Optical electron transfer for smart devices

In molecular computing how does structure influence electron transfer ?

In their Dalton Transactions Hot Article, Frederic Paul and his team look at the intramolecular electron transfer in a fluorenyl iron compound with a view to optimising mixed valent compounds for smart molecular devices.

Optical electron transfer through 2,7-diethynylfluorene spacers in mixed-valent complexes containing electron-rich “(η2-dppe)(η5-C5Me5)Fe” endgroups
Floriane Malvolti, Cedric Rouxel, Olivier Mongin, Philippe Hapiot, Loic Toupet, Mireille Blanchard-Desce and Frédéric Paul, Dalton Trans., 2011, DOI: 10.1039/C1DT10231A

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