Archive for the ‘Hot Article’ Category

Hot Article: Arty silca-coated nanocrystals

Ping Yang and co-workers from the University of Jinan, China have created SiO2-coated CdTe nanocrystal using

a controlled sol–gel reaction. Look at more images of these beautiful nanocrystals which show how science can be art and find out more about the research in this CrystEngComm Hot Article.

Ping Yang, Zhimin Yuan, Jie Yang, Aiyu Zhang, Yongqiang Cao, Qinghui Jiang, Ruixia Shi, Futian Liu and Xin Cheng
CrystEngComm, 2011, DOI: 10.1039/C0CE00350F

READ FOR FREE! Until November 25th.

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HOT Article: A crystalline gas?

In this CrystEngComm Hot Article, Andrzej Katrusiak and colleagues discuss the isobaric freezing of 1,1,1-trichloroethane to yields crystals. These crystals could shed new light on the range of intermolecular interactions that are capable of controlling molecular re-orientation and arrangement.

Crystalline gas of 1,1,1-trichloroethane 
Maciej Bujak, Marcin Podsiadło and Andrzej Katrusiak

CrystEngComm, 2011,DOI: 10.1039/C0CE00493F

READ FOR FREE! Until 25th November.

 

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Top Ten most-read CrystEngComm articles in September

Read the most-read CrystEngComm articles of September 2010, listed below:

Chang-Chun Ji, Jing Li, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C003986A
 
Kai Jiang, Lu-Fang Ma, Xiao-Yuan Sun and Li-Ya Wang, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00190B
 
Shuang Wang, Jie Qin, Xin-Long Wang, Chao Qin, Ting-Ting Li and Zhong-Min Su, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C004065G
 
Anirban Karmakar and Israel Goldberg, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00474J
 
Rui-Qin Zhong, Ru-Qiang Zou and Qiang Xu, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00150C
 
Christer B. Aakeröy, Neil R. Champness and Christoph Janiak, CrystEngComm, 2010, 12, 22-43
DOI: 10.1039/B919819A
 
Jing-Xin Meng, Yang-Guang Li, Hai Fu, Xiao-Lan Wang and En-Bo Wang, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00356E
 
Joseph G. Nguyen, Kristine K. Tanabe and Seth M. Cohen, CrystEngComm, 2010, 12, 2335-2338
DOI: 10.1039/C000154F
 
Wenbing Yuan, Ana Lazuen Garay, Anne Pichon, Rob Clowes, Colin D. Wood, Andrew I. Cooper and Stuart L. James, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00486C
 
Xianchun Liu, Yan Xing and Xizheng Liu, CrystEngComm, 2010, 12, 383-386
DOI: 10.1039/B911000C

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Hot Article: Engineering Crystals for Painkilling Performance

The marketed crystalline form of the painkiller celecoxib (Cel-III), COX-2 selective anti-inflammatory drug, has poor solubility. Various strategies to improve this and increase its bioavailability have been published including the use of crystalline forms of the sodium salt. This study by Julius Remenar and colleagues in the USA describes the structural findings and insights that have resulted from their effort to harness and understand the sodium salts of Celecoxib. Find out more in this CrystEngComm ‘Hot Article’.

Celecoxib sodium salt: engineering crystal forms for performanceCelecoxib sodium salt: engineering crystal forms for performance
Julius F. Remenar, Mark D. Tawa, Matthew L. Peterson, Örn Almarsson, Magali B. Hickey and Bruce M. Foxman
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00475H, Paper

READ FOR FREE! Until November 18th.

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Hot Article: Tetracarboxylate pillars

Cocrystal controlled solid-state synthesis of a rigid tetracarboxylate ligand that pillars both square grid and Kagomé lattice layersMichael Zaworotko and colleagues from the University of South Florida demonstrate how a tetracarboxylic acid (BIPA-TC) is prepared using C3S3 and then used as a ligand to generate two isomeric nets that represent examples of “ligand-to-ligand” pillaring. To find out more about this ‘Hot Article’ read the full communication here.

Cocrystal controlled solid-state synthesis of a rigid tetracarboxylate ligand that pillars both square grid and Kagomé lattice layers 
Jason A. Perman, Amy J. Cairns, Łukasz Wojtas, Mohamed Eddaoudi and Michael J. Zaworotko
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00542H, Communication

READ FOR FREE! Until November 16th.

