Organic Chemistry Frontiers Blog

Organic Chemistry Frontiers is delighted to share with you the HOT articles of June 2018!

You can access these publications for free till 31^st August 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Photoexcited perylene diimide radical anions for the reduction of aryl halides: a bay-substituent effect
Pei-Zhi Zhang, Rui Liu, Ling-Dong Sun, Hao Dong, Lin-Dong Li, Xiao-Yu Zheng, Ke Wu and Chun-Hua Yan
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00445E

Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group
Xia Zhao, Xiancai Zheng, Miaomiao Tian, Yifan Tong, Bo Yang, Xianfu Wei, Di Qiu and Kui Lu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00401C

Diastereoselectivity in a cyclic secondary amine catalyzed asymmetric Mannich reaction: a model rationalization from DFT studies
Siwei Shu, Zhao Liu, Yukui Li, Zhuofeng Ke and Yan Liu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00424B

Facile synthesis of macrocyclic peptide toxins of GpTx-1 and its analogue
Chao Chen, Mei Hong, Xiaoqi Guo, Fangming Wu, Changlin Tian, Yangding Wang and Zhaoqing Xu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00415C

Chemical synthesis and biological evaluation of penta- to octa- saccharide fragments of Vi polysaccharide from Salmonella typhi
Gao-Lan Zhang, Meng-Man Wei, Chengcheng Song, Yu-Feng Ma, Xiu-Jing Zheng, De-Cai Xiong and Xin-Shan Ye
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00471D

Dysohonin A, a meroditerpenoid incorporating a 6,15,6-fused heterotricyclic ring system from Dysoxylum hongkongense
Jin-Xin Zhao, Cui-Ping Liu, Meng-Meng Zhang, Jia Li and Jian-Min Yue
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00469B

Access to sulfonylated furans or imidazo[1,2-a]pyridines via a metal-free three-component, domino reaction
Zhiming Cui, Baofu Zhu, Xuechen Li and Hua Cao
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00443A

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide
Ke-Jin Jiao, Zhao-Ming Li, Xue-Tao Xu, Li-Pu Zhang, Yi-Qian Li, Kun Zhang and Tian-Sheng Mei
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00507A

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines
Linfeng Cui, Yang’en You, Xueling Mi and Sanzhong Luo
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00496J

Organic Chemistry Frontiers is delighted to share with you the HOT articles of May 2018!

You can access these publications for free till 31^th July 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Efficient catalytic vicinal diamination of arylene diimides
Michael Kremer, Maximilian Kersten and Sigurd Höger
Org. Chem. Front., 2018,5, 1825-1829
http://dx.doi.org/10.1039/C8QO00222C

Azidoheteroarylation of unactivated olefins through distal heteroaryl migration
Min Wang, Zhen Wu, Bo Zhang and Chen Zhu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00301G

Selective formation of phthalimides from amines, aldehydes and CO by Pd-catalyzed oxidative C–H aminocarbonylation
Renyi Shi, Fan Liao, Huiying Niu and Aiwen Lei
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00282G

Selenium dioxide-promoted selective synthesis of mono- and bis-sulfenylindoles
Samuel Thurow, Filipe Penteado, Gelson Perin, Diego Alves, Claudio Santi, Bonifacio Monti, Carl H. Schiesser, Thiago Barcellos and Eder J. Lenardão
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00360B

Highly enantioselective Ir/f-amphox-catalyzed hydrogenation of ketoamides: efficient access to chiral hydroxy amides
Yang Hu, Xuguang Yin, Ziyi Chen, Xiu-Qin Dong and Xumu Zhang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00307F

A more reliable synthesis of a Gemini vitamin D analog, a potentially effective chemotherapeutic agent for the treatment of colorectal carcinomas
Hugo Santalla, Fátima Garrido, Generosa Gómez and Yagamare Fall
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00338F

Three-component reaction to synthesize E-vinyl silyl anti-1,2-diols via sequential [1,4]-O-to-O/[1,4]-C-to-O silyl migrations
Qiang Pu, Xiaoxiao Tang, Lu Gao and Zhenlei Song
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00332G

