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HOT Article: Accidentally on purpose, a relatively simple model to study magneto-structural relationships in complex Mn clusters

23 Sep 2011
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In this HOT Article, the serendipitous self-assembly of the complex [MnIII2ZnII2(Ph-sao)2(Ph-saoH)4(hmp)2], whose magnetic core consists solely of two symmetry equivalent Mn(III) ions linked by two symmetry equivalent –N–O– moieties, provided Brechin and co-workers with a relatively simple model complex with which to study the magneto-structural relationships in more complicated polynuclear oxime-bridged Mn(III) cluster compounds.

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Accidentally on purpose: construction of a ferromagnetic, oxime-based [MnIII2] dimer
Ross Inglis, Edel Houton, Junjie Liu, Alessandro Prescimone, Joan Cano, Stergios Piligkos, Stephen Hill, Leigh F. Jones and Euan K. Brechin
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT11118C
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