Archive for 2012

HOT Article: Forensic fingerprints

Agnieszka Banas and Mark Breese from the National University of Singapore, and colleagues from Singapore and the UK have discovered there is more to be revealed in fingerprints. The non-destructive technique of synchrotron radiation-based Fourier transform infra-red (SR-FTIR) micro-imaging has been used to explore the molecular chemistry within the microstructures of microscopic particles found within latent fingerprints. Fingerprints can be contaminated with all sorts of things that a person has come in contact with, like powders, creams, medications and high explosive materials.

Click on the link below to read more about this work.

Detection of microscopic particles present as contaminants in latent fingerprints by means of synchrotron radiation-based Fourier transform infra-red micro-imaging
A. Banas, K. Banas, M. B. H. Breese, J. Loke, B. Heng Teo and S. K. Lim
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35355E

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HOT Article: Detecting people in collapsed buildings

Mochalski & Amman et al., Analyst, 2012, 137, 3278

In the last few years there have been a number of large natural disasters, including the earthquakes in Haiti and Indonesia, and the earthquake and subsequent tsunami in Japan. These disasters result in devastation and the collapse of buildings and infrastructure in cities, town and villages. Search and rescue teams looking for survivors in the rubble currently use techniques like geophones, telescopic cameras, infrared (IR) cameras, or search dogs to locate survivors.  Paweł Mochalski, Anton Amann and a collaborative team from Poland, Austria and Greece have used headspace solid phase micro-extraction gas chromatography-mass spectrometry to study the biomarkers in urine, and looked at how the profile of 22 volatile species in urine changed when in contact with concrete and brick, in an attempt to signify human presence. Read about their interesting study below.

Permeation profiles of potential urine-borne biomarkers of human presence over brick and concrete
Paweł Mochalski, Agapios Agapiou, Milt Statheropoulos and Anton Amann
Analyst, 2012, 137, 3278-3285
DOI: 10.1039/C2AN35214A

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HOT articles in Analyst

Check out some of the HOT articles published so far this month in Analyst. These papers will be free to access for 2 weeks.

The effect of anticancer drugs on seven cell lines monitored by FTIR spectroscopy
Allison Derenne, Magali Verdonck and Erik Goormaghtigh
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35116A

Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules
Rajendar Bandari and Michael R. Buchmeiser
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35193E

Facile magnetization of metal–organic framework MIL-101 for magnetic solid-phase extraction of polycyclic aromatic hydrocarbons in environmental water samples
Shu-Hui Huo and Xiu-Ping Yan
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35429B

Generating contrast in hyperpolarized 13C MRI using ligand–receptor interactions
Kayvan R. Keshari, John Kurhanewicz, Jeffrey M. Macdonald and David M. Wilson
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35406C

Micro- and nanostructures and their application in gas chromatography
M. Mittermüller and D. A. Volmer
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35184F

Characterization of microstructured fibre emitters: in pursuit of improved nano electrospray ionization performance
Xinyun Wu, Richard D. Oleschuk and Natalie M. Cann
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35249D

Switchable ‘on–off–on’ electrochemical technique for direct detection of survivin mRNA in living cells
Jing Liu, Hong Zhou, Jing-Juan Xu and Hong-Yuan Chen
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35463B

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Analyst Issue 14 now online!

Park & Hong et al., Analyst, 2012, 137, 3249

Issue 14 for Analyst has now gone online for you to have a look at. We have some wonderful and interesting covers this time.

On the front cover we have an image from Tai Hyun Park, Seunghun Hong and colleagues from Seoul National University, Seoul, Korea. They have developed a biosensor that works on the same principles as the canine nose and have used it in the detection of hexanal, which is an indicator of the oxidation of food and food quality.

A bioelectronic sensor based on canine olfactory nanovesicle–carbon nanotube hybrid structures for the fast assessment of food quality
Juhun Park, Jong Hyun Lim, Hye Jun Jin, Seon Namgung, Sang Hun Lee, Tai Hyun Park and Seunghun Hong
Analyst, 2012, 137, 3249-3254
DOI: 10.1039/C2AN16274A

Gupta et al., Analyst, 2012, 137, 3216

Tarkeshwar Gupta from the University of Delhi and co-workers from India and Germany have given us our inside front cover this issue. In their communication they have made an efficient sensor for ascorbic acid using a copper complex-based monolayer on glass. They hope this is a step forward in research in monolayer-based remote-sensing devices and wireless sensor fabrication.

“Turn on” electron-transfer-based selective detection of ascorbic acid via copper complexes immobilized on glass
Vikram Singh, Prakash Chandra Mondal, Jeyachandran Yekkoni Lakshmanan, Michael Zharnikov and Tarkeshwar Gupta
Analyst, 2012, 137, 3216-3219
DOI: 10.1039/C2AN16197D

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HOT articles in Issue 14

We have a number of HOT articles in this week’s latest issue of Analyst. With topics including urine-borne biomarkers, nerve agent detection, nanostructures for gas chromatography and a bioelectronic sensor based on a dog’s nose, this is a very HOT issue indeed! These papers will be free to access until July 4th.

