Interview: Keiichiro Ogawa talks to CrystEngComm

Keiichiro Ogawa talks to CrystEngComm about his love of opera and colours in organic crystals
 

Keiichiro Ogawa is a professor of chemistry at the Graduate School of Arts and Sciences, University of Tokyo, Japan. His research is aimed at the understanding and control of the dynamic behaviour of organic compounds and other molecular assemblies in crystals. Keiichiro was awarded the Crystallographic Society Japan Award in 1997 and recently a Chemical Society of Japan Contribution Award in 2007. He is a member of the CrystEngComm Advisory Board. 

Why did you to become a scientist?

Having grown up in a family of three generations of scientists, I have wanted to be a scientist since boyhood. In particular, I was intrigued by science because it unravels the mysteries of the universe, and leads to technologies that contribute to our wellbeing.
 

What projects are you working on at the moment?

My group is working on solid-state reactions in organic crystals, particularly those related with color-changing phenomena, i.e., photochromism and thermochromism.
 

What do you think will be the next big breakthrough in your field?

Such a prediction is difficult but it will probably be the emergence of completely new methods for measuring these phenomena. If this happens it could provide totally a new insights into the world of matter, as brought about by the arrival of the analytical techniques in X-ray crystallography and NMR spectroscopy.
 

How do you think crystal engineering will develop in the next five years?

As methodologies for detection of minor products are refined, organic solid state reaction mechanisms should become better understood. This will give us much a more comprehensive picture of what happens in a sequence of solid-state reactions.
 

What is the most rewarding aspect of your work?

The excitement of presenting new findings and/or interpretations to an appreciative and expert audience!  
 

 

What is the secret to a successful research group?

Good people and good projects are the most essential components for successful scientific research. I’ve been fortunate in having an excellent research colleague, very good students and some challenging research topics. 

What achievement are you most proud of?

I am particularly proud at having found that an apparent shortening of the central bond of stilbene-type molecules is caused by the torsional vibrations in crystals (K. Ogawa et al., JACS, 1992, 114, 1041). This finding led to the discovery of a more prominent molecular motion, i.e., pedal motion in crystals (J. Harada and K. Ogawa, Chem. Soc. Rev., 2009, 38, 2244.).
 

What advice would you give to a young scientist?

Young scientists must understand their principal research topic as deeply as possible, while being aware of the broader thrust of the field. The wider view can often provide insights into the subject you are most interested in. 

What would you do if you weren’t a scientist?

My hobby is opera singing and my dream would be to be a professional singer, though I know I don’t have sufficient talent to start this career. Music can move one’s heart instantly, even within a second. Science can also do this, though not so quickly as in music. The important thing for me is that they both give joy.
 

What is your favourite place to be?

If I must live and work in one place, it would definitely be Tokyo. I have lived in Tokyo since my birth and I find it a vibrant, safe, and beautiful city. I like to visit other places, particularly in foreign countries, but I always enjoy returning home.
 

More about Keiichiro on his webpage at the University of Tokyo. 

Read some of Keiichiro’s research in the following CrystEngComm articles: 

Crystalline-state conformational change of β-nitrostyrenes and its freezing at low temperature
Jun Harada, Mayuko Harakawa and Keiichiro Ogawa
CrystEngComm, 2009, 11, 638-642 DOI: 10.1039/B815869J
 
Single crystal cis–trans photoisomerizations of 2-(9-anthrylmethylene)-1-indanones
Jun Harada, Mayuko Harakawa, Shingo Sugiyama and Keiichiro Ogawa
CrystEngComm, 2009, 11, 1235-1239 DOI: 10.1039/B821900A
 
Conformational change of all-trans-1,6-diphenyl-1,3,5-hexatriene in two crystalline forms
Jun Harada, Mayuko Harakawa and Keiichiro Ogawa
CrystEngComm, 2008, 10, 1777-1781 DOI: 10.1039/B811220G
 

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Hot Article: Arty silca-coated nanocrystals

Ping Yang and co-workers from the University of Jinan, China have created SiO2-coated CdTe nanocrystal using

a controlled sol–gel reaction. Look at more images of these beautiful nanocrystals which show how science can be art and find out more about the research in this CrystEngComm Hot Article.

Ping Yang, Zhimin Yuan, Jie Yang, Aiyu Zhang, Yongqiang Cao, Qinghui Jiang, Ruixia Shi, Futian Liu and Xin Cheng
CrystEngComm, 2011, DOI: 10.1039/C0CE00350F

READ FOR FREE! Until November 25th.

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HOT Article: A crystalline gas?

In this CrystEngComm Hot Article, Andrzej Katrusiak and colleagues discuss the isobaric freezing of 1,1,1-trichloroethane to yields crystals. These crystals could shed new light on the range of intermolecular interactions that are capable of controlling molecular re-orientation and arrangement.

