Archive for the ‘News’ Category

Issue 1 of Reaction Chemistry & Engineering

Covers

Issue 1 of Reaction Chemistry & Engineering is now published online, read it here.

The front covers feature work by Hartman et al. and Noel et al. Take a look inside for articles on polymer reaction engineering, new flow reactor technology, biocatalysis and more!

All articles published in Reaction Chemistry & Engineering in 2016 and 2017 are free-to-access for all. Access is automatic through registered institutions, or individuals can fill in this simple online form to create a free publishing personal account and obtain access to Reaction Chemistry & Engineering and a host of other free content from the Royal Society of Chemistry.

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Breaking news… first Advance Articles published

HeaderThe first Reaction Chemistry & Engineering Advance Articles are now published!

A big thank you to all our board members, authors, referees and others that have worked hard to make this possible.

Read on for a taster of what’s available, and take some time to explore our content. Articles will now be published online as soon as they are ready – the best way to keep up to date with the latest work is to subscribe to our RSS feed or sign-up to email alerts. Don’t forget, the first two volumes of Reaction Chemistry & Engineering are free-to-access for everyone.

A selection of our very first articles:

GAInfluence of water on the deprotonation and the ionic mechanisms of a Heck alkynylation and its resultant E-factors” by Chuntian Hu, Kevin H. Shaughnessy and Ryan L. Hartman

This paper presents a comprehensive investigation into the influence of water on the cationic and anionic derivatives of the deprotonation mechanism of a Heck alkynylation, including evaluation of kinetic parameters, DFT free energy calculations and E-factor analysis in batch and continuous flow. The study increases understanding of how chemical waste generated during Heck alkynylations can be minimised.


GA

A convenient numbering-up strategy for the scale-up of gas–liquid photoredox catalysis in flow by Yuanhai Su, Koen Kuijpers, Volker Hessel and Timothy Noël

This paper presents a modular photocatalytic flow reactor system and its application to the scale-up of the aerobic oxidation of thiols to disulfides, showing a good flow distribution and a yield comparable to a single device. The assembly is made up of only commercially available parts and can be quickly put together by anyone familiar with flow chemistry.


GA

Thermolysis of 1,3-dioxin-4-ones: fast generation of kinetic data using in-line analysis under flow” by Thomas Durand, Cyril Henry, David Bolien, David C. Harrowven, Sally Bloodworth, Xavier Franck and Richard J. Whitby

This paper uses a commercial flow reactor with stepped flow rate for rapid acquisition of kinetic data for the thermolysis of 1,3-dioxin-4-ones. UV and IR provide in-line reaction analysis and kinetic information is extracted from the resulting spectra. The methods developed are widely applicable for reaction study and process development.

We hope you find these articles of interest, don’t forget to check out all the latest content here.

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Sign up for the Reaction Chemistry & Engineering Email Alerts

Email alertsThe Reaction Chemistry & Engineering Email Alerts are a great way to find out about all the latest news and content from the journal.

Our first News Alert will be going out soon, with a roundup of all the most recent developments, so be sure to sign up now.

You can also sign up to Issue Alerts, providing all the content from the latest issue of the journal, which will begin once we have published our first issue.

Don’t forget you can also follow us on Twitter to keep fully up to date.

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Reaction chemistry across the Royal Society of Chemistry

We are delighted to announce that the Royal Society of Chemistry’s newest journal, Reaction Chemistry & Engineering, is now open for submissions – read the full announcement here.

Reaction Chemistry & Engineering cover

To celebrate this, we’ve put together a collection of some of the most exciting recent reaction chemistry papers in Royal Society of Chemistry journals. All the articles in the collection are currently free to access.

We hope that you enjoy reading this collection of great reaction chemistry. After you’re done, why not explore the scope of Reaction Chemistry & Engineering and send us your own best reaction chemistry research now for the chance of being included in our very first issue?

Iron-catalyzed kinetic resolution of N-sulfonyl oxaziridines, Kevin S. Williamson, James W. Sawicki and Tehshik P. Yoon, Chem. Sci., 2014, 5, 3524–3527. Topic areas: New reactions and reaction optimisation; Catalysis and catalytic reaction engineering.

Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions, José G. Hernández, Ian S. Butler and Tomislav Friščić, Chem. Sci., 2014, 5, 3576–3582. Topic areas: Reaction pathways and design; New reactions and reaction optimisation.

Effects of internal and external carboxylic acids on the reaction pathway of organocatalytic 1,4-addition reactions between aldehydes and nitroolefins, Jörg Duschmalé, Johannes Wiest, Markus Wiesner and Helma Wennemers, Chem. Sci., 2013, 4, 1312–1318. Topic areas: Reaction mechanism and kinetics; Reaction pathways and design; Reaction analysis and monitoring.

Kinetic correlation between aldehyde/enamine stereoisomers in reactions between aldehydes with ɑ-stereocenters and chiral pyrrolidine-based catalysts, Jordi Burés, Alan Armstrong and Donna G. Blackmond, Chem. Sci., 2012, 3, 1273. Topic areas: Reaction mechanism and kinetics, Reaction analysis and monitoring, Catalysis and catalytic reaction engineering

Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis, Qingquan Lu, Jian Zhang, Pan Peng, Guanghui Zhang, Zhiliang Huang, Hong Yi, Jeffrey T. Miller and Aiwen Lei, Chem. Sci., 2015, 6, 4851. Topic areas: Reaction pathways and design; Reaction analysis and monitoring; New reactions and reaction optimisation.

A self optimizing synthetic organic reactor system using real-time in-line NMR spectroscopy, Victor Sans, Luzian Porwol, Vincenza Dragone and Leroy Cronin, Chem. Sci., 2015, 6, 1258. Topic areas: Reaction analysis and monitoring, New reactions and reaction optimisation; Emerging reactor technology.

Cascade upgrading of γ-valerolactone to biofuels, Kai Yan, Todd Lafleur, Xu Wu, Jiajue Chai, Guosheng Wu and Xianmei Xie, Chem. Commun., 2015, 51, 6984. Topic areas: Catalysis and catalytic reaction engineering; Sustainable reaction engineering.

Beyond the use of modifiers in selective alkyne hydrogenation: silver and gold nanocatalysts in flow mode for sustainable alkene production, Gianvito Vilé and Javier Pérez-Ramírez, Nanoscale, 2014, 6, 13476. Topic areas: Catalysis and catalytic reaction engineering; Multiphase and reacting flows; Sustainable reaction engineering.

Continuous flow chemistry: a discovery tool for new chemical reactivity patterns, Jan Hartwig, Jan B. Metternich, Nikzad Nikbin, Andreas Kirschning and Steven V. Ley, Org. Biomol. Chem., 2014, 12, 3611. Topic areas: Multiphase and reacting flows; New reactions and reaction optimisation.

Continuous synthesis of artemisinin-derived medicines, Kerry Gilmore, Daniel Kopetzki, Ju Weon Lee,  Zoltán Horváth, D. Tyler McQuade, Andreas Seidel-Morgenstern and Peter H. Seeberger, Chem. Commun., 2014, 50, 12652. Topic areas: Emerging reactor technologies; Multiphase and reacting flows.

End-to-end continuous flow synthesis and purification of diphenhydramine hydrochloride featuring atom economy, in-line separation, and flow of molten ammonium salts, David R. Snead and Timothy F. Jamison, Chem. Sci., 2013, 4, 2822. Topic areas: Sustainable reaction engineering; Multiphase and reacting flows.

To keep up with the latest news from Reaction Chemistry & Engineering, be sure to sign up to our e-alerts and follow us on twitter @RSC_ReactionEng.

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