CrystEngComm Blog

Psychedelic biodegradable copolyesters

02 Feb 2011

Check out these amazing images in a recent CrystEngComm Advance Article by Zhaobin Qiu and Yan Yang.

Crystallisation kinectics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) depend significantly on both the comonomer composition and crystallisation temperature. This should yield a better understanding of the structure-property relationship of biodegradable polymers.

Crystallisation kinetics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) copolyesters: effects of comonomer composition and crystallization temperature
Yan Yang and Zhaobin Qiu*
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00598c

For more fascinating crystal images, why not take a look at our Crystal Clear blog posts

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This week’s CrystEngSelects

28 Jan 2011

By Vibhuti Patel, Deputy Editor.

Here is this week’s selection of advanced articles of interest to crystal engineers from across the RSC journals.

Articles are chosen from:
ChemComm,
CrystEngComm,
Dalton Transactions,
Journal of Materials Chemistry,
New Journal of Chemistry,
Nanoscale,
Organic & Biomolecular Chemistry.

Three 2D Ag^I-framework isomers with helical structures controlled by the chirality of camphor-10-sulfonic acid

Peng Guo, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01384F, Paper

Dimerization of pentanuclear clusters [Fe₃Q(AsMe)(CO)₉] (Q = Se, Te) as a conversion pathway to novel cubane-like aggregates

Nikolay A. Pushkarevsky, Sergey N. Konchenko, Manfred Zabel, Michael Bodensteiner and Manfred Scheer, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01587C, Paper

Liquid crystalline amorphous blue phase and its large electrooptical Kerr effect

Khoa V. Le, Satoshi Aya, Yuji Sasaki, Hyunhee Choi, Fumito Araoka, Kenji Ema, Jozef Mieczkowski, Antal Jakli, Ken Ishikawa and Hideo Takezoe, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM04009F, Communication

Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes

Chang-Yan Cao, Wei Guo, Zhi-Min Cui, Wei-Guo Song and Wei Cai, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03749D, Paper

Improved visible-light photocatalysis of nano-Bi₂Sn₂O₇ with dispersed s-bands

Jianjun Wu, Fuqiang Huang, Xujie Lü, Ping Chen, Dongyun Wan and Fangfang Xu, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03252B, Paper

Visible-light-response iodine-doped titanium dioxide nanocrystals for dye-sensitized solar cells

Qian Hou, Yanzhen Zheng, Jian-Feng Chen, Weilie Zhou, Jie Deng and Xia Tao, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03327H, Paper

Reversible photochemical control of cholesteric liquid crystals with a diamine-based diarylethene chiroptical switch

Thomas van Leeuwen, Thomas C. Pijper, Jetsuda Areephong, Ben L. Feringa, Wesley R. Browne and Nathalie Katsonis, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03626A, Paper

Polymorphic and mechanochromic luminescence modulation in the highly emissive dicyanodistyrylbenzene crystal: secondary bonding interaction in molecular stacking assembly

Seong-Jun Yoon and SooYoung Park, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03711G, Paper

Rapid synthesis of quasi-spherical (Ba,Sr)TiO₃ nanocrystals via a microwave-activated glycothermal approach

Yang Xiaowei, Zeng Yanwei, Mo Leiqing and Han Longxiang, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM02689A, Paper

Spongy structure of CdS nanocrystals decorated with dye molecules for semiconductor sensitized solar cells

Tao Ling, Ming-Ke Wu, Kai-Yang Niu, Jing Yang, Zhi-Ming Gao, Jing Sun and Xi-Wen Du, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03530K, Paper

Wurtzite Cu₂ZnSnS₄ nanocrystals: a novel quaternary semiconductor

Xiaotang Lu, Zhongbin Zhuang, Qing Peng and Yadong Li, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05064D, Communication

[WS₄Cu₃I₂]⁻ and [WS₄Cu₄]²⁺ secondary building units formed a metal–organic framework: Large tubes in a highly interpenetrated system

Zhen-Zhong Lu, Rui Zhang, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05015F, Communication

Spontaneous enrichment of one-handed helices by dissolution of quasiracemic crystals of a tetranuclear single helical complex

Shigehisa Akine, Sayaka Hotate, Takashi Matsumoto and Tatsuya Nabeshima, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04998K, Communication

A nanoporous metal–organic framework with accessible Cu²⁺ sites for the catalytic Henry reaction

Lian-Xu Shi and Chuan-De Wu, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05074A, Communication

