HOT Article: A non-linear optical crystal

In this CrystEngComm Hot article, Sunil Verma and co-workers have produced a large single crystal of lithium pnitrophenolate trihydrate, which can be used as a non-linear optical material.

Non-linear optical materials can be used in lasers, and organic NLO materials are particularly desirable because they have higher non-linearity and better laser damage resistance when compared to inorganic materials.

This article is significant because the authors have managed to grow a large size crystal, which is normally difficult due to the weakness of the van der Waals and hydrogen bonds holding the molecules together.

Read the full article to find out more about the slow cooling solution growth method used…

Solubility, crystal growth, morphology, crystalline perfection and optical homogeneity of lithium p-nitrophenolate trihydrate, a semiorganic NLO crystal
S. Dinakaran, Sunil Verma and S. Jerome Das
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00663G, Paper

READ FOR FREE until 3rd March 2011

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Psychedelic biodegradable copolyesters

Check out these amazing images in a recent CrystEngComm Advance Article by Zhaobin Qiu and Yan Yang.

Crystallisation kinectics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) depend significantly on both the comonomer composition and crystallisation temperature.  This should yield a better understanding of the structure-property relationship of biodegradable polymers.

Crystallisation kinetics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) copolyesters: effects of comonomer composition and crystallization temperature
Yan Yang and Zhaobin Qiu*
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00598c

For more fascinating crystal images, why not take a look at our Crystal Clear blog posts

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This week’s CrystEngSelects

Here is this week’s selection of advanced articles of interest to crystal engineers from across the RSC journals.

Articles are chosen from:
ChemComm,
CrystEngComm,
Dalton Transactions,
Journal of Materials Chemistry,
New Journal of Chemistry,
Nanoscale,
Organic & Biomolecular Chemistry.
Peng Guo, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01384F, Paper
 
Nikolay A. Pushkarevsky, Sergey N. Konchenko, Manfred Zabel, Michael Bodensteiner and Manfred Scheer, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01587C, Paper
 
Khoa V. Le, Satoshi Aya, Yuji Sasaki, Hyunhee Choi, Fumito Araoka, Kenji Ema, Jozef Mieczkowski, Antal Jakli, Ken Ishikawa and Hideo Takezoe, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM04009F, Communication
 
Chang-Yan Cao, Wei Guo, Zhi-Min Cui, Wei-Guo Song and Wei Cai, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03749D, Paper
 
Jianjun Wu, Fuqiang Huang, Xujie Lü, Ping Chen, Dongyun Wan and Fangfang Xu, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03252B, Paper
 
Qian Hou, Yanzhen Zheng, Jian-Feng Chen, Weilie Zhou, Jie Deng and Xia Tao, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03327H, Paper
 
Thomas van Leeuwen, Thomas C. Pijper, Jetsuda Areephong, Ben L. Feringa, Wesley R. Browne and Nathalie Katsonis, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03626A, Paper
 
Seong-Jun Yoon and SooYoung Park, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03711G, Paper
 
Yang Xiaowei, Zeng Yanwei, Mo Leiqing and Han Longxiang, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM02689A, Paper
 
Tao Ling, Ming-Ke Wu, Kai-Yang Niu, Jing Yang, Zhi-Ming Gao, Jing Sun and Xi-Wen Du, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03530K, Paper
 
Xiaotang Lu, Zhongbin Zhuang, Qing Peng and Yadong Li, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05064D, Communication
 
Zhen-Zhong Lu, Rui Zhang, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05015F, Communication
 
Shigehisa Akine, Sayaka Hotate, Takashi Matsumoto and Tatsuya Nabeshima, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04998K, Communication
 
Lian-Xu Shi and Chuan-De Wu, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05074A, Communication
 
Daniel G. Stroppa, Luciano A. Montoro, Armando Beltrán, Tiago G. Conti, Rafael O. da Silva, Juan Andrés, Edson R. Leite and Antonio J. Ramirez, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04570E, Communication
 
Johannes Forster, Benedikt Rösner, Marat M. Khusniyarov and Carsten Streb, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05536K, Communication
 
Dong-Ying Du, Jun-Sheng Qin, Yang-Guang Li, Shun-Li Li, Ya-Qian Lan, Xin-Long Wang, Kui-Zhan Shao, Zhong-Min Su and En-Bo Wang, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04343E, Communication
 
T. Shanmugapriya, R. Vinayakan, K. George Thomas and P. Ramamurthy, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00374C, Paper
 
Ruibiao Fu, Shengmin Hu and Xintao Wu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00791A, Paper
 
Lydia Brelot, Xiao-yu Cao, Jack Harrowfield, Jean-Marie Lehn, Kari Rissanen and Luca Russo, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00814A, Paper
 
Wei Tang, Dongliang Huang, Lili Wu, Chaozhong Zhao, Lingling Xu, Hong Gao, Xitian Zhang and Weibo Wang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00710B, Paper
 
Sen-Tsun Jean and Yung-Chiun Her, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00480D, Paper
 
Liliana Dobrzańska, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00469C, Paper
 
Jing Zhou, Gaoling Zhao, Bin Song and Gaorong Han, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00793E, Paper
 
Yangang Sun, Rujia Zou, Qiwei Tian, Jianghong Wu, Zhigang Chen and Junqing Hu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00600A, Paper
 
Chia-Hao Lee, Fang-Yi Su, Yi-Hsiu Lin, Chih-Ho Chou and Kwang-Ming Lee, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00610F, Paper
 
