Archive for the ‘News’ Category

Establishing mechanisms of solid state double [2 + 2] photochemical reactions

A double [2 + 2] photochemical reaction of 1,5-bis(4-pyridyl)-1,4-pentadiene-3-one (1P) was observed with in four co-crystal forms of 1P with the hydrogen bonding template molecule phloroglucinol (PG) or 5-methoxy resorcinol (MR). 1H NMR and the UV-vis spectroscopic studies established a stepwise mechanism for this reaction through the formation of a monocyclobutane intermediate.

Read more at:

Solid state double [2 + 2] photochemical reactions in the co-crystal forms of 1,5-bis(4-pyridyl)-1,4-pentadiene-3-one: establishing mechanism using single crystal X-ray, UV and 1H NMR
Ramkinkar Santra and Kumar Biradha
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00612B

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Top Ten most-read CrystEngComm articles in January

Read the most-read CrystEngComm articles of January 2011, listed below:

Qi-Bing Bo, Zhen-Wei Zhang, Jin-Ling Miao, Da-Qi Wang and Guo-Xin Sun, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00811G
 
Qilong Zhu, Tianlu Sheng, Ruibiao Fu, Shengmin Hu, Chaojun Shen, Xiao Ma and Xintao Wu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00393J
 
Rui-Qi Song and Helmut Cölfen, CrystEngComm, 2011, 13, 1249-1276
DOI: 10.1039/C0CE00419G
 
Jing-Yun Wu and Sheng-Ming Huang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00552E
 
Yun Ling, Lei Zhang, Jing Li and Miao Du, CrystEngComm, 2011, 13, 768-770
DOI: 10.1039/C0CE00775G
 
Jennifer Swift, CrystEngComm, 2011, 13, 1059-1059
DOI: 10.1039/C0CE90030C
 
Xiu-Li Wang, Hong-Yan Lin, Bao Mu, Ai-Xiang Tian, Guo-Cheng Liu and Ning-Hai Hu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00400F
 
Michael J. Turner, Joshua J. McKinnon, Dylan Jayatilaka and Mark A. Spackman, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00683A
 
F. Christopher Pigge, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00417K
 
Xinling Tang and Masaharu Tsuji, CrystEngComm, 2011, 13, 72-76
DOI: 10.1039/C0CE00018C

To keep up-to-date with all the best crystal engineering research articles, sign up for the journal’s e-alerts here.

 

 

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Cover article: Crystal engineering for improved drug performance

Check out the latest cover for CrystEngComm issue 4 published online now:

COVER ARTICLE

CEC issue 4 cover image

Crystalline hydrates and propylene glycol solvates of celecoxib sodium salt (Cel-Na) were prepared and characterized with the aim of improving oral drug absorption by breaking up the H-bonding interactions present in crystals of the poorly soluble marketed form of the drug.

Read more at:
Remenar et al., CrystEngComm, 2011, 13, 1047-1048

DOI: 10.1039/C1CE90004H, Cover

This issue of CrystEngComm is a themed issue focussing on Crystal Growth, guest edited by Professor Jennifer Swift. Other articles in this exciting issue include communications and papers by Lara Estroff, Joanna Aizenberg, Bart Kahr and Allan Myerson. Browse the issue.

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Psychedelic biodegradable copolyesters

Check out these amazing images in a recent CrystEngComm Advance Article by Zhaobin Qiu and Yan Yang.

Crystallisation kinectics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) depend significantly on both the comonomer composition and crystallisation temperature.  This should yield a better understanding of the structure-property relationship of biodegradable polymers.

Crystallisation kinetics and morphology of biodegradable poly(butylene succinate-co-ethylene succinate) copolyesters: effects of comonomer composition and crystallization temperature
Yan Yang and Zhaobin Qiu*
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00598c

For more fascinating crystal images, why not take a look at our Crystal Clear blog posts

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

This week’s CrystEngSelects

Here is this week’s selection of advanced articles of interest to crystal engineers from across the RSC journals.