Anomalous oriented attachment growth behavior on SnO₂ nanocrystals

Daniel G. Stroppa, Luciano A. Montoro, Armando Beltrán, Tiago G. Conti, Rafael O. da Silva, Juan Andrés, Edson R. Leite and Antonio J. Ramirez, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04570E, Communication

Tuning the light absorption of a molecular vanadium oxide system for enhanced photooxidation performance

Johannes Forster, Benedikt Rösner, Marat M. Khusniyarov and Carsten Streb, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05536K, Communication

An unprecedented 3D 8-connected pure inorganic framework based on nanosized {[Na₁₂PO₁₆H₂₄]⊂[P₄Mo₆O₃₁H₆]₄}¹⁵⁻ clusters and zinc cations

Dong-Ying Du, Jun-Sheng Qin, Yang-Guang Li, Shun-Li Li, Ya-Qian Lan, Xin-Long Wang, Kui-Zhan Shao, Zhong-Min Su and En-Bo Wang, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04343E, Communication

Synthesis of CdS nanorods and nanospheres: shape tuning by the controlled addition of a sulfide precursor at room temperature

T. Shanmugapriya, R. Vinayakan, K. George Thomas and P. Ramamurthy, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00374C, Paper

Syntheses, crystal structures, thermal stabilities, magnetism and luminescence of two 3D metal phosphonates

Ruibiao Fu, Shengmin Hu and Xintao Wu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00791A, Paper

A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles

Lydia Brelot, Xiao-yu Cao, Jack Harrowfield, Jean-Marie Lehn, Kari Rissanen and Luca Russo, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00814A, Paper

Surface plasmon enhanced ultraviolet emission and observation of random lasing from self-assembly Zn/ZnO composite nanowires

Wei Tang, Dongliang Huang, Lili Wu, Chaozhong Zhao, Lingling Xu, Hong Gao, Xitian Zhang and Weibo Wang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00710B, Paper

Growth mechanism and cathodoluminescence properties of indium hydroxide nanocubes synthesized from a simple aqueous solution

Sen-Tsun Jean and Yung-Chiun Her, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00480D, Paper

Anion directed supramolecular architectures of silver(I) complexes with 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene and a reversible, solvent-induced structural change during a single-crystal-to-single-crystal transformation

Liliana Dobrzańska, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00469C, Paper

Solvent-controlled synthesis of three-dimensional TiO₂ nanostructures via a one-step solvothermal route

Jing Zhou, Gaoling Zhao, Bin Song and Gaorong Han, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00793E, Paper

Hydrothermal synthesis, growth mechanism, and properties of three-dimensional micro/nanoscaled hierarchical architecture films of hemimorphite zinc silicate

Yangang Sun, Rujia Zou, Qiwei Tian, Jianghong Wu, Zhigang Chen and Junqing Hu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00600A, Paper

Anion-controlled assemblies of C–HO hydrogen bonded grid, stair or bilayer structures by L-shaped pyridinium salts

Chia-Hao Lee, Fang-Yi Su, Yi-Hsiu Lin, Chih-Ho Chou and Kwang-Ming Lee, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00610F, Paper

SnO₂ nanoribbons: excellent field-emitters

Rujia Zou, Junqing Hu, Zhenyu Zhang, Zhigang Chen and Meiyong Liao, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00543F, Paper

A two-step temperature-raising process to gold nanoplates with optical and surface enhanced Raman spectrum properties

Hongyu Liu and Qing Yang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00432D, Paper

Uncommon crystal motif of brucine in its diastereomeric salt with (11-oxo-11H-dibenzo[b,f][1,4]thiazepin-10-yl)-acetic acid: a case of possible crystallization-induced dynamic resolution

Maria Altamura, Antonio Guidi, Loïc Jierry, Paola Paoli and Patrizia Rossi, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00595A, Paper

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Chemistry World news article on CrystEngComm enamel regeneration paper

26 Jan 2011

By Holly Sheahan, Development Editor.

A CrystEngComm Hot article on using nanofibre mats to remineralise tooth enamel has been picked up by the society magazine Chemistry World.

This fascinating paper from Stephen Mann’s group at Bristol University, describes a way to reduce hypersensitivity in teeth.

Read the Chemistry World news story, or access the original paper:

Electrospun mats of PVP/ACP nanofibres for remineralization of enamel tooth surfaces
Jane Fletcher, Dominic Walsh, Christabel Emma Fowler and Stephen Mann
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00806K, Paper

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Highlight: Controlling flexibility in crystal engineering

25 Jan 2011

By Carl Saxton.