Micro- and nanostructures and their application in gas chromatography
M. Mittermüller and D. A. Volmer
Analyst, 2012, 137, 3195-3201
DOI: 10.1039/C2AN35184F

“Turn on” electron-transfer-based selective detection of ascorbic acid via copper complexes immobilized on glass
Vikram Singh, Prakash Chandra Mondal, Jeyachandran Yekkoni Lakshmanan, Michael Zharnikov and Tarkeshwar Gupta
Analyst, 2012, 137, 3216-3219
DOI: 10.1039/C2AN16197D

A novel screen-printed electrode array for rapid high-throughput detection
Shuai Mu, Xiao Wang, Yuan-Ting Li, Yang Wang, Da-Wei Li and Yi-Tao Long
Analyst, 2012, 137, 3220-3223
DOI: 10.1039/C2AN35261C

Fluorogenic and chromogenic probe for rapid detection of a nerve agent simulant DCP
Wei-hui Wu, Jun-jun Dong, Xin Wang, Jian Li, Shao-hui Sui, Gao-yun Chen, Ji-wei Liu and Ming Zhang
Analyst, 2012, 137, 3224-3226
DOI: 10.1039/C2AN35428D

A bioelectronic sensor based on canine olfactory nanovesicle–carbon nanotube hybrid structures for the fast assessment of food quality
Juhun Park, Jong Hyun Lim, Hye Jun Jin, Seon Namgung, Sang Hun Lee, Tai Hyun Park and Seunghun Hong
Analyst, 2012, 137, 3249-3254
DOI: 10.1039/C2AN16274A

The effect of anticancer drugs on seven cell lines monitored by FTIR spectroscopy
Allison Derenne, Magali Verdonck and Erik Goormaghtigh
Analyst, 2012, 137, 3255-3264
DOI: 10.1039/C2AN35116A

Simultaneous electrochemical measurement of metal and organic propellant constituents of gunshot residues
Maika Vuki, Kwok-Keung Shiu, Michal Galik, Aoife M. O’Mahony and Joseph Wang
Analyst, 2012, 137, 3265-3270
DOI: 10.1039/C2AN35379B

Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules
Rajendar Bandari and Michael R. Buchmeiser
Analyst, 2012, 137, 3271-3277
DOI: 10.1039/C2AN35193E

Permeation profiles of potential urine-borne biomarkers of human presence over brick and concrete
Paweł Mochalski, Agapios Agapiou, Milt Statheropoulos and Anton Amann
Analyst, 2012, 137, 3278-3285
DOI: 10.1039/C2AN35214A

Follow Analyst on Twitter: @analystrsc

Follow Analyst on Twitter: @analystrsc

Colorimetric recognition and sensing of nitrite with unmodified gold nanoparticles based on a specific diazo reaction with phenylenediamine
Jia Zhang, Cheng Yang, Xiaolei Wang and Xiurong Yang
Analyst, 2012, 137, 3286-3292
DOI: 10.1039/C2AN35204D

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HOT article: Monitoring chicken meat freshness by colorimetric sensor

Scientists in Spain used an array of 16 chromogenic indicators with different chemical recognition properties to follow the ageing of chicken stored in modified atmosphere packaging (MAP).

Many currently available methods to check meat spoilage are destructive, time-consuming, expensive and require qualified personnel. This means that they are fine for food safety inspections, but not suitable for use in shops or on every piece of packaged meat. Chromogenic sensors are cheap, versatile, can be printed on packaging and easily measured by cameras or the naked eye. The team observed characteristic colour fingerprints for each day of the study (which was carried out over 12 days) and gave clear differentiation at two-day intervals.

Once the 16-dye array had been successfully used, the team developed a simpler version based on just two dyes with three categories allowing differentiation between ‘fresh’, ‘beginning of decay’ and ‘non-fresh’. This shortened version could be printed on packaging and observed by the naked eye.

Monitoring of chicken meat freshness by means of a colorimetric sensor array
Analyst
, 2012,
DOI: 10.1039/C2AN35211G

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HOT article: Saliva sample collector for non-invasive health test

Monitoring volatile organic compound (VOC) levels in workers exposed to these compounds is important for their health. This is normally done by taking blood samples. However, scientists are looking towards using saliva samples instead, as a non-invasive technique.

Collecting saliva samples is done by either passive drool (in which the subject has to sit tight while their saliva drips off their lips into a collection vessel) or by chewing on a piece of cotton wool (which is then centrifuged to collect the saliva). But, neither technique can be used to detect VOCs in saliva.

Now, UK scientists at Loughborough University and Unilever R&D in the Wirral have come up with a new approach to overcome this problem. They carried out sampling of VOCs directly in the mouth using a polydimethylsiloxane sampler.

