| Metal and metal-containing clusters have received considerable interest within the scientific community due to their wide range of applications in areas like catalysis and biomedicine. This focus collection highlights the exciting articles on the metal and metal-containing clusters that recently appeared in Inorganic Chemistry Frontiers. Articles featured in our focus collections are handpicked by Editors. We hope you find them enjoyable to read. |  |
Review Articles
State-of-the-art strategies for the synthesis of zeolite-encapsulated subnanometric metal clusters
Konnov, Stanislav V.; Bruter, Daniil V.; Pavlov, Vladimir S.; Ivanova, Irina I.
Atomically precise nanocluster-catalyzed coupling reactions
Hu, Jinhui; Li, Yi-Ming; Zhang, Bei; Kang, Xi; Zhu, Manzhou
Design strategies and applications of electrochemiluminescence from metal nanoclusters
Li, Tingting; Sui, Jiyu; Dong, Weinan; Zhang, Yu; Zhang, Ying; Li, Yanan; Wu, Zhennan; Bai, Xue
A dual-heteroatom-lanthanide cluster-embedded polyoxotungstate for sequential fluorescence detection of Fe³⁺ and pyrophosphate
Zhang, Siyu; Gong, Tiantian; Liu, Chenyun; Wang, Qiuyu; Chen, Fuxiu; Liu, Jiancai; Chen, Lijuan; Zhao, Junwei
Recent studies on the reaction of [X₆O₁₉]⁸⁻ (X = Nb, Ta) polyanions under acidic conditions
Wang, Haiying; Liang, Zhijie; Zhang, Dongdi; Niu, Jingyang
Tuning photoluminescence properties of Au clusters by surface modification and doping: lessons from case studies of icosahedral Au₁₃
Buschmann, Dennis Alexander; Hirai, Haru; Tsukuda, Tatsuya
Stimuli-responsive gold-polyoxometalate multielectron transformers
Monakhov, Kirill
Targeting protein aggregation: the promising application of polyoxometalates in neurodegenerative diseases
Chen, Junyi; Yang, Wen-Zhu; Chen, Huilan; Ding, Xiuxia; Chen, Hongxu; Zhan, Cai-Hong; Jin, Zhigang
Research Articles
Ligand-mediated core structure engineering and luminescence of metal nanoclusters: tuning emission from NIR-I to NIR-II
Liu, Jia-Wei; Li, Dan; Lu, Peng-Xu; Wen, Tao-Xiao; Chen, Yan-Ru; Jia, Jian-Hua; Tong, Ming-Liang
Disobedient boron clusters: synthesis, structure and bonding of hypoelectronic open and closo osmaborane clusters
Kar, Ketaki; Saha, Suvam; Patel, Deepak Kumar; Ghosh, Sundargopal
The first fcc-type (AgCu)₁₄ alloy nanocluster with unexpected Cu core doping
Yang, Jin-Sen; Zhang, Li-Jun; Xiao, Lu-Yao; Li, Jin; Dong, Xi-Yan
Fivefold-symmetry-induced reverse template effect: self-assembly of a high-nuclear core-shell polyoxophosphovanadate
Yuan, Meng; Yao, Aiping; Zhao, Liang; Wang, Xinlong; Qin, Chao; Su, Zhongmin
Acidity/hydridicity evaluation of Sb-H bonds and formation of a new group 15 metal cluster topology
MacEachern, Mitchell A. Z.; George, Tanner; Chitnis, Saurabh S.
