Archive for December, 2011

Issue 2 now online

Analyst, 2012, Issue 2 front coverThe second issue of 2012 is now online.

Featured on the front cover are Optical Chemical Sensors (Optodes), which have proven to be a versatile and powerful analytical tool often comparable or even better than traditional electrochemical sensors.  In this study Aron Hakonen from the University of Gothenburg and Niklas Strömberg of the SP Technical Research Institute of Sweden show that a nanoparticle enhanced ammonium fluorosensor is suitable for non-invasive high-quality ammonium imaging of complex samples.

The plasmon sensitized optical sensors were utilized as a bioanalytical tool for chemical imaging of natural degradation processes occurring in biological tissues. Analytical performance of the nanoparticle enhanced sensors confirmed superior sensitivity, reversibility, durability and overall image quality over non-doped sensing membranes.

In addition, a straightforward square root function was utilized to improve image quality and simplify the calibration process.

They say that the nanoparticle interaction/coextraction based sensing scheme utilized in this study is general and can be used for numerous ions, preferably combined with the diffusion consistent calibrations for superior analytical performance.

Diffusion consistent calibrations for improved chemical imaging using nanoparticle enhanced optical sensors
Aron Hakonen and Niklas Strömberg
Analyst, 2012, 137, 315-321
DOI: 10.1039/C1AN15528H

On the back cover is work from Hui-Fen Wua and colleagues at the National Sun Yat-Sen University, Kaohsiung, Taiwan on the detection of bacteria using physical preconcentration coupled ZnO NPs assisted MALDI-MS (PP-MALDI-MS).  Ants and humans coexist closely and for the most part happily, but this work shows that perhaps these insects aren’t as harmless* as they seem.  Their study is an attempt to highlight the ability of these seemingly harmless ants to collect bacteria from their surroundings and transport them, and they confirmed that ants are potent carriers of bacteria and are good indicators of the bacteria present in the specific environment.

Analyst 2012, Issue 2 back coverTracing the pathogen Staphylococcus aureus on laboratory ants using physical preconcentration coupled ZnO nanoparticle assisted MALDI-TOF MS
Judy Gopal, Hui-Fen Wu, Chia-Hsun Lee and Muthu Manikandan
Analyst, 2012, 137, 357-364
DOI: 10.1039/C1AN15625J

These articles will be free for 6 weeks so take a look and let your colleagues know.

(*as someone who has been bitten by a soldier ant in the jungle, I have to disagree with the assessment of these insects as harmless!)

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Analytical Chemistry Summer Studentship Scheme 2012

The Trustees of the Analytical Chemistry Trust Fund announce the Analytical Chemistry Summer Studentship Scheme:

The purpose of the awards is to give experience of research to undergraduates with research potential and to encourage them to consider a career in Analytical Chemistry research on completion of their undergraduate degree.

The awards provide support for the student at a rate of £180 per week (£190 per week in London), for a period of between 6 and 8 weeks during the summer vacation.

Applications for funding should be made by the supervisor (Industrial or Academic) wishing to host a studentship in the field of Analytical Chemistry.

Visit the website for more details and to apply.

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HOT article: Detecting water in fuel

Professor Boris MizaikoffTake a look at this HOT paper from Editorial Board member Boris Mizaikoff.

Water is a common contaminant in industrial oils and petroleum products. It impairs the performance and longevity of machinery, so it’s important to detect it in these products. A previous approach has involved off-site analysis, but this method is time consuming and may be compromised because of the potential variability in water concentration introduced by storage, transportation or shipment of a sample.

Here, Professor Mizaikoff and colleagues have focused on quantifying trace amounts of water in hydrocarbons using hexane as a model system for industrial oils and petroleum using mid-infrared evanescent field absorption spectroscopy.

They used a silver halide fibre optic waveguide to interrogate in situ water-in-hexane emulsions. The limits of detection and limits of quantification of water in hexane using tin-crosslinked polyacrylic acid modified fibres were 76 and 170ppm, respectively. The IR absorption signature of water in hexane was detected at concentrations as low as 10ppm.