Articles are chosen from:
ChemComm,
CrystEngComm,
Dalton Transactions,
Journal of Materials Chemistry,
New Journal of Chemistry,
Nanoscale,
Organic & Biomolecular Chemistry.
Peng Guo, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01384F, Paper
 
Nikolay A. Pushkarevsky, Sergey N. Konchenko, Manfred Zabel, Michael Bodensteiner and Manfred Scheer, Dalton Trans., 2011, Advance Article
DOI: 10.1039/C0DT01587C, Paper
 
Khoa V. Le, Satoshi Aya, Yuji Sasaki, Hyunhee Choi, Fumito Araoka, Kenji Ema, Jozef Mieczkowski, Antal Jakli, Ken Ishikawa and Hideo Takezoe, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM04009F, Communication
 
Chang-Yan Cao, Wei Guo, Zhi-Min Cui, Wei-Guo Song and Wei Cai, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03749D, Paper
 
Jianjun Wu, Fuqiang Huang, Xujie Lü, Ping Chen, Dongyun Wan and Fangfang Xu, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03252B, Paper
 
Qian Hou, Yanzhen Zheng, Jian-Feng Chen, Weilie Zhou, Jie Deng and Xia Tao, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03327H, Paper
 
Thomas van Leeuwen, Thomas C. Pijper, Jetsuda Areephong, Ben L. Feringa, Wesley R. Browne and Nathalie Katsonis, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03626A, Paper
 
Seong-Jun Yoon and SooYoung Park, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03711G, Paper
 
Yang Xiaowei, Zeng Yanwei, Mo Leiqing and Han Longxiang, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM02689A, Paper
 
Tao Ling, Ming-Ke Wu, Kai-Yang Niu, Jing Yang, Zhi-Ming Gao, Jing Sun and Xi-Wen Du, J. Mater. Chem., 2011, Advance Article
DOI: 10.1039/C0JM03530K, Paper
 
Xiaotang Lu, Zhongbin Zhuang, Qing Peng and Yadong Li, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05064D, Communication
 
Zhen-Zhong Lu, Rui Zhang, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05015F, Communication
 
Shigehisa Akine, Sayaka Hotate, Takashi Matsumoto and Tatsuya Nabeshima, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04998K, Communication
 
Lian-Xu Shi and Chuan-De Wu, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05074A, Communication
 
Daniel G. Stroppa, Luciano A. Montoro, Armando Beltrán, Tiago G. Conti, Rafael O. da Silva, Juan Andrés, Edson R. Leite and Antonio J. Ramirez, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04570E, Communication
 
Johannes Forster, Benedikt Rösner, Marat M. Khusniyarov and Carsten Streb, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC05536K, Communication
 
Dong-Ying Du, Jun-Sheng Qin, Yang-Guang Li, Shun-Li Li, Ya-Qian Lan, Xin-Long Wang, Kui-Zhan Shao, Zhong-Min Su and En-Bo Wang, Chem. Commun., 2011, Advance Article
DOI: 10.1039/C0CC04343E, Communication
 
T. Shanmugapriya, R. Vinayakan, K. George Thomas and P. Ramamurthy, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00374C, Paper
 
Ruibiao Fu, Shengmin Hu and Xintao Wu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00791A, Paper
 
Lydia Brelot, Xiao-yu Cao, Jack Harrowfield, Jean-Marie Lehn, Kari Rissanen and Luca Russo, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00814A, Paper
 
Wei Tang, Dongliang Huang, Lili Wu, Chaozhong Zhao, Lingling Xu, Hong Gao, Xitian Zhang and Weibo Wang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00710B, Paper
 
Sen-Tsun Jean and Yung-Chiun Her, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00480D, Paper
 
Liliana Dobrzańska, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00469C, Paper
 
Jing Zhou, Gaoling Zhao, Bin Song and Gaorong Han, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00793E, Paper
 