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Hot Article: Chemical and epitaxial interactions compete in controlling crystal polymorphs

A team at New York University have revealed the importance of chemical interactions at the nucleation surface compared with the periodic surface potential associated with epitaxy in controlling polymorphism through epitaxial relationships with crystalline substrates.  In this communication, Brian Olmsted and Michael Ward test the effectiveness of GRACE (Geometric Real-space Analysis of Crystal Epitaxy) software in predicting cases of epitaxially directed nucleation by performing a combinatorial crystallization study involving crystalline substrates and polymorphic compounds.

The role of chemical interactions and epitaxy during nucleation of organic crystals on crystalline substratesThe role of chemical interactions and epitaxy during nucleation of organic crystals on crystalline substrates
Brian K. Olmsted and Michael D. Ward
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00366B, Communication

READ FOR FREE! Until 9th November.

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Hot Article: How stable are tautomers?

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Hot Article: Stilbazolium organic optical crystals

In their CrystEngComm Hot Article, O-Pil Kwon and colleagues have developed a new cation core structure, N-benzyl stilbazolium nonlinear optical chromophore with a non-polar benzyl group to achieve acentric molecular ordering in the crystalline state.

Acentric nonlinear optical N-benzyl stilbazolium crystals with high environmental stability and enhanced molecular nonlinearity in solid state 
Pil-Joo Kim, Jae-Hyeok Jeong, Mojca Jazbinsek, Seong-Ji Kwon, Hoseop Yun, Jong-Taek Kim, Yoon Sup Lee, In-Hyung Baek, Fabian Rotermund, Peter Günter and O-Pil Kwon
CrystEngComm, 2010, DOI: 10.1039/C0CE00456A

READ FOR FREE! Until the 2nd of November.

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Flowery magnetic microspheres clean water

Chinese scientists reveal an easy and effective synthetic method to obtain iron oxide microspheres to treat contaminated water.

Industrial wastewater containing toxic metal ions and organic pollutants has become a serious threat to the environment and public health. So the synthesis of three-dimensional micro and nanomaterials with the capability of absorbing undesired water contaminants in a straightforward and effective manner is a priority for environmental scientists.

Now Hongjie Zhang and colleagues at Changhun Institute of Applied Chemistry, have designed an easy method to synthesise flower-shaped Fe3O4 microspheres with magnetic properties, which can be used as absorbents to treat wastewater. Unlike previous synthetic routes, Zhang’s hydrothermal method avoids the use of surfactants and copolymers that would need to be removed from solution.

Find out more about this article in Lorena Tomas Laudo’s story here Hierarchically structured Fe3O4 microspheres: morphology control and their application in wastewater treatment
Xiyan Li, Zhenjun Si, Yongqian Lei, Xiaona Li, Jinkui Tang, Shuyan Song and Hongjie Zhang, 
CrystEngComm, 2010 DOI: 10.1039/c0ce00217h

Or read the CrystEngComm article for FREE until the 2nd of November:

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Top Ten most-read CrystEngComm articles

Read the most-read CrystEngComm articles of August 2010, listed below:

C. Malla Reddy, G. Rama Krishna and Soumyajit Ghosh, CrystEngComm, 2010, 12, 2296-2314
DOI: 10.1039/C003466E
 
Qinhe Pan, Qiang Chen, Wei-Chao Song, Tong-Liang Hu and Xian-He Bu, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C002658A
 
Joseph G. Nguyen, Kristine K. Tanabe and Seth M. Cohen, CrystEngComm, 2010, 12, 2335-2338
DOI: 10.1039/C000154F
 
Xiao-Qiang Liang, Jiang-Tao Jia, Tao Wu, Dong-Ping Li, Lei Liu, Guang-Shan Zhu CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00329H
 
Lei Hou, Wen-Juan Shi, Yao-Yu Wang, Bo Liu, Wen-Huan Huang and Qi-Zhen Shi, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00167H
 
Massimiliano Massi, Mark I. Ogden, Tomoko Radomirovic and Franca Jones, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00263A
 
Deyun Ma, Weixia Wang, Yingwei Li, Jing Li, Carole Daiguebonne, Guillaume Calvez and Olivier Guillou, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00135J
 
Di Sun, Qin-Juan Xu, Chun-Yin Ma, Na Zhang, Rong-Bin Huang and Lan-Sun Zheng, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C0CE00017E
 
Eue-Soon Jang, Jung-Hee Won, Young-Woon Kim, Xiaoyuan Chen and Jin-Ho Choy, CrystEngComm, 2010, Advance Article
DOI: 10.1039/C001001D
 
Gautam R. Desiraju, CrystEngComm, 2003, 5, 466-467
DOI: 10.1039/B313552G

 

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