Hot Article: chiral Ti complexes

In this hot article the authors describe the synthesis of enantiomerically enriched titanium complexes. The compounds are chiral at the metal center but also chemically rigid towards racemization:

Optically active bis(β-diketonate) complexes of titanium
Natcharee Kongprakaiwoot, Jack B. Armstrong, Bruce C. Noll and Seth N. Brown
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00828A, Paper

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