Crystalline gas of 1,1,1-trichloroethane 
Maciej Bujak, Marcin Podsiadło and Andrzej Katrusiak

CrystEngComm, 2011,DOI: 10.1039/C0CE00493F

READ FOR FREE! Until 25th November.

 

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This week’s CrystEngSelects

Here is this week’s selection of advanced articles of interest to crystal engineers from across the RSC journals.

Articles are chosen from:
ChemComm,
CrystEngComm,
Dalton Transactions,
Journal of Materials Chemistry,
New Journal of Chemistry,
Nanoscale,
Organic & Biomolecular Chemistry.

 

Qilong Zhu, Tianlu Sheng, Ruibiao Fu, Chunhong Tan, Shengmin Hu and Xintao Wu
Chem. Commun., 2010, Advance Article
DOI: 10.1039/C0CC02550J, Communication
 
Jun Jiang, Min-Rui Gao, Yun-Hao Qiu, Guang-Sheng Wang, Lei Liu, Guo-Bin Cai and Shu-Hong Yu
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00153H, Paper
 
Jacek Klinowski, Filipe A. Almeida Paz, Patrícia Silva and João Rocha
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00708K, Perspective
 
Ping Yang, Zhimin Yuan, Jie Yang, Aiyu Zhang, Yongqiang Cao, Qinghui Jiang, Ruixia Shi, Futian Liu and Xin Cheng
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00350F, Paper
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00281J, Paper
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00168F, Paper
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00340A, Paper
 
Khemchand Dewangan, Nupur Nikkan Sinha, Prashant K. Sharma, Avinash C. Pandey, N. Munichandraiah and N. S. Gajbhiye
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00271B, Paper
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C004371K, Paper
 
Xing Li, Mei-Qin Zha, Shui-Ying Gao, Paul J. Low, Yuan-Zhao Wu, Ning Gan and Rong Cao
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00382D, Paper
 
Baoji Hu, Kunlun Ding, Tianbin Wu, Xiaosi Zhou, Honglei Fan, Tao Jiang, Qian Wang and Buxing Han
Chem. Commun., 2010, Advance Article
DOI: 10.1039/C0CC03485A, Communication
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00553C, Communication
 
Michaela Meyns, Neus G. Bastus, Yuxue Cai, Andreas Kornowski, Beatriz H. Juárez, Horst Weller and Christian Klinke
J. Mater. Chem., 2010, Advance Article
DOI: 10.1039/C0JM03004J, Communication
 
Maciej Bujak, Marcin Podsiadło and Andrzej Katrusiak
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00493F, Communication
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00507J, Communication
 
Li-Min Zhao, Zhen-Jie Zhang, Shi-Yuan Zhang, Ping Cui, Wei Shi, Bin Zhao, Peng Cheng, Dai-Zheng Liao and Shi-Ping Yan
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00315H, Paper
 
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT01064B, Paper
 
Xu Zou, Bingbing Liu, Quanjun Li, Zepeng Li, Bo Liu, Wei Wu, Qiang Zhao, Yongming Sui, Dongmei Li, Bo Zou, Tian Cui, Guangtian Zou and Ho-Kwang Mao
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00170H, Paper
 
J. Mater. Chem., 2010, Advance Article
DOI: 10.1039/C0JM02355H, Paper
 
Poulami Jana, Sibaprasad Maity and Debasish Haldar
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00143K, Paper
 
Huaibin Shen, Jin Zhong Niu, Hongzhe Wang, Xiaomin Li, Lin Song Li and Xia Chen
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00709A, Paper
 
Ana Belén Lago, Rosa Carballo, Nuria Fernández-Hermida and Ezequiel M. Vázquez-López
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00330A, Paper
 
Changzhou Yuan, Xiaogang Zhang, Linrui Hou, Laifa Shen, Diankai Li, Fang Zhang, Chuangang Fan and Jiamao Li
J. Mater. Chem., 2010, Advance Article
DOI: 10.1039/C0JM02174A, Paper
 
Alberto Naldoni, Alessandro Minguzzi, Alberto Vertova, Vladimiro Dal Santo, Laura Borgese and Claudia L. Bianchi
J. Mater. Chem., 2010, Advance Article
DOI: 10.1039/C0JM02446E, Paper
 
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00388C, Paper
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CrystEngComm Poster Prize winner Raeeun Lee

Congratulations to Raeeun Lee from the Osaka University in Japan– recent winner of the CrystEngComm Poster Prize at the 60th JSCC Symposium which took place in Osaka from the 27th-30th September!