Atomically precise metal nanocluster sandwich heterojunction for robust and efficient photocatalytic CO₂ reduction to methanol
Lu, Rui; Yao, Aimin; Dai, Yali; Yin, Haijiao; Li, Chengqi; Du, Yuanxin; Zhu, Manzhou
Tailoring two magic number Au₁₃ nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO-shaped core
Liu, Jing; Liu, Jia-Chuan; Wang, Hai-Ling; Liao, Pei-Yu; Jia, Jian-Hua; Tong, Ming-Liang
Insight into the role of Cd atoms in clusters for the oxidation reaction of styrene
Liu, Zhiping; Feng, Lijie; Qin, Chenzhan; Qian, Feng; Li, Qinzhen; Chai, Jinsong; Lv, Ying; Yang, Sha; Zhu, Manzhou
Pyramidal Nd₂ScN inside an icosahedral C₈₀ cage
Yang, Wei; Wang, Yaofeng; Popov, Alexey A.; Liu, Fupin
Dual-state heptanuclear metal cluster-based MOF materials: open metal site enhanced acetylene/ethylene separation and coordinated water-driven propylene/propane kinetics
Zhang, Rizhao; Fan, Yaqing; Xue, Jin-peng; Chai, Yuqiao; Li, Bao; Li, Jia
Sulfonylcalix[4]arene-based Al₄ clusters: three aluminum oxo clusters with different coordinated solvents for the CO₂ cycloaddition reaction
Liu, Xiao-Jie; Guo, Long-Xue; Xu, Wei; Wang, Ya-Wen; Tian, Yuan-Hang; Zhao, Li-Xing; Li, Xiao-Yu; Li, Jin-Hua; Wang, Guo-Ming
N-heterocyclic carbene-stabilized Cu₉ clusters with combined thermally activated delayed fluorescence and phosphorescence
Zhang, Lin-Mei; Xie, Mo; Wei, Hui-Zhi; Yuan, Shang-Fu; Li, Dong-Sheng; Wu, Tao
Calix[6]arene-functionalized titanium-oxo clusters for photocatalytic cycloaddition of carbon dioxide to epoxides
Hou, Jinle; Liu, Yuxin; Huang, Nahui; Azam, Mohammad; Huang, Chen; Wang, Zhi; Huang, Xianqiang; Qu, Konggang; Sun, Di
Cobalt nanoparticles coupled with polyoxometalate nanoclusters to boost electrocatalytic conversion of nitrite to ammonia at low potentials
Wang, Qiu-Feng; Jia, Meng-Qi; Yin, Xing-Yu; Zheng, Sha; Yang, Wei-Xin; Ma, Cheng; Ni, Lu-Bin; Diao, Guo-Wang; Zhang, Lu-Nan
Fluorine-containing counterions as catalysts triggering the size transformation of copper nanoclusters
Si, Ningjing; Xu, Ying; Fang, Xiaolong; Zhao, Donglin; Li, Hao; Kang, Xi; Zhu, Manzhou
Solvent-induced assembly and photocatalytic properties of atomically precise tellurotungstate-templated Ag clusters
Ning, Jiwei; Zhao, Mengyun; Dong, Yuanyuan; Chi, Manzhou; Li, Yurui; Feng, Yeqin; Qin, Yun; Lv, Hongjin; Yang, Guo-Yu
Near-infrared luminescence AgPd alloy superatomic clusters
Ma, Xiao-Hong; Qin, Jian-Hua; Wang, Fei-Fan; Luo, Peng; Dong, Xi-Yan
Alkaline earth-tuned polyoxometalate frameworks: enhanced selectivity in styrene epoxidation
Duan, Zhi-Cheng; Li, Guanghua; Cui, Xiao-Bing
Crystallization induces thermally activated delayed fluorescence of Ag₁₄ nanoclusters
Yang, Jin-Sen; Xiao, Lu-Yao; Liu, Fan; Xu, Jun; Dong, Xi-Yan; Hu, Jia-Hua; Li, Jing; Zang, Shuang-Quan