Yangang Sun, Rujia Zou, Qiwei Tian, Jianghong Wu, Zhigang Chen and Junqing Hu, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00600A, Paper
 
Chia-Hao Lee, Fang-Yi Su, Yi-Hsiu Lin, Chih-Ho Chou and Kwang-Ming Lee, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00610F, Paper
 
Rujia Zou, Junqing Hu, Zhenyu Zhang, Zhigang Chen and Meiyong Liao, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00543F, Paper
 
Hongyu Liu and Qing Yang, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00432D, Paper
 
Maria Altamura, Antonio Guidi, Loïc Jierry, Paola Paoli and Patrizia Rossi, CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00595A, Paper
Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Chemistry World news article on CrystEngComm enamel regeneration paper

A CrystEngComm Hot article on using nanofibre mats to remineralise tooth enamel has been picked up by the society magazine Chemistry World.

This fascinating paper from Stephen Mann’s group at Bristol University, describes a way to reduce hypersensitivity in teeth.

Read the Chemistry World news story, or access the original paper:

Electrospun mats of PVP/ACP nanofibres for remineralization of enamel tooth surfaces
Jane Fletcher, Dominic Walsh, Christabel Emma Fowler and Stephen Mann
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00806K, Paper

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Highlight: Controlling flexibility in crystal engineering

Here, Christopher Pigge (University of Iowa, US) discusses both the advantages and disadvantages that can arise when using flexible components in crystal engineering.  Both organic (mainly triaroylbenzenes) and metal-organic framework systems derived from flexible ligands are reviewed.

Read the Highlight by Christopher Pigge here.

Losing control? “Design” of crystalline organic and metal-organic networks using conformationally flexible buidling blocks
F. Christopher Pigge
CrystEngComm, 2011, Advance Article, DOI: 10.1039/c0ce00417k

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

FREE Chemistry World Webinar

Chemistry World are hosting the first Chemistry World webinar on 31 January. This will include an active audience in Burlington House and be FREE to watch online.

Find out more by reading the blog, and to find out how to register.

Connecting Chemistry and Mass Spectrometry on the Internet – ChemSpider
Monday 31 January 2011


Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

HOT article: Micropeonies from nanocrystals

In this HOT article, in CrystEngComm, Chen and co-workers from Harbin Institute of Technology, China report on the morphology and assembly-controlled synthesis of PbTe 3D nanostructures via a facile solvothermal method. They found that the addition of different amounts of glucose can mediate the nucleation and growth of PbTe, resulting in the formation of 3D architectures from 2D nanosheets and nanocrystals. Other factors affecting the morphology such as the amount of NaOH and the volume ratio of ethanol to water, were  systematically investigated. The electrical conductivity was also dependent on the morphology.

Read more for FREE!

PbTe hierarchical nanostructures: solvothermal synthesis, growth mechanism and their electrical conductivities
Rencheng Jin, Gang Chen,* Qun Wang, Jian Pei, Jingxue Sun and Yang Wang
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00455C, Paper

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

CrystEngComm issue 3 – now online!

The latest issue of CrystEngComm is now online.  Check it out!

The striking cover image depicts a vending machine for different layered motifs.  In pressing the different molecule buttons, you get either a single layer, bilayer or polar single layer networks (from top to bottom).

Take a closer look at the cover image here.

Alicia Beatty’s group from the Univeristy of Missouri-St Louis, USA, describe the syntheses and crystal structures of lamellar solids constructed from 3,5-pyrazole dicarboxylic acid and amines and that sterically demanding groups impose different hydrogen-bonding connectivity.  In the past this combination has resulted in one recurring layer motif.

Want to read more about Beatty et al.’s paper?

Exceptions to the rule: new hydrogen-bonded networks from an old reliable
Onome Ugono, Nigam P. Rath and Alicia M. Beatty*
CrystEngComm, 2011, 13, 753-758

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)