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Hot Articles in September 2017

19 Oct 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of September 2017!

You can access these publications for free till 30^th November 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Asymmetric S_N2′-type C–H functionalization of arenes with propargylic alcohols
Shangze Wu, Xin Huang, Chunling Fu and Shengming Ma
Org. Chem. Front., 2017,4, 2002-2007
http://dx.doi.org/10.1039/C7QO00588A

Comparative investigation of the reactivities between catalysts [Cp*RhCl₂]₂ and [Cp*IrCl₂]₂ in the oxidative annulation of isoquinolones with alkynes: a combined experimental and computational study
Chaoyue Zhao, Qingmei Ge, Baiquan Wang and Xiufang Xu
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00586E

Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions
Benjamin Laroche and Bastien Nay
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00633K

Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
Yao-Liang Sun, Yin Wei and Min Shi
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00512A

A redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[5]arene-based host–guest recognition
Yujuan Zhou, Kecheng Jie and Feihe Huang
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00736A

Rearranged limonoids with unique 6/5/6/5 tetracarbocyclic skeletons from Toona ciliata and biomimetic structure divergence
Jun Luo, Wan-Sha Huang, Sheng-Mou Hu, Pan-Pan Zhang, Xu-Wei Zhou, Xiao-Bing Wang, Ming-Hua Yang, Jian-Guang Luo, Chen Wang, Chang Liu, He-Quan Yao, Can Zhang, Hong-Bin Sun, Yi-Jun Chen and Ling-Yi Kong
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00678K

Gold-catalyzed diversified synthesis of 3-aminosugar analogues of digitoxin and digoxin
Jing Zeng, Guangfei Sun, Ruobin Wang, Shuxin Zhang, Shuang Teng, Zhiwen Liao, Lingkui Meng and Qian Wan
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00648A

Scandium-catalyzed C(sp³)–H alkylation of N,N-dimethyl anilines with alkenes
Hongjie Gao, Jianhong Su, Pengfei Xu and Xin Xu
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00718C

A copper(I)-catalyzed asymmetric Mannich reaction of glycine Schiff bases with isatin-derived ketimines: enantioselective synthesis of 3-substituted 3-aminooxindoles
Jing-Yan Zhu, Wu-Lin Yang, Yang-Zi Liu, Shao-Jing Shang and Wei-Ping Deng
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00691H

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Hot Articles in August 2017

07 Sep 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of August 2017!

You can access these publications for free till 31^st October 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Photoredox meets gold Lewis acid catalysis in the alkylative semipinacol rearrangement: a photocatalyst with a dark side
M. Zidan, T. McCallum, L. Thai-Savard and L. Barriault
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00590C, Research Article

Palladium catalyzed C(sp³)–H acetoxylation of aliphatic primary amines to γ-amino alcohol derivatives
Kang Chen, Ding Wang, Zhao-Wei Li, Zheng Liu, Fei Pan, Yun-Fei Zhang and Zhang-Jie Shi
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00432J, Research Article

Garciyunnanimines A–C, novel cytotoxic polycyclic polyprenylated acylphloroglucinol imines from Garcinia yunnanensis
Dan Zheng, Hong Zhang, Chang-Wu Zheng, Yuan-Zhi Lao, Dan-Qing Xu, Lian-Bo Xiao and Hong-Xi Xu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00485K, Research Article

Identifying a cobalt catalyst for highly selective hydrosilylation of allenes
Zheng Yang, Dongjie Peng, Xiaoyong Du, Zheng Huang and Shengming Ma
Org. Chem. Front., 2017,4, 1829-1832
DOI: 10.1039/C7QO00497D, Research Article

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Hot Articles in July 2017

10 Aug 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of July 2017!

You can access these publications for free till 30^th September 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Silver-mediated fluorination of alkyl iodides with TMSCF₃ as the fluorinating agent
Liyan Wang, Xiaohuan Jiang and Pingping Tang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00450H

Efficient trifluoromethylation via the cyclopropanation of allenes and subsequent C–C bond cleavage
Yang Tang, Qiong Yu and Shengming Ma
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00419B, Research Article

Iridium-catalyzed direct asymmetric reductive amination of aromatic ketones
Haizhou Huang, Zitong Wu, Guorui Gao, Le Zhou and Mingxin Chang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00400A, Research Article