Self-assembly of a giant molybdenum titanium-oxo cluster [Mo₄₂Ti₁₂(O₂)₂₄] for bifunctional oxidation catalysis
Xu, Ming; Wang, Ting; Zhang, Wenjing; Guo, Keke; Wang, Ping; Qin, Chao; Xu, Lin; Su, Zhongmin; Wang, Xinlong
Structural disproportionation of Ag₂₀Cu₁₀ highlights the impact of cluster structure on electrocatalytic properties for CO₂ reduction
Wang, Yujiao; Xiong, Lin; Cheng, Qian; Hu, Daqiao; Jin, Shan; Zhu, Manzhou
Effect of chiral camphor thiolate ligands on the structure and stability of Au₁₉ nanoclusters
Zhang, Xiaoya; Wu, Shuwen; Li, Qinzhen; Chai, Jinsong; Gao, Guiqi; Huang, Baoyu; Yang, Sha; Zhu, Manzhou
Self-assembly of high-nuclear core-shell polyoxovanadates with Lindqvist templates
Wu, Shuangxue; Fu, Yaomei; Gan, Hongmei; Zhao, Liang; Wang, Xinlong; Qin, Chao; Su, Zhongmin
First tetrametallic 19-nuclear Ceᴵᴵᴵ-Scᴵᴵᴵ-Wⱽᴵ-Sbᴵᴵᴵ cluster-incorporated polyoxometalate for electrochemical biosensing of CYFRA21-1
Li, Jiaxin; Tang, Zhigang; Liu, Yu; Chen, Lijuan; Zhao, Junwei
An unprecedented oxalate-functionalized Ta/W polyoxometalate enabling the self-assembly of a 2D composite for catalytic hydrogenation
Li, Shujun; Huang, Meng-Yao; Cheng, Weiyi; Shah, Waqas Ali; Dai, Xu-Sheng; Ma, Nana; Zhao, Qianyi; Chen, Xuenian
Controlling the structural and adsorption features of polyoxovanadate-based metal-organic clusters by adjustable template effect
Wang, Yan-Hu; Tong, Ke-Wei; Chen, Chao-Qin; Du, Jing; Yang, Guo-Ping; Yang, Peng
Archimedean heterologous helixes in Ti₁₀Cd₆-oxo nanoclusters: double-helical self-assembly and therapeutic application in Parkinson’s disease
Meng, Ling-Cui; Chen, Jun-Yi; Feng, Zhi-Ming; Jiang, Zhan-Guo; Jin, Zhigang; Zhan, Cai-Hong
New members of the lanthanide titanium cluster family: Janus nanoclusters and their applications in optical imaging and photodynamic therapy
Li, Ru-Yan; Qin, Wen-Wen; Yang, Fan; Wang, Hai-Ling; Tang, Meng-Juan; Zou, Hua-Hong; Liang, Fu-Pei; Chen, De-Xin; Zhu, Zhong-Hong
High-nuclearity Ag-substituted tetrameric sandwich-type polyoxometalates for excellent catalytic performance in C-C bond formation
Sun, Yahao; Cai, Minzhen; Chen, Hanhan; Ma, Pengtao; Niu, Jingyang; Wang, Jingping
A purely inorganic germanium-molybdenum-oxo cluster with ruthenium participation for visible-light-driven CO₂ reduction
Li, Kunhong; Hong, Yumei; Ma, Xinyi; Zhao, Yujie; Zhang, Shihao; Ma, Pengtao; Niu, Jingyang; Wang, Jingping
A two-dimensional confined polyoxometalate-based chiral luminescence sensor for highly enantioselective sensing
Hu, Guicong; Wu, Zhaohui; Cai, Ailin; Xing, Xinzhu; Chang, Wen; Qiao, Qinglong; Qi, Bo; Song, Yu-Fei
Ligand-regulated catalytic activity in fluorescent gold nanoclusters
Yang, Wenxuan; Wang, Shenming; Wei, Xiaoyun; Feng, Zhenzhen; Qin, Guangyong; Mao, Jian; Zhen, Zheng; Miao, Xintong; Cheng, Yifeng; Wang, Xiaojuan; Huang, Fang; He, Hua
