Phosphine, arsine and thioether complexes with metal fluorides are especially rare. In this Hot Article, Bill Levason and colleagues report the first examples of soft-donor alkyl phosphine complexes of TiF4.
Taking TiF4 complexes to extremes – the first examples with phosphine co-ligands
Marek Jura, William Levason, Edmund Petts, Gillian Reid, Michael Webster and Wenjian Zhang
Dalton Trans., 2010, DOI: 10.1039/C0DT00747A
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