The strategy requires a single measurement, requires no sample preparation and has the potential for direct in situ detection.

Detecting trace amounts of water in hydrocarbon matrices with infrared fiberoptic evanescent field sensors
Yuliya Luzinova, Bogdan Zdyrko, Igor Luzinov and Boris Mizaikoff
Analyst, 2012, Advance Article
DOI: 10.1039/C1AN15521K

Luzinova et al., 2012

Take a look at some of Boris’ other recent work:

Nitrogen-doped diamond-like carbon as optically transparent electrode for infrared attenuated total reflection spectroelectrochemistry
Nicola Menegazzo, Markus Kahn, Roswitha Berghauser, Wolfgang Waldhauser and Boris Mizaikoff
Analyst, 2011, 136, 1831-1839
DOI: 10.1039/C0AN00503G

Communication: Surface-modified ZnSe waveguides for label-free infrared attenuated total reflection detection of DNA hybridization
Carla S. Riccardi, Dennis W. Hess and Boris Mizaikoff
Analyst, 2011, 136, 4906-4911
DOI: 10.1039/C0AN00504E

Don’t forget that Boris is our Associate Editor for Europe.  If you are a European author, why not submit your next paper to his office?

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First issue of 2012 now online!

Analyst 2012, Issue 1 covers

Analyst, 2012, 137(1): 1-276

An early New Year present from Analyst: it’s Issue 1 of 2012, which has now been published online.

We start the year as we mean to go on, with some excellent cover articles with equally good cover images.

On the front cover is an article from Jason Greenwood and colleagues from Queen’s University, Belfast on mass spectra obtained from the interaction of intense, femtosecond laser pulses with 1,3-butadiene, 1-butene, and n-butane.  They discuss potential mass spectrometry applications of the technique, such as the analysis of catalytic reaction products.

Communication: Femtosecond lasers for mass spectrometry: Proposed application to catalytic hydrogenation of butadiene
Orla Kelly, Martin J. Duffy, Raymond B. King, Louise Belshaw, Ian D. Williams, Jacinto Sá, Chris R. Calvert and Jason B. Greenwood
Analyst, 2012, 137, 64-69
DOI: 10.1039/C1AN15706J

Research from Analyst Editorial Board members features on the other covers of Issue 1.  On the inside front cover, Justin Gooding and colleagues from the University of New South Wales describe a simple colorimetric method for the detection of copper ions in water.  Nanoparticle cross-linking, evidenced as a colour change, is used for the detection of copper ions.

A novel route to copper(II) detection using ‘click’ chemistry-induced aggregation of gold nanoparticles
Carol Hua, William H. Zhang, Swahnnya R. M. De Almeida, Simone Ciampi, Danmar Gloria, Guozhen Liu, Jason B. Harper and J. Justin Gooding
Analyst, 2012, 137, 82-86
DOI: 10.1039/C1AN15693D

Emory et al., Analyst, 2012, 137, 87-97

On the outside back cover, Steven Soper and co-workers report a simple and compact fluorescence single-molecule instrument that is straightforward to operate and consists of fiber optics directly coupled to a microfluidic device.

Design and development of a field-deployable single-molecule detector (SMD) for the analysis of molecular markers
Jason M. Emory, Zhiyong Peng, Brandon Young, Mateusz L. Hupert, Arnold Rousselet, Donald Patterson, Brad Ellison and Steven A. Soper
Analyst, 2012, 137, 87-97
DOI: 10.1039/C1AN15658F

Covers from 2011Issue 1 of 2012 also contains information on all our Editorial Board members and an Editorial from Paul Bohn, Chair of the Board and May Copsey, Editor of Analyst.

Editorial: Analyst, unconfined by traditional discipline barriers
Analyst, 2012, 137, 17-20
DOI: 10.1039/C1AN90099D

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