A series of four-substituted polyoxometalate-thiacalix[4]arene-based materials for the efficient photocatalytic reduction of Cr(Ⅵ)
Zhang, Jia-Yi; Song, Yuting; Yang, Jin; Pei, Wen-Yuan; Ma, Jian-Fang
Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo₁₂₀Ce₆}₂ dimers for high-efficiency photocatalytic oxidation
Zhou, Dexiang; Li, Bingbing; Zhao, Qixin; Tang, Xinyu; Lan, Tingya; Su, Heyang; Yang, Guoping; Xuan, Weimin
Cluster-like Mo₂N anchored on reduced graphene oxide as an efficient and high-performance catalyst for deep-degree oxidative desulfurization
Song, Weizhuang; Wang, Dongxu; Yue, Xianyun; Jin, Chengxu; Wu, Yangchen; Shi, Yu; Liu, Jiancong; Wu, Aiping; Tian, Chungui; Fu, Honggang
A pair of diphosphine-protected gold nanoclusters differing by a single gold atom on the kernel surface
Li, Wenming; Wang, Shuguang; Wang, Yonghong; Chen, Yining; Lei, Xiaofeng; Diao, Jianfeng; Dai, Afang; Liu, Fuling; Gan, Zibao; Zheng, Xiuwen
Superatomic interconversion causes reversible on-off luminescence of doped silver nanoclusters
Lei, Wenjie; Shao, Yang; Ren, Fangya; Guo, Mengdi; You, Qing; Fang, Xianjun; Kong, Jie; Zhou, Meng; Yin, Baoqi; Luo, Zhixun
Atomically precise Ag₂₅(SR)₁₈ nanoclusters: a stable photosensitizer for photocatalysis
Zhan, Linjian; Zhang, Junyi; Ning, Boyuan; He, Yunhui; Xiao, Guangcan; Chen, Zhixin; Xiao, Fang-Xing
Fast and selective protein modification with iron-substituted polyoxometalates via a radical pathway
Moussawi, Mhamad Aly; Abdelhameed, Shorok A. M.; de Azambuja, Francisco; Wijten, Andy; Vasovic, Tamara; Velickovic, Tanja Cirkovic; Parac-Vogt, Tatjana N.
Nanocluster-regulated porous ionic rotaxane assemblies with solvent-adaptability for selective adsorption and conductivity
Wang, Jiaxu; Wei, Mingfeng; Zhu, Zexi; Li, Bao; Wu, Lixin
Enhancing the performance of polyoxometalate-based memristors in harsh environments based on hydrogen bonding and cooperative π-conjugation interactions
Meng, Ming-Ze; Gao, Yi-Qun; Chen, Yi-Ping; Li, Hao-Hong; Huang, Xiao-Hui
Assembly of Si-substituted heteropolyoxotantalate architecture
Chen, Hanhan; Xu, Haojie; Ma, Xinyi; Ma, Pengtao; Wang, Jingping; Niu, Jingyang
Atomically precise Cu₁₄ and Cu₁₃ nanoclusters for the oxygen evolution reaction: one additional Cu atom matters
Liu, Ziyi; Zhu, Pan; Zhou, Xianxing; Qin, Lubing; Liu, Xunying; Tang, Qing; Tang, Zhenghua
An hourglass-shaped nickel-based polyoxometalate crystalline material as a highly efficient bifunctional electrocatalyst for the oxygen evolution reaction and detection of H₂O₂
Li, Yajie; Zhu, Na; Su, Zhixuan; Hu, Xiaoli; Dou, Zhiyu; Su, Zhongmin
Synergistic crystalline catalysts assembled with Wells-Dawson-type polyoxometalates and heterovalent metal complexes for efficient benzylic C-H bond oxidation
