For the first time, metal-organic nanotubes have been made using a hydrogen-bonding self-assembly approach.
Jianlin Han and Yi Pan and colleagues from Nanjing University, China, used specially designed ligands to control the hydrogen bonding, constructing 2D layered structures that self-assembled into nanotubes. Such materials are exciting for their potential for use as molecular capillaries and sieves, and for use in biological models.
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Hydrogen-bonding self-assembly of two dimensional (2D) layer structures generating metal–organic nanotubes
Hailong Sun, Haibo Mei, Guanghui An, Jianlin Han and Yi Pan
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00471E , Communication
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