Merging photoredox catalysis with transition metal catalysis: site-selective C4 or C5-H phosphonation of 8-aminoquinoline amides
Huijie Qiao, Suyan Sun, Yue Zhang, Hongmei Zhu, Xiaomeng Yu, Fan Yang, Yusheng Wu, Zhongxian Li and Yangjie Wu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00305F, Research Article

The asymmetric synthesis of multisubstituted diquinanes via the domino reaction of electron-deficient enynes
Qian Yao, Lili Lin, Hang Zhang, Han Yu, Qian Xiong, Xiaohua Liu and Xiaoming Feng
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00408G, Research Article

Concise asymmetric total synthesis of (−)-patchouli alcohol
Guang-Qiang Xu, Guo-Qiang Lin and Bing-Feng Sun
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00459A, Research Article

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Hot Articles in May 2017

07 Jun 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of May 2017!

You can access these publications for free till 31^st July 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Copper-catalyzed oxidative amidation of α,β-unsaturated ketones via selective C–H or C–C bond cleavage
Tony Wheellyam Pouambeka, Ge Zhang, Guang-Fan Zheng, Guo-Xing Xu, Qian Zhang, Tao Xiong and Qian Zhang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00146K, Research Article

Synthesis and conformational structure of hydrazo-bridged homo calix[2]pyridine[2]triazines
Dong-Dong Liang and Mei-Xiang Wang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00221A, Research Article

Synthesis of pyrazolo[5,1-a]isoquinolines through copper-catalyzed regioselective bicyclization of N-propargylic sulfonylhydrazones
Hai-Tao Tang, Jia-Hao Zeng, Jun-Jia Chen, Yun-Bing Zhou, Ren-Hao Li and Zhuang-Ping Zhan
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00249A, Research Article

The influence of branched alkyl side chains in A–D–A oligothiophenes on the photovoltaic performance and morphology of solution-processed bulk-heterojunction solar cells
Ibrahim Ata, Sadok Ben Dkhil, Martin Pfannmöller, Sara Bals, David Duché, Jean-Jacques Simon, Tomoyuki Koganezawa, Noriyuki Yoshimoto, Christine Videlot-Ackermann, Olivier Margeat, Jörg Ackermann and Peter Bäuerle
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00222J, Research Article

Photoinduced difunctionalization of 2,3-dihydrofuran for the efficient synthesis of 2,3-disubstituted tetrahydrofurans
Xingxing Zhu, Man-Yi Han, Pinhua Li and Lei Wang –
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00242D, Research Article

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Hot Articles in April 2017

15 May 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of April 2017!

You can access these publications for free till 30^th June 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Radical cyclization of benzene-tethered 1,7-enynes with aryldiazonium tetrafluoroborates: a facile route to benzo[j]phenanthridines
Yuanyuan An, Jun Zhang, Hongguang Xia and Jie Wu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00193B, Research Article

Asymmetric synthesis of CF₃– and indole-containing tetrahydro-β-carbolines via chiral spirocyclic phosphoric acid-catalyzed aza-Friedel–Crafts reaction
En Xie, Abdul Rahman and Xufeng Lin
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00229G, Research Article

Squaramide-catalyzed domino Michael/aza-Henry [3 + 2] cycloaddition: asymmetric synthesis of functionalized 5-trifluoromethyl and 3-nitro substituted pyrrolidines
Qiang Liu, Kun Zhao, Ying Zhi, Gerhard Raabe and Dieter Enders
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00161D, Research Article

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Hot Articles in March 2017

17 Apr 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of March 2017!

You can access these publications for free till 31^st May 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Synthesis of 3-((arylsulfonyl)methyl)indolin-2-ones via insertion of sulfur dioxide using anilines as the aryl source
Tong Liu, Danqing Zheng and Jie Wu
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00075H, Research Article

Iridium-catalyzed asymmetric hydrogenation of cyclic iminium salts
Yue Ji, Guang-Shou Feng, Mu-Wang Chen, Lei Shi, Haifeng Du and Yong-Gui Zhou
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00060J, Research Article

Enantioselective synthesis of naturally occurring isoquinoline alkaloids: (S)-(−)-trolline and (R)-(+)-oleracein E
Weilong Lin and Shengming Ma
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00062F, Research Article

Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes
Liu Song, Weiming Yuan and Shengming Ma
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00135E, Research Article

