HOT Organic & Biomolecular Chemistry articles for March – updated throughout the month

A computational and experimental study of O-glycosylation. Catalysis by human UDP-GalNAc polypeptide:GalNAc transferase-T2
Hansel Gómez, Raúl Rojas, Divya Patel, Lawrence A. Tabak, José M. Lluch and Laura Masgrau
Org. Biomol. Chem., 2014, Advance Article, DOI: 10.1039/C3OB42569J

A computational and experimental study of O-glycosylation. Catalysis by human UDP-GalNAc polypeptide:GalNAc transferase-T2

Free to access until 25th April


Benzofuranquinones as inhibitors of indoleamine 2,3-dioxygenase (IDO). Synthesis and biological evaluation
Catarina Carvalho, David Siegel, Martyn Inman, Rui Xiong, David Ross and Christopher J. Moody
Org. Biomol. Chem., 2014, Advance Article, DOI: 10.1039/C3OB42258E

Benzofuranquinones as inhibitors of indoleamine 2,3-dioxygenase (IDO). Synthesis and biological evaluation

Free to access until 25th April


Diastereoselective Ireland–Claisen rearrangements of substituted allyl β-amino esters: applications in the asymmetric synthesis of C(5)-substituted transpentacins
Stephen G. Davies, Ai M. Fletcher, James A. Lee, Paul M. Roberts, Myriam Y. Souleymanou, James E. Thomson and Charlotte M. Zammit  
Org. Biomol. Chem., 2014, Advance Article, DOI: 10.1039/C4OB00274A

Diastereoselective Ireland–Claisen rearrangements of substituted allyl β-amino esters: applications in the asymmetric synthesis of C(5)-substituted transpentacins

Free to access until 25th April


Biomimetic total synthesis of (±)-yezo’otogirin A
Hiu C. Lam, Kevin K. W. Kuan and Jonathan H. George  
Org. Biomol. Chem., 2014,12, 2519-2522, DOI: 10.1039/C4OB00186A

Biomimetic total synthesis of (±)-yezo'otogirin A

Free to access until 25th April


Anti-cooperative ligand binding and dimerisation in the glycopeptide antibiotic dalbavancin
Mu Cheng, Zyta M. Ziora, Karl A. Hansford, Mark A. Blaskovich, Mark S. Butler and Matthew A. Cooper  
Org. Biomol. Chem., 2014,12, 2568-2575, DOI: 10.1039/C3OB42428F

Anti-cooperative ligand binding and dimerisation in the glycopeptide antibiotic dalbavancin

Free to access until 25th April


Fructose controlled ionophoric activity of a cholate–boronic acid
James R. D. Brown, Inmaculada C. Pintre and Simon J. Webb  
Org. Biomol. Chem., 2014,12, 2576-2583, DOI: 10.1039/C4OB00165F

Fructose controlled ionophoric activity of a cholate–boronic acid

Free to access until 25th April


Phosphodiesters serve as potentially tunable aglycones for fluoro sugar inactivators of retaining β-glycosidases
B. P. Rempel and S. G. Withers  
Org. Biomol. Chem., 2014,12, 2592-2595, DOI: 10.1039/C4OB00235K

Phosphodiesters serve as potentially tunable aglycones for fluoro sugar inactivators of retaining β-glycosidases

Free to access until 25th April


Acyclic CB[n]-type molecular containers: effect of solubilizing group on their function as solubilizing excipients
Ben Zhang, Peter Y. Zavalij and Lyle Isaacs
Org. Biomol. Chem., DOI: 10.1039/C3OB42603C, Paper
Free to access until 21st April


Out-Basicity of 1,8-bis(dimethylamino)naphthalene: the experimental and theoretical challenge
Valery A. Ozeryanskii, Alexander F. Pozharskii, Alexander S. Antonov and Alexander Filarowski
Org. Biomol. Chem., DOI: 10.1039/C3OB41986J, Paper
Free to access until 21st April


Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: highly enantioselective and chemoselective access to a chiral benzylmethyl center
Shuang Yang, Shou-Fei Zhu, Na Guo, Song Song and Qi-Lin Zhou
Org. Biomol. Chem., DOI: 10.1039/C4OB00018H, Communication
Free to access until 5th April


Making Fe(BPBP)-catalyzed C–H and C=C oxidations more affordable
Vital A. Yazerski, Peter Spannring, David Gatineau, Charlotte H. M. Woerde, Sara M. Wieclawska, Martin Lutz, Henk Kleijn and Robertus J. M. Klein Gebbink
Org. Biomol. Chem., DOI: 10.1039/C3OB42249F, Paper
Free to access until 5th April


Chromane helicity rule – scope and challenges based on an ECD study of various trolox derivatives
Marcin Górecki, Agata Suszczyńska, Magdalena Woźnica, Aneta Baj, Michał Wolniak, Michał K. Cyrański, Stanisław Witkowski and Jadwiga Frelek
Org. Biomol. Chem., DOI: 10.1039/C3OB42376J, Paper
Free to access until 5th April


Reaction pathways and free energy profiles for cholinesterase-catalyzed hydrolysis of 6-monoacetylmorphine
Yan Qiao, Keli Han and Chang-Guo Zhan
Org. Biomol. Chem., DOI: 10.1039/C3OB42464B, Paper
Free to access until 10th April

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