Rujia Zou, Junqing Hu, Zhenyu Zhang, Zhigang Chen and Meiyong Liao, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00543F, Paper
 
Hongyu Liu and Qing Yang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00432D, Paper
 
Maria Altamura, Antonio Guidi, Loïc Jierry, Paola Paoli and Patrizia Rossi, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00595A, Paper
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Top Ten most-read CrystEngComm articles in December

Read the most-read CrystEngComm articles of December 2010, listed below:

 

Hailong Sun, Haibo Mei, Guanghui An, Jianlin Han and Yi Pan, CrystEngComm, 2011, 13, 734-737
DOI: 10.1039/C0CE00471E
 
Yun Ling, Lei Zhang, Jing Li and Miao Du, CrystEngComm, 2011, 13, 768-770
DOI: 10.1039/C0CE00775G
 
Michael J. Turner, Joshua J. McKinnon, Dylan Jayatilaka and Mark A. Spackman, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00683A
 
Kai Jiang, Lu-Fang Ma, Xiao-Yuan Sun and Li-Ya Wang, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00190B
 
Xiu-Li Wang, Hong-Yan Lin, Bao Mu, Ai-Xiang Tian, Guo-Cheng Liu and Ning-Hai Hu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00400F
 
Wenzhong Wang, Ya Tu, Pengcheng Zhang and Guling Zhang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00563K
 
Yun-Liang Jiang, Yu-Ling Wang, Jing-Xiang Lin, Qing-Yan Liu, Zhang-Hui Lu, Na Zhang, Jia-Jia-Wei and Li-Qin Li, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00431F
 
Shunshun Xiong, Sujing Wang, Xinjun Tang and Zhiyong Wang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00422G
 
Zuo-Xi Li, Xin Chu, Guang-Hua Cui, Yu Liu, Le Li and Gang-Lin Xue, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00865F
 

To keep up-to-date with all the best crystal engineering research articles, sign up for the journal’s e-alerts here.

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Chemistry World news article on CrystEngComm enamel regeneration paper

A CrystEngComm Hot article on using nanofibre mats to remineralise tooth enamel has been picked up by the society magazine Chemistry World.

This fascinating paper from Stephen Mann’s group at Bristol University, describes a way to reduce hypersensitivity in teeth.

Read the Chemistry World news story, or access the original paper:

Electrospun mats of PVP/ACP nanofibres for remineralization of enamel tooth surfaces
Jane Fletcher, Dominic Walsh, Christabel Emma Fowler and Stephen Mann
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00806K, Paper

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Highlight: Controlling flexibility in crystal engineering

Here, Christopher Pigge (University of Iowa, US) discusses both the advantages and disadvantages that can arise when using flexible components in crystal engineering.  Both organic (mainly triaroylbenzenes) and metal-organic framework systems derived from flexible ligands are reviewed.

Read the Highlight by Christopher Pigge here.

Losing control? “Design” of crystalline organic and metal-organic networks using conformationally flexible buidling blocks
F. Christopher Pigge
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00417k

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HOT Article: Nanofibre mats remineralize tooth enamel

Free to access until Tuesday 15th February 2011!

In this CrystEngComm Hot Article, Stephen Mann and co-workers demonstrate the use of electrospun mats of amorphous calcium phosphate (ACP)/poly(vinylpyrrolidone) (PVP) nano- and microfibres to promote in vitro remineralization of dental enamel and dentine tubule occlusion.

The method is performed under clinically relevant conditions and holds the potential for a new approach to the regeneration of enamel and the alleviation of dentine hypersensitivity.

Read more:
Electrospun mats of PVP/ACP nanofibres for remineralization of enamel tooth surfaces
Jane Fletcher, Dominic Walsh, Christabel Emma Fowler and Stephen Mann,
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00806K, Paper

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January Crystal Clear: Strontium sulphate stars

This month’s Crystal Clear is a strontium sulphate nano-star, made by a two step growth process from SrCrO4 nanowires in a solution of Na2SO4 at room temperature.

Liang Zhen and colleagues at Harbin Institute of Technology, China published this work in Issue 3 of CrystEngComm

Synthesis and formation process of SrSO4 sisal-like hierarchical structures at room temperature
Wen-Shou Wang, Liang Zhen, Cheng-Yan Xu and Wen-Zhu Shao
CrystEngComm, 2011, 13, 620-625
DOI: 10.1039/C0CE00062K, Paper

READ FOR FREE until 21st February

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FREE Chemistry World Webinar

Chemistry World are hosting the first Chemistry World webinar on 31 January. This will include an active audience in Burlington House and be FREE to watch online.

Find out more by reading the blog, and to find out how to register.

Connecting Chemistry and Mass Spectrometry on the Internet – ChemSpider
Monday 31 January 2011


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HOT Article: Use of DFT for physisorption

This latest work from Marcus A. Neumann’s group uses dispersion-corrected density functional theory to look at the energy minimisation of 2,6-bis(2,4-dichlorobenzylidene)cyclohexanone. In this CrystEngComm Hot article they discover that this method predicts the low-temperature phase transition seen in experiment.

As the authors state ‘we believe that DFT-D energy minimisation provides a valuable tool since the calculations have now been shown to be sufficiently reliable to guide experimental studies towards targets most likely to exhibit interesting temperature dependent variation’

READ the full article for free until 18th February

Experimental verification of a subtle low-temperature phase transition suggested by DFT-D energy minimisation
Andrew D. Bond, Katarzyna A. Solanko, Jacco van de Streek and Marcus A. Neumann
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00676A, Communication

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