Highly enantioselective nitro-Mannich reaction of ketimines under phase-transfer catalysis
Bin Wang, Tong Xu, Lei Zhu, Yu Lan, Jingdong Wang, Ning Lu, Zhonglin Wei, Yingjie Lin and Haifeng Duan
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00124J, Research Article

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Hot Articles in February 2017

27 Mar 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of February 2017!

You can access these publications for free till 30^th Apr 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

The impact of interplay between electronic and steric effects on the synthesis and the linear and non-linear optical properties of diketopyrrolopyrrole bearing benzofuran moieties
Anna Purc, Beata Koszarna, Irina Iachina, Daniel H. Friese, Mariusz Tasior, Krzysztof Sobczyk, Tomasz Pędziński, Jonathan Brewer and Daniel T. Gryko
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00869K, Research Article

A chiral ion-pair photoredox organocatalyst: enantioselective anti-Markovnikov hydroetherification of alkenols
Zhongbo Yang, Han Li, Sujia Li, Ming-Tian Zhang and Sanzhong Luo
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00806B, Research Article

(1S)-(−)-N-Trifluoromethylthio-2,10-camphorsultam and its derivatives: easily available, optically pure reagents for asymmetric trifluoromethylthiolation
He Zhang, Xuebing Leng, Xiaolong Wan and Qilong Shen
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00042A, Research Article

KBr/K₂S₂O₈-mediated dibromohydration of N-(2-alkynylaryl)acetamide
Guanyinsheng Qiu, Yuewen Li, Lele Ma and Hongwei Zhou
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00840B, Research Article

A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid
Wenju Chang, Jie Dai, Jingfu Li, Yuan Shi, Wenlong Ren and Yian Shi
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00111H, Research Article

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Hot Articles in January 2017

17 Feb 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of January 2017!

You can access these publications for free till 15^th Mar 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization
Hui Chen, Cong Lin, Chunhua Xiong, Zhanxiang Liu and Yuhong Zhang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00755D, Research Article

Phosphine-mediated domino reactions of phthalimidomalonates with allenoates or but-2-ynoate: facile entry into highly functionalized pyrroloisoindolinone derivatives
Zhusheng Huang, Qingqing Chen, Xiuqin Yang, Yang Liu, Li Zhang, Tao Lu and Qingfa Zhou
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00775A, Research Article

5-Azadibenzo[a,g]corannulene
V. M. Tsefrikas, A. K. Greene and L. T. Scott
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00831C, Research Article

From tetrabenzoheptafulvalene to sp² carbon nano-rings
Kwan Yin Cheung, Shuaijun Yang and Qian Miao
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00828C, Research Article

Iridium catalysts with modular axial-unfixed biphenyl phosphine–oxazoline ligands: asymmetric hydrogenation of α,β-unsaturated carboxylic acids
Qian Wang, Zongpeng Zhang, Caiyou Chen, Hailong Yang, Zhengyu Han, Xiu-Qin Dong and Xumu Zhang
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00677A, Research Article

Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution
He Chen, Lin Zhu and Chaozhong Li
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00854B, Research Article

Thiolate–palladium(IV) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions
Dongdong Xu, Xiaotian Qi, Meng Duan, Zhaoyuan Yu, Lei Zhu, Chunhui Shan, Xiaoyu Yue, Ruopeng Bai and Yu Lan
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00841K, Research Article

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Hot Articles in December 2016

13 Jan 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of December 2016!

You can access these publications for free till 15^th Feb 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Mechanism of selective C–H cyanation of 2-phenylpyridine with benzyl nitrile catalyzed by CuBr: a DFT investigation
Da-Gang Zhou, Fan Yang, Xing Yang, Chao-Xian Yan, Pan-Pan Zhou and Huan-Wang Jing
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00652C, Research Article

New reactivity of ethynyl benziodoxolone: modulating iron-catalyzed dehydration of propargyl alcohols
Huiyu Chen, Xiaoru Shao, Huifei Wang and Hongbin Zhai
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00631K, Research Article

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Hot Articles in November 2016

22 Dec 2016

Organic Chemistry Frontiers is delighted to share with you the HOT articles of November 2016!

You can access these publications for free till 15^th Jan 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Synthesis of a figure-eight azahelicene dimer with high emission and CPL properties
Ayako Ushiyama, Satoru Hiroto, Junpei Yuasa, Tsuyoshi Kawai and Hiroshi Shinokubo
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C6QO00629A, Research Article