Archive for 2011

June Crystal Clear: Nanoscale Olympic torch

This month’s Crystal Clear is a tungsten oxide nanobrush made using oriented attachment and Ostwald ripening.

The brushes look like torches, and with sports fans doing their best to get London 2012 olympic tickets today, and the excitement of the games coming to the UK next year grows, we thought CrystEngComm should get involved!

We are therefore delighted to present a nanoscale olympic torch!

These crystals were made by Wolfgang Tremel and co-workers from Johannes Gutenberg-Universität, Germany and the National Institute for Materials Science, Japan, and appeared in Issue 13 of CrystEngComm, a themed issue on Dynamic behaviour and reactivity in crystalline solids, guest edited by Graeme Day and Tomislav Friščić from Cambridge University.

Read the full article if you’d like to find out more about these crystals…

Asymmetric tungsten oxide nanobrushes via oriented attachment and Ostwald ripening
Aswani Yella, Ujjal K. Gautam, Enrico Mugnaioli, Martin Panthöfer, Yoshio Bando, Dmitri Golberg, Ute Kolb and Wolfgang Tremel
CrystEngComm, 2011, 13, 4074-4081

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Hot Article: Aminoazines and their affinity for graphite

James D. Wuest and co-workers from the University of Montréal, Canada, look at crystalline amino-substituted azines in this CrystEngComm Hot article.

They look at how 2D and 3D structures of crystalline materials can be designed, using aminoazines and alkanecarboxylic acids absorbed on graphite as the test case, and as the authors say ‘Our results may therefore help identify other families of compounds that dependably favor analogous crystallization in 3D and 2D, possibly even when multiple surfaces are used and when significant epitaxy is not present’

Read the full article for FREE to find out more about these 2D and 3D structures…

Engineering homologous molecular organization in 2D and 3D. Cocrystallization of aminoazines and alkanecarboxylic acids
Adam Duong, Thierry Maris and James D. Wuest
CrystEngComm, 2011, DOI: 10.1039/C1CE05445G

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Midwest Organic Solid-State Chemistry Symposium XXI

The 21st Midwest Organic Solid-State Chemistry Symposium (MOSSCS) was held this past June 10-11, 2011 at Eastern Illinois University in Charleston Illinois.  The origins of this meeting date back to Professor David Curtin’s retirement (Univ. of Illinois) in 1998 that has since rotated among a cohort of universities in the Midwestern United States.  MOSSCS meetings provide a mechanism for emerging research scientist (undergraduate and graduate students, and postdocs) working in solid-state chemistry with an opportunity to showcase their work and become aware of the activities of other research groups. 

Prashant Chopade, CrystEngComm prize winner

While all topics related to organic solid state chemistry are welcomed, this year’s meeting consisted of 27 talks centered on crystal transformations, glass solids, polymorphism, energetic materials, pharmaceuticals, and molecular recognition.  The keynote speakers, Lian Yu (Univ. of Wisconsin) and Joe Lauher (Stoney Brook Univ.), and each of the conference presenters, provided extensive insight and stimulating discussion of the current challenges and trends in solid-state materials.  In addition to the interchange of inspiring science, each MOSSCS meeting highlights the best student presentation.  This year’s award winner was Mr Prashant Chopade from Kansas State University.

Check out Prashant’s research in his recent paper published in ChemComm:

Facile synthesis and supramolecular chemistry of hydrogen bond/halogen bond-driven multi-tasking tectons
Christer B. Aakeröy, Prashant D. Chopade, Claudia Ganser and John Desper
Chem. Commun., 2011, 47, 4688-4690 DOI: 10.1039/C1CC10436E

Report from Kraig Wheeler, Eastern Illinois University

Were you at MOSSCS this year? Tell us about your experience by posting a comment below…..

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Hot Article: Metal oxide nanoheterostructures

This CrystEngComm Hot article describes the fabrication of SnO2/α-Fe2O3 nanoheterostructures by a hydrothermal process.

The structures are made of iron oxide nanoprisms with tin dioxide nanorods on the inner and outer surfaces, which gives them superior visible light photocatalytic properties. The authors believe this is due to ‘the effective electron-hole separation at the SnO2/α-Fe2O3 interfaces’.

Read the full article for FREE to find out more about these nanostructures…

SnO2/α-Fe2O3 nanoheterostructure with novel architecture: structural characteristics and photocatalytic properties
Ju Xu, Feng Huang, Yunlong Yu, Anping Yang and Yuansheng Wang
CrystEngComm, 2011, DOI: 10.1039/C1CE05270E

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Themed issue: Dynamic behaviour and reactivity in crystalline solids

CrystEngComm‘s themed issue on Dynamic behaviour and reactivity in crystalline solids is now online!

The issue is guest edited by Graeme Day and Tomislav Friščić from Cambridge University. Read their editorial, Dynamic behaviour in the solid state.

An editorial by Prof Sir John Meurig Thomas is also included in the issue, and his perspective on Crystal engineering: origins, early adventures and some current trends, is well worth reading.

Other articles include:

Drug-drug co-crystals: Temperature-dependent proton mobility in the molecular complex of isoniazid with 4-aminosalicylic acid
Pawel Grobelny, Arijit Mukherjee and Gautam R. Desiraju

Are glycine cyclic dimers stable in aqueous solution?
Said Hamad and C. Richard A. Catlow

Solid-state synthesis of mixed trihalides via reversible absorption of dihalogens by non porous onium salts
L. Meazza, J. Martí-Rujas, G. Terraneo, C. Castiglioni, A. Milani, T. Pilati, Pierangelo Metrangolo and Giuseppe Resnati

View all the articles in Issue 13, 2011.

