Scientists from Japan have discovered that the synchronization of Cu and Ce valence charge in Cu/CeO2 catalysts can improve the catalytic activity for NO reduction. They used an operando time-resolved XAFS technique at the Cu and Ce k-edges to study the catalytic NO reduction under periodic (rich-lean cycling) operation.
Read the details in this PCCP communication:
Operando XAFS study of catalytic NO reduction over Cu/CeO2: the effect of copper–ceria interaction under periodic operation
Yasutaka Nagai, Kazuhiko Dohmae, Yusaku F. Nishimura, Hitoshi Kato, Hirohito Hirata and Naoki Takahashi DOI: 10.1039/C3CP44316G