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Top Ten most-read CrystEngComm articles in September

Read the most-read CrystEngComm articles of September 2010, listed below:

Chang-Chun Ji, Jing Li, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C003986A
 
Kai Jiang, Lu-Fang Ma, Xiao-Yuan Sun and Li-Ya Wang, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00190B
 
Shuang Wang, Jie Qin, Xin-Long Wang, Chao Qin, Ting-Ting Li and Zhong-Min Su, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C004065G
 
Anirban Karmakar and Israel Goldberg, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00474J
 
Rui-Qin Zhong, Ru-Qiang Zou and Qiang Xu, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00150C
 
Christer B. Aakeröy, Neil R. Champness and Christoph Janiak, CrystEngComm, 2010, 12, 22-43
DOI: 10.1039/B919819A
 
Jing-Xin Meng, Yang-Guang Li, Hai Fu, Xiao-Lan Wang and En-Bo Wang, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00356E
 
Joseph G. Nguyen, Kristine K. Tanabe and Seth M. Cohen, CrystEngComm, 2010, 12, 2335-2338
DOI: 10.1039/C000154F
 
Wenbing Yuan, Ana Lazuen Garay, Anne Pichon, Rob Clowes, Colin D. Wood, Andrew I. Cooper and Stuart L. James, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00486C
 
Xianchun Liu, Yan Xing and Xizheng Liu, CrystEngComm, 2010, 12, 383-386
DOI: 10.1039/B911000C

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Hydrogen bond defined

An IUPAC task group has recently published their recommendations for the definition for the hydrogen bond.

“The hydrogen bond is an attractive interaction between a hydrogen atom from a molecule or a molecular fragment X–H in which X is more electronegative than H, and an atom or a group of atoms in the same or a different molecule, in which there is evidence of bond formation.”

The recommendations continue with a list of experimental and theoretical criteria that can be used as evidence for the presence of the hydrogen bond, and finish with characteristics that are typical of hydrogen bonded systems.

The task group membership includes Professor Gautam Desiraju (Bangalore, India), founding Editorial Board member, and current Advisory Board member of CrystEngComm.

For more information on the task group and to view the provisional recommendation see the IUPAC report.

Follow the links below to read two CrystEngComm Highlights with a focus on hydrogen bonding:

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Hot Article: Engineering Crystals for Painkilling Performance

The marketed crystalline form of the painkiller celecoxib (Cel-III), COX-2 selective anti-inflammatory drug, has poor solubility. Various strategies to improve this and increase its bioavailability have been published including the use of crystalline forms of the sodium salt. This study by Julius Remenar and colleagues in the USA describes the structural findings and insights that have resulted from their effort to harness and understand the sodium salts of Celecoxib. Find out more in this CrystEngComm ‘Hot Article’.

Celecoxib sodium salt: engineering crystal forms for performanceCelecoxib sodium salt: engineering crystal forms for performance
Julius F. Remenar, Mark D. Tawa, Matthew L. Peterson, Örn Almarsson, Magali B. Hickey and Bruce M. Foxman
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00475H, Paper

READ FOR FREE! Until November 18th.

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Hot Article: Tetracarboxylate pillars

Cocrystal controlled solid-state synthesis of a rigid tetracarboxylate ligand that pillars both square grid and Kagomé lattice layersMichael Zaworotko and colleagues from the University of South Florida demonstrate how a tetracarboxylic acid (BIPA-TC) is prepared using C3S3 and then used as a ligand to generate two isomeric nets that represent examples of “ligand-to-ligand” pillaring. To find out more about this ‘Hot Article’ read the full communication here.

Cocrystal controlled solid-state synthesis of a rigid tetracarboxylate ligand that pillars both square grid and Kagomé lattice layers 
Jason A. Perman, Amy J. Cairns, Łukasz Wojtas, Mohamed Eddaoudi and Michael J. Zaworotko
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00542H, Communication

READ FOR FREE! Until November 16th.

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π-stacked catenenes

Towards catenanes using π-stacking interactions and their influence on the spin-state of a bis(2,2′:6′,2″-terpyridine)iron(ii) domainAn article of interest to CrystEngComm readers from our sister journal Dalton Transactions has been published online.  The article, by Catherine Housecroft and colleagues at the University of Basel, looks at catenanes which use π-stacking interactions.  They show that multiple face-to-face π-stacking of arene and pyridine rings occurs in [FeL2]2+ and [RuL2]2+ (L = 6,6″-bis(4-methoxyphenyl)-4′-phenyl-2,2′:6′,2″-terpyridine) and causes [Fe(2)2][PF6]2 to be high-spin. 

Read more in the full Dalton Transactions article here: 
Towards catenanes using π-stacking interactions and their influence on the spin-state of a bis(2,2′:6′,2″-terpyridine)iron(II) domain
Sven Y. Brauchli, Edwin C. Constable, Kate Harris, Daniel Häussinger, Catherine E. Housecroft, Pirmin J. Rösel and Jennifer A. Zampese
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00743A, Paper

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