Archive for 2011

Top Ten most-read Dalton Transactions articles in December

Read the most-read Dalton Transactions articles of December 2010, listed below:

C. N. R. Rao and Manashi Nath, Dalton Trans., 2003, 1-24
DOI: 10.1039/B208990B
 
Ming-Xing Yang, Li-Juan Chen, Shen Lin, Xiao-Hua Chen and Hua Huang, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT00781A
 
C. N. R. Rao, S. R. C. Vivekchand, Kanishka Biswas and A. Govindaraj, Dalton Trans., 2007, 3728-3749
DOI: 10.1039/B708342D
 
Hai-Yan Liu, Hua Wu, Jian-Fang Ma, Ying-Ying Liu, Jin Yang and Ji-Cheng Ma, Dalton Trans., 2011, 40, 602-613
DOI: 10.1039/C0DT01024C
 
Holger Braunschweig and Rian D. Dewhurst, Dalton Trans., 2011, 40, 549-558
DOI: 10.1039/C0DT01181A
 
P. P. Edwards, A. Porch, M. O. Jones, D. V. Morgan and R. M. Perks, Dalton Trans., 2004, 2995-3002
DOI: 10.1039/B408864F
 
Bart M. J. M. Suijkerbuijk, Bas N. H. Aerts, Harm P. Dijkstra, Martin Lutz, Anthony L. Spek, Gerard van Koten and Robertus J. M. Klein Gebbink, Dalton Trans., 2007, 1273-1276
DOI: 10.1039/B701978P
 
Deborah L. Kays, Dalton Trans., 2011, 40, 769-778
DOI: 10.1039/C0DT01247E
 
Ye Peng, Teng Ben, Jun Xu, Ming Xue, Xiaofei Jing, Feng Deng, Shilun Qiu and Guangshan Zhu, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01268H
 
Jacek Klinowski, Filipe A. Almeida Paz, Patrícia Silva and João Rocha, Dalton Trans., 2011, 40, 321-330
DOI: 10.1039/C0DT00708K

To keep up-to-date with all the best inorganic research articles, sign up for the journal’s e-alerts here.

 

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Dalton Transactions Issue 6 Now Published

View the latest issue of Dalton Transactions or read this week’s cover article, a Perspective by Wolfdieter Schenk on the coordination chemistry of the sulfur oxides, thioformaldehyde and its oxides.

Cover article:

The coordination chemistry of small sulfur-containing molecules: a personal perspective
Wolfdieter A. Schenk
Dalton Trans, 2011, 40, 1209-1219
DOI: 10.1039/c0dt00975j, Perspective

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Hot Article: Cunning characterisation of yttrium 89

Fernando Lopez Ortiz and colleagues from the Universidad de Almerıa in Spain have used NMR correlation experiments between 89Y and 31P nuclei to elucidate the structures of yttrium complexes in solution which have previously proved notoriously tricky to characterise.

Find out how they did this in their Dalton Transactions Hot Article. FREE to read until the 19th February 2011.

31 P,89Y Shift correlation. Application to the speciation of yttrium complexes with triphenylphosphine oxide 
Ignacio Fernández, Víctor Yañez-Rodríguez and Fernando López Ortiz
Dalton Trans., 2011, DOI: 10.1039/C0DT01733G, Communication

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Nominations welcome for RSC Awards

Do you know someone who has advanced research in inorganic chemistry by developing new organometallic compounds or providing vital insight into catalytic processes? The RSC Prizes and Awards recognise achievements by individuals, teams and organisations. There are over 60 Prizes and Awards available, covering all areas of the chemical sciences. 

Nomination is quick and easy using our online system and you can nominate yourself or a colleague. The closing date for nominations is 31 January 2011 so please don’t wait.

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FREE Chemistry World Webinar

Chemistry World are hosting the first Chemistry World webinar on 31 January. This will include an active audience in Burlington House and be FREE to watch online.

Find out more by reading the blog, and to find out how to register.

