dan Preston and James D. Crowley

Dalton Trans., 2017,46, 2402-2414

Self-assembled metallosupramolecular architectures generated using “click” ligands have become an increasingly popular area of inorganic chemistry.

Alkynyl-protected gold and gold–silver nanoclusters  

Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Jia-Qi Wang and Quan-Ming Wang

Dalton Trans., 2017,46, 3427-3434

Alkynyl-protected coinage metal nanoclusters show new structural features and have interesting luminescence properties and catalytic behavior.

Copper(I)–NHC complexes as NHC transfer agents

Fady Nahra, Alberto Gómez-Herrera and Catherine S. J. Cazin

Dalton Trans., 2017,46, 628-631

The latest advances involving the use of copper(I)–NHC complexes as NHC transfer agents are described.

Generalization of the Tolman electronic parameter: the metal–ligand electronic parameter and the intrinsic strength of the metal–ligand bond

Dieter Cremer and Elfi Kraka

Dalton Trans., 2017,46, 8323-8338

Dieter Cremer and Elfi Kraka

The MLEP is a new, generally applicable measure of the metal–ligand bond strength based on vibrational spectroscopy, replacing the TEP.

 

β-Diketiminate complexes of the first row transition metals: applications in catalysis

R.L. Webster

Dalton Trans., 2017,46, 4483-4498

Although β-diketiminate complexes have been widely explored in stoichiometric studies, their use as catalysts is largely underdeveloped.

 

 

These articles are free to view until 15th February 2018

Submit your research or reviews to Dalton Transactions– see our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

 

 

 

 

 

 

 

 

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Rising Stars in Coordination Chemistry – Call for Submissions

This year’s International Conference on Coordination Chemistry (ICCC2018) is being held in Sendai, Japan, from July 30th – August 4th and features a ‘Rising Stars’ session aimed at PhD students and early career researchers. If you, or someone you know, is a Rising Star in Coordination Chemistry see the flyer below for further details.

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