Convergent syntheses of 2,3-dihydrobenzofurans via a Catellani strategy
Chenggui Wu, Hong-Gang Cheng, Ruiming Chen, Han Chen, Ze-Shui Liu, Jingyang Zhang, Yuming Zhang, Yuxin Zhu, Zhi Geng and Qianghui Zhou
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00348C

The iridium-catalysed reductive coupling reaction of tertiary lactams/amides with isocyanoacetates
Xiu-Ning Hu, Tai-Long Shen, Dong-Cheng Cai, Jian-Feng Zheng and Pei-Qiang Huang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00312B

Asymmetric [4 + 2] cycloadditions with 3-furfural derivatives and α-cyano-α,β-unsaturated ketones
Chuan-Qi Duan, Xiao-Long He, Wei Du and Ying-Chun Chen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00351C

Organic Chemistry Frontiers is delighted to share with you the HOT articles of April 2018!

You can access these publications for free till 3o^th June 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Enantioselective indium(I)-catalyzed [4 + 2] annulation of alkoxyallenes and β,γ-unsaturated α-keto esters
Sujia Li, Jian Lv and Sanzhong Luo
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00319J

The design of rigid cyclic tripyrrins: the importance of intermolecular interactions on aggregation and luminescence
Jun-Fei Wang, Yuhang Yao, Yingying Ning, Yin-Shan Meng, Chun-Liang Hou, Jing Zhang and Jun-Long Zhang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00313K

Iridium-catalysed conjugated alkynylation of α,β-unsaturated amide through alkene isomerization
Yun Chen, Zi-Xuan Wang, Qian Li, Li-Jin Xu and Bi-Jie Li
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00136G

Organic Chemistry Frontiers is delighted to share with you the HOT articles of March 2018!

You can access these publications for free till 31^st May 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Base-promoted [3 + 3] cyclization of cyclopropenones and cyclopropenethiones with amides for the synthesis of 6H-1,3-oxazin-6-ones and 6H-1,3-thiazin-6-ones
Ben Niu, Bo Jiang, Liu-Zhu Yu and Min Shi
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00091C

Research Article Isolation and biosynthesis of labdanmycins: four new labdane diterpenes from endophytic Streptomyces
Zi-Jun Xiong, Jianping Huang, Yijun Yan, Li Wang, Zhiyan Wang, Jing Yang, Jianying Luo, Jie Li and Sheng-Xiong Huang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00085A

Efficient access to chiral benzo[c]chromenes via asymmetric transfer hydrogenation of ketals
Yangshan Li, Miao Wan, Shutao Sun, Zhongjun Fu, Haofei Huang and Lei Liu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00096D

Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates
Hui Leng Sang, Songjie Yu and Shaozhong Ge
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00167G

Total synthesis of teixobactin and its stereoisomers
L. Liu, S. Wu, Q. Wang, M. Zhang, B. Wang, G. He and G. Chen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00145F

Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO₂SCF₂H or PhSO₂SCF₃
Bin Xu, Decai Wang, Yonghong Hu and Qilong Shen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00115D

Research Article Catalyst-controlled synthesis of 4-amino-isoquinolin-1(2H)-one and oxazole derivatives
Ben Niu, Ruixing Liu, Yin Wei and Min Shi
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00125A

Mechanistic insights into the different chemoselectivities of Rh₂(II)-catalyzed ring expansion of cyclobutanol-substituted aryl azides and C–H bond amination of cyclopentanol-substituted aryl azides: a DFT study
Dafang Gao and Xiaoguang Bao
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00113H

Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes
Jianxiang Yan, Jian Xu, Yao Zhou, Jinglong Chen and Qiuling Song
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00147B

Asperones A–E, five dimeric polyketides with new carbon skeletons from the fungus Aspergillus sp. AWG 1–15
Guo-Ping Yin, Ya-Rong Wu, Chao Han, Xiao-Bing Wang, Hong-Liang Gao, Yong Yin, Ling-Yi Kong and Ming-Hua Yang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00070K