Connecting Chemistry and Mass Spectrometry on the Internet – ChemSpider
Monday 31 January 2011

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Dalton Transactions Issue 5 Now Published

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Check out this week’s issue of Dalton Transactions, where the outside cover displays work by Nils Metzler-Nolte and colleagues, from Ruhr-University Bochum, Germany. In their paper they make a ruthenium Tp sandwich bioconjugate, with a structure reminescent of a scorpion.

View the issue, or read the research…

Outside cover article:

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Microwave-assisteTpRu(p-(CO-Tyr-Gly-Gly-Phe-Leu-OH)-C6H4Tp) as the first example of a ruthenium Tp sandwich bioconjugated synthesis of the Tp sandwich compound TpRu(p-Br-C6H4Tp) and application of its benzoic acid derivative TpRu(p-(CO2H)-C6H4Tp) in the covalent labelling of biomolecules
Johannes Zagermann, Mariusz Molon and Nils Metzler-Nolte
Dalton Trans., 2011, 40, 1011-1015
DOI: 10.1039/C0DT01121E, Communication

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Perspective: Conversions between metal–ligand multiple bond types

In this Dalton Transactions Perspective, Aaron Odom from Michigan State University examines single-step methods for the conversion of one type of metal-ligand multiple bond to another. These reactions have a wide variety of applications in organic synthesis, e.g. in carbonyl olefination.

The Perspective includes recent examples from the author’s own laboratory on metallacycles prepared directly from an imido ligand.

Read more: Conversions between metal-ligand multiple bond (MLMB) types: carbonyl olefination and other applications
Aaron L. Odom
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT00825G, Perspective

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Infinite winding water chain

Syntheses, structures and properties of two unusual silver–organic coordination networks: 1D-1D tubular intertwinement and existence of an infinite winding water chain
Bo Li, Shuang-Quan Zang, Can Ji, Chen-Xia Du, Hong-Wei Hou and Thomas C. W. Mak
Dalton Trans., 2011, 40, 788-792
Cover article – Check out the science behind the art of our most recent cover for Dalton Transactions, volume 40, issue 4 

Two new silver(I) coordination polymers have been constructed from the flexible H3btc and
bridging bpy ligands under different conditions. The results indicate that different coordination modes play a vital role in the assembly of supramolecular architectures. The new polymers represent the  first example of 1D-1D parallel interpenetrated tubular chains in a coordination polymer, and a double-ladder structure, in which an infinite winding water chain has been identified

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Chemistry World news article on Dalton Transactions fluorescent sensor paper

Chemistry World have spotted Zhilin Wang’s recently published paper in Dalton Transactions.

The researchers work entitled ‘A Zn2+-specific turn-on fluorescent probe for ratiometric sensing of pyrophosphate in both water and blood serum’ is a highly interesting piece using inorganic chemistry to make a promising fluorescent biosensor. See what Chemistry World thought about it and access the rest of the news story or read the original paper.

A Zn2+-specific turn-on fluorescent probe for ratiometric sensing of pyrophosphate in both water and blood serum
Jinghan Wen, Zhirong Geng, Yuxin Yin, Zhong Zhang and Zhilin Wang
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01262A, Paper

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HOT Article: Serendipitous ionic liquids by reactive distillation

In this Dalton Transactions Hot article, ionic liquids are made by reactive distillation.

Peter Licence and co-workers from the University of Nottingham discovered this method by accident while researching [C4C1Im][BF4], when they realised that the substance they had after distillation was very different to their starting materials. Further investigation revealed they had created a borane-substituted imidazol-2-ylidene, a compound with potential to be an excellent solvent for a wide variety of reactions.

The conventional technique to make these type of ionic liquids is via a direct nucleophilic reaction, which is experimentally difficult as the starting reagents are highly reactive. This distillation technique is particularly good, not only because of the stability and availability of the starting materials, but because of the high purity of the obtained products.

Read on to find out more details about this technique.

Borane-substituted imidazol-2-ylidenes: syntheses in vacuo
Alasdair W. Taylor, Kevin R. J. Lovelock, Robert G. Jones and Peter Licence
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01240H, Paper

READ FOR FREE until February 11th

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