Although it takes 10 minutes to collect a sample, the team says that they are working towards reducing the time to one minute. The method could be combined with other VOC sampling methods – breath and skin analysis – they say.

Sampling and Characterisation of Volatile Organic Compound Profiles in Human Saliva Using a Polydimethylsiloxane Coupon Placed Within the Oral Cavity
Analyst, 2012, Accepted Manuscript
DOI: 10.1039/C2AN35432B

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Robert Boyle Prize for Analytical Science announced

In this month’s issue of Analyst, we have a paper from Norman Dovichi, from the University of Notre Dame, USA, who has recently been announced as the recipient of the Robert Boyle Prize for Analytical Science for 2012 by the Royal Society of Chemistry. The prize was awarded for his pioneering development of ultrasensitive separations, including the first separations at zepto- and yoctomole levels and capillary electrophoresis-based DNA sequencing for the human genome.

If you are interested to hear about his work, Norman will be speaking at the RSC Symposium at Pittcon 2013, which is being held March 17 – 21, 2013, Pennsylvania Convention Center, Philadelphia, PA USA.

His recent paper in Analyst, is on the new design of a sheath flow cuvette that uses an inexpensive quartz cuvette. The sensitivity and performance was then tested using capillary electrophoresis and a laser-induced fluorescence detector. Click on the title below to read more.

Simplified sheath flow cuvette design for ultrasensitive laser induced fluorescence detection in capillary electrophoresisSimplified sheath flow cuvette design for ultrasensitive laser induced fluorescence detection in capillary electrophoresis
Oluwatosin O. Dada, Bonnie J. Huge and Norman J. Dovichi
Analyst, 2012, 137, 3099-3101
DOI: 10.1039/C2AN35321K

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HOT articles in Issue 13

Professor Pavel Matousek

Professor Pavel Matousek

In addition to the excellent themed issue collection on Single Entities, there are other high-profile names in the latest issue of Analyst.

Editorial Board member Pavel Matousek and collaborators employ transmission Raman spectroscopy for the first time to analyse model formulations comprising tabletted cocrystals.

Transmission Raman spectroscopy for quality control in model cocrystal tablets
Jonathan C. Burley, Aalae Alkhalil, Matthew Bloomfield and Pavel Matousek
Analyst, 2012, 137, 3052-3057
DOI: 10.1039/C2AN35216H

Another Editorial Board member, Graham Cooks, also features. In his paper, leaf spray mass spectrometry is explored as a fast and simple way for direct analysis of glycosides in Stevia leaves without sample pretreatment.

Professor Graham Cooks

Professor Graham Cooks

Direct analysis of steviol glycosides from Stevia leaves by ambient ionization mass spectrometry performed on whole leaves
J. Isabella Zhang, Xin Li, Zheng Ouyang and R. Graham Cooks
Analyst, 2012, 137, 3091-3098
DOI: 10.1039/C2AN16263F

There is also a collection of HOT papers to take a look at…

(more…)

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Issue 13 online: the ‘Single’ issue, Guest Edited by Henry S. White

Professor Henry S. White

Professor Henry S. White, Guest Editor

Unlucky for some, but not for Analyst: Issue 13 is now online and features papers from the ‘Single’ issue, guest edited by Professor Henry S. White from the University of Utah. The issue features some great articles from authors such as Jonathan Cooper, Zuzanna Siwy, Lane Baker and Jonathan Sweedler.

In his Editorial, Professor White highlights the wealth of information that there is to be gained when analytical chemistry is studied at the “single entity” level.

Editorial – Single Entities
Henry S. White
Analyst, 2012, 137, 2921-2921
DOI: 10.1039/C2AN90049A

The stunning front cover features a themed issue paper from Jonathan Cooper and colleagues from the University of Glasgow on the combination of microdroplet technology with cell-free cytoskeletal protein expression as tool for biological investigation.

Analyst, 2012, Vol 137, Issue 13, front cover

Front cover: Chanasakulniyom et al., Analyst, 2012, 137, 2939-2943

Expression of membrane-associated proteins within single emulsion cell facsimiles
Mayuree Chanasakulniyom, Chiara Martino, David Paterson, Louise Horsfall, Susan Rosser and Jonathan M. Cooper
Analyst, 2012, 137, 2939-2943
DOI: 10.1039/C2AN35047E

Featured on the colourful inside front cover is a themed issue paper from the group of Zuzanna Siwy of the University of California, Irvine, on single nanopores with a hydrophobic layer at the pore entrance gates, providing a way to control the transport of ions.

A hydrophobic entrance enhances ion current rectification and induces dewetting in asymmetric nanopores
Matthew Pevarnik, Ken Healy, Matthew Davenport, Joseph Yen and Zuzanna S. Siwy
Analyst, 2012, 137, 2944-2950
DOI: 10.1039/C2AN16139G

These cover articles will be free to access for 6 weeks.

Take a look at the other HOT papers from the themed issue:

(more…)

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