Here, Christopher Pigge (University of Iowa, US) discusses both the advantages and disadvantages that can arise when using flexible components in crystal engineering. Both organic (mainly triaroylbenzenes) and metal-organic framework systems derived from flexible ligands are reviewed.

Read the Highlight by Christopher Pigge here.

Losing control? “Design” of crystalline organic and metal-organic networks using conformationally flexible buidling blocks
F. Christopher Pigge
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00417k

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HOT Article: Nanofibre mats remineralize tooth enamel

24 Jan 2011

By Jo Pugh, Publishing Editor.

Free to access until Tuesday 15th February 2011!

In this CrystEngComm Hot Article, Stephen Mann and co-workers demonstrate the use of electrospun mats of amorphous calcium phosphate (ACP)/poly(vinylpyrrolidone) (PVP) nano- and microfibres to promote in vitro remineralization of dental enamel and dentine tubule occlusion.

The method is performed under clinically relevant conditions and holds the potential for a new approach to the regeneration of enamel and the alleviation of dentine hypersensitivity.

Read more:
Electrospun mats of PVP/ACP nanofibres for remineralization of enamel tooth surfaces
Jane Fletcher, Dominic Walsh, Christabel Emma Fowler and Stephen Mann,
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00806K, Paper

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January Crystal Clear: Strontium sulphate stars

21 Jan 2011

By Holly Sheahan, Development Editor.

This month’s Crystal Clear is a strontium sulphate nano-star, made by a two step growth process from SrCrO₄ nanowires in a solution of Na₂SO₄ at room temperature.

Liang Zhen and colleagues at Harbin Institute of Technology, China published this work in Issue 3 of CrystEngComm

Synthesis and formation process of SrSO4 sisal-like hierarchical structures at room temperature
Wen-Shou Wang, Liang Zhen, Cheng-Yan Xu and Wen-Zhu Shao
CrystEngComm, 2011, 13, 620-625
DOI: 10.1039/C0CE00062K, Paper

READ FOR FREE until 21st February

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FREE Chemistry World Webinar

21 Jan 2011

By Holly Sheahan, Development Editor.

Chemistry World are hosting the first Chemistry World webinar on 31 January. This will include an active audience in Burlington House and be FREE to watch online.

Find out more by reading the blog, and to find out how to register.

Connecting Chemistry and Mass Spectrometry on the Internet – ChemSpider
Monday 31 January 2011

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HOT Article: Use of DFT for physisorption

21 Jan 2011

By Holly Sheahan, Development Editor.

This latest work from Marcus A. Neumann’s group uses dispersion-corrected density functional theory to look at the energy minimisation of 2,6-bis(2,4-dichlorobenzylidene)cyclohexanone. In this CrystEngComm Hot article they discover that this method predicts the low-temperature phase transition seen in experiment.

As the authors state ‘we believe that DFT-D energy minimisation provides a valuable tool since the calculations have now been shown to be sufficiently reliable to guide experimental studies towards targets most likely to exhibit interesting temperature dependent variation’

READ the full article for free until 18th February

Experimental verification of a subtle low-temperature phase transition suggested by DFT-D energy minimisation
Andrew D. Bond, Katarzyna A. Solanko, Jacco van de Streek and Marcus A. Neumann
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00676A, Communication

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HOT article: Micropeonies from nanocrystals

20 Jan 2011

By Helen Lunn, Publishing Editor.

In this HOT article, in CrystEngComm, Chen and co-workers from Harbin Institute of Technology, China report on the morphology and assembly-controlled synthesis of PbTe 3D nanostructures via a facile solvothermal method. They found that the addition of different amounts of glucose can mediate the nucleation and growth of PbTe, resulting in the formation of 3D architectures from 2D nanosheets and nanocrystals. Other factors affecting the morphology such as the amount of NaOH and the volume ratio of ethanol to water, were systematically investigated. The electrical conductivity was also dependent on the morphology.

CrystEngComm Blog

Psychedelic biodegradable copolyesters

This week’s CrystEngSelects

Top Ten most-read CrystEngComm articles in December

Chemistry World news article on CrystEngComm enamel regeneration paper

Highlight: Controlling flexibility in crystal engineering

HOT Article: Nanofibre mats remineralize tooth enamel

January Crystal Clear: Strontium sulphate stars

FREE Chemistry World Webinar

HOT Article: Use of DFT for physisorption

HOT article: Micropeonies from nanocrystals

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