Find out more about our guest editors by visiting their websites (Dr Day, Dr Friščić,) or reading this CrystEngCommunity interview with Graeme Day.

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HOT article: Crystalline perfection

Lithium niobate (LN), a nonlinear optical  material in its single crystal form, is well proven as a potential and unique material for its use in advanced photonic device applications like second-harmonic generation, optical switching, optical modulators, holographic data storage, acousto-optic and ferroelectric. The transition and rare earth metal ions (Fe, Mn, Cuand Ce) improve the data storage capabilities of LN by improving its photorefraction efficiency. However, when the concentration of dopants in the crystal increase, high geometric strains develop in the lattice resulting in the agglomeration of point defects, the formation of dislocations finally leading to structural boundaries. These defects mask or partially/completely deteriorate some of the anisotropic physical properties of the single crystals and reduce the efficiency of the devices made out of these crystals.

In this HOT article, a very detailed account of a novel technique for producing optical quality single crystals of doped lithium niobate is presented. The authors have grown Fe doped LiNbO3 single crystals using an indigenously developed Czochralski growth setup. In order to achieve good quality crystals (free from structural defects, voids and grain boundaries) from the Czochralski method they have used a post growth cooling technique. Additionally they have evaluated the potential of the material for use in optical devices and shown it to be “fit for purpose”.

Read more for FREE at:

Crystalline perfection, EPR, prism coupler and UV-VIS-NIR studies on Cz-grown Fe-doped LiNbO3: A photorefractive nonlinear optical crystal
Satya Kumar Kushwaha, Kamlesh Kumar Maurya, Narayanasamy Vijayan and Godavarthi Bhagavannarayana
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C0CE00892C

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HOT article: Nanorods make a stand

In this HOT article, ZnO nanorods were helped to “stand” vertically on microsubstrates by an interesting seed-mediated approach. Taking ZnO nanosheets as the microsubstrates, ZnO nanorods can grow vertically, not lying horizontally, on the facets with the aid of a seed layer precoating to form hierarchical ZnO nanorod-nanosheet architectures. The diameter as well as the length of the standing nanorods can be controlled effectively by adjusting the growth time and the amount of ammonia in the growth solution. The precoated seed layer has been found to be the key factor in determining the resultant morphology.

Read more for FREE at:

Help nanorods “stand” on microsubstrate to form hierarchical ZnO nanorod-nanosheet architectures
Jun Jiang, Feng Gu, Wei Shao, Lili Gai, Chunzhong Li and Guangjian Huang
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C1CE05180F

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Hot Article: Cocrystals by halogen bonding

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This CrystEngComm Hot article investigates the formation of co-crystals from an isoindoline nitroxide and an iodoperfluorocarbon, and looks at the halogen bonding in the resulting crystals.

This is particularly interesting as organic spin systems such as this are of importance in the fields of spintronics and spin-based quantum computing. This method is fast and reliable, so the making of organic molecular magnetic materials is much easier.

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Read the full article for FREE to discover more about the way they prepared their x-bonding co-crystals…

Vapour phase assembly of a halogen bonded complex of an isoindoline nitroxide and 1,2-diiodotetrafluorobenzene
Karl J. P. Davy, John McMurtrie, Llew Rintoul, Paul V. Bernhardt and Aaron S. Micallef
CrystEngComm, 2011, DOI: 10.1039/C1CE05344B

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Hot Article: Green synthesis of PbS nanocrystals

In this CrystEngComm Hot Article, Hongzheng Chen and colleagues synthesized uniform PbS nanocrystals using a surfactant-free electrodeposition method.

They investigated the effect of the concentration of Cl ions, deposition time and applied deposition current in tuning the morphology of the crystals.

The authors believe the method could be extended to the shape-controlled synthesis of other semiconductor crystals, especially metal sulfides.

Read more for FREE:

Morphology evolution route of PbS crystals via environment-friendly electrochemical deposition
Weiming Qiu, Mingsheng Xu, Fei Chen, Xi Yang, Yaxiong Nan and Hongzheng Chen
CrystEngComm, 2011, Advance Article
DOI: 10.1039/C1CE05225J, Paper

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Hot Article: ZnS nanocrystals with a cone-shaped head

Masato Uehara and Hideaki Maeda look at unusually shaped zinc sulphide nanocrystals in this CrystEngComm Hot article.

The scientists from Japan, made ZnS nanocrystals with a conical head, rather than the expected truncated pyramid.

Read the full article for FREE to find our more about these interesting nanocrystals…

Structural characterization of ZnS nanocrystals with a conic head using HR–TEM and HAADF tomography
Masato Uehara, Yusuke Nakamura, Satoshi Sasaki, Hiroyuki Nakamura and Hideaki Maeda
CrystEngComm, 2011, DOI: 10.1039/C1CE05168G

This paper is building on the team’s earlier work, published in CrystEngComm earlier in the year:

Controlled synthesis and structural evolutions of ZnS nanodots and nanorods using identical raw material solution, M. Uehara, S. Sasaki, Y. Nakamura, C. G. Lee, K. Watanabe, H. Nakamura and H. Maeda
CrystEngComm, 2011, 13, 2973–2983

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