Marcetta Y. Darensbourg and colleagues from Texas A& M University, look at NiFe-heterobimetallic complexes, and their bonding and structure, to increase their understanding of the features of natural bimetallic sites in enzymes.
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cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3
Chung-Hung Hsieh, Rachel B. Chupik, Scott M. Brothers, Michael B. Hall and Marcetta Y. Darensbourg
Dalton Trans., 2011, DOI: 10.1039/C1DT10438A