Liu, Ze-Xuan; Du, Jing; Li, Shuai; Zhu, Miao-Qi; Ma, Yuan-Yuan; Han, Zhan-Gang
Kernel-differentiated fusion strategy redefines critical size thresholds in giant twinned-FCC RS-AuNCs: unlocking size adaptability and birth of metallicity
Fang, Youqiong; Wang, Pu; Pei, Yong; Xiong, Lin
The rise and fall of copper hydride clusters: a snapshot of hexanuclear-to-dodecanuclear expansion
Ekanayake, Dewmi A.; Krause, Jeanette A.; Guan, Hairong
Photoredox catalysis enabled by atomically precise metal nanoclusters
Zhang, Junyi; Zhan, Linjian; Ning, Boyuan; He, Yunhui; Xiao, Guangcan; Chen, Zhixin; Xiao, Fang-Xing
Copper doping boosts the catalase-like activity of atomically precise gold nanoclusters for cascade reactions combined with urate oxidase in the ZIF-8 matrix
Wang, Yi-Shu; Chen, Yan; Dong, Chen; Wang, Zhao-Yang; Cai, Jinmeng; Zhao, Xueli; Mo, Hui-Lin; Zang, Shuang-Quan
Core-shell [Cu₄₅(C₆H₁₁S)₂₄(P(PhF)₃)₄H₁₉]²⁺ nanocluster: synthesis, structure and catalytic hydroboration
Yu, Hang; Jia, Jianmei; Yang, Tao; Chen, Kai; Jin, Shan; Xiong, Lin; Zhu, Manzhou
Boosting the oxygen reduction activity of silver nanoclusters via selective exposure of solvent-coordinated sites
Wang, Zhao-Di; Han, Ye; Sun, Wen-Yan; Peng, Peng; Zang, Shuang-Quan
A wheel-like polyoxometalate for haloperoxidase-inspired antibiofouling with H₂O₂ in situ provided by electrocatalysis
Bian, Yumeng; Wang, Runze; Xu, Xinxin; Chen, Jin; Wang, Qiang
An unprecedented {Y₂⊂Y₁₀} type disk-like Y₁₂ nanocluster featuring electroluminescence property in OLED device
Shi, Lin-Ping; Li, Wen-Liang; Wang, Pu-Yue; Wu, Xiao-Ming; Yao, Zhao-Quan; Zhao, Jiong-Peng; Liu, Fu-Chen
Stepwise synthesis of symmetric and asymmetric Anderson-polyoxometalates for light-driven hydrogen evolution
Endres, Patrick; Sachdeva, Garima; Winter, Andreas; Diaz, Dolores; Goerls, Helmar; Fritz, Nicole; Neumann, Christof; Turchanin, Andrey; Streb, Carsten; Schubert, Ulrich S.
Polyoxometalate-assisted crystallization for ultraselective Ln(Ⅲ)/An(Ⅵ) separation under strongly acidic conditions
Zhang, Guangtao; Li, Yarui; Chen, Jiarui; Cui, Yunyi; Zhou, Xiaoyuan; Zou, Qing; Guo, Xiaofeng; Li, Yongxin; Lin, Peng; Lin, Jian
Highly reversible Zn electrodeposition enabled by glutathione-protected copper nanoclusters for aqueous Zn-ion batteries
Wang, Lu-Fan; Wang, Xiao-Yuan; Xu, Shu; Wu, Zhou; Sun, Guoqiang; Liu, Xiao-Fei; Huang, Ren-Wu; Zang, Shuang-Quan
A low-loss optical waveguide from a 1D europium nanocluster
Xia, Jingjing; Dong, Weinan; He, Shengrong; Jiang, Feng; Tian, Wenming; Sun, Qi; Hong, Meixin; Meng, Lingchen; Zhang, Yu; Wu, Zhennan; Li, Tingting; Bai, Xue
Insights into the intricate charge photoaccumulation in a polyoxometalate-BODIPY covalent hybrid
Carino, Christian; Moussa, Naguy; Blanchard, Sebastien; Sole-Daura, Albert; Proust, Anna; Izzet, Guillaume
Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature
Zuo, Ya-Kun; Li, Yan-Ru; Sun, Yan-Qiong; Li, Xin-Xiong; Sun, Cai; Zheng, Shou-Tian
Achieving ultra-trace analysis and multi-light driven photodegradation toward phenolic derivatives via a bifunctional catalyst derived from a Cu(Ⅰ)-complex-modified polyoxometalate
Li, Shuang; Wang, Bingqian; Liu, Guocheng; Li, Xiaohui; Sun, Chang; Zhang, Zhong; Wang, Xiuli
L-Arginine-modified gold nanoclusters for rapid and visual quantification of bacterial infection
Hong, Le; Ding, Lina; Ma, Zhenyu; Wang, Lin; Wang, Kun; Dong, Weinan; Qi, Manlin; Shi, Yujia; Liu, Chenyu; Sun, Xiaolin; Bai, Xue; Li, Chunyan; Wu, Zhennan
Coinage metal(Ⅰ) clusters based on a flexible P,P′(N,N′)₂-ligand: colorful phosphorescence, abnormal thermal quenching behavior and anticounterfeiting application
Baranov, Andrey Yu.; Doronina, Evgeniya P.; Rakhmanova, Mariana I.; Bagryanskaya, Irina Yu.; Brylev, Konstantin A.; Sukhikh, Taisiya S.; Artem’ev, Alexander V.
Boosting the high rate and durability of lithium-sulfur batteries using a bidirectional catalyst of a polyoxometalate-cyclodextrin supramolecular compound
Song, Jian; Jiang, Yuanyuan; Lu, Yizhong; Cao, Yundong; Zhang, Yuxi; Fan, Linlin; Liu, Hong; Gao, Guanggang
Unveiling the unique promotional role of samarium in polyoxometalate catalysed selective oxidation of benzyl alcohol
Feng, Su-Yuan; Rong, Zhong-Yi; Chen, Qinwei; Wu, Xiao-Yuan; Wu, Weiming; Wang, Sa-Sa; Lu, Can-Zhong
Visualizing the fluorescence of AgPt NCs by an asymmetrical pseudo-ligand exchange method
He, Lizhong; Dong, Tingting; Hu, Xiaoyang; Gan, Zibao
Multispin superatoms: seven-nuclear rhenium clusters with unusual magnetic properties
Pronin, Aleksei S.; Gaifulin, Yakov M.; Sukhikh, Taisiya S.; Lavrov, Alexander N.; Mironov, Yuri V.
Narrow-band circularly polarized red electroluminescence in trinuclear clusters
Yang, Xin; Cheng, Han; Shi, Lin-Xi; Wang, Jin-Yun; Chen, Zhong-Ning
Mixed addenda polyoxometalates by cooperative self-assembly and modulation of their optoelectronic properties
Singh, Ganga; Choudhary, Ruchika; Mandal, Debaprasad
Enhancing room-temperature CO oxidation via encapsulation of bimetallic PtNi clusters within mesoporous silicate-1 catalysts
Cui, Ronghua; Yang, Siyuan; Zhang, Lifeng; Chen, Xing; Luo, Langli
A series of pinwheel-shaped Ln₂₁-oxo-cluster-embedded polyoxometalates as single-crystal proton-conductive and tunable photoluminescent materials
Cao, Yun-Fei; Jin, Xin-Rong; Xia, Wen-Jun; Sun, Yan-Qiong; Li, Xin-Xiong; Zheng, Shou-Tian
Two robust polyoxovanadate clusters having a square-prism V₁₀Ox core for efficient catalysis of benzene hydroxylation to phenol
Wang, Ji-Lei; Xu, Ling-Xi; Wang, Qin; Yan, Pin-Fang; Chen, Xin-Lian; Jin, Ting; Mei, Hua; Xu, Yan
Structural regulation of NHC-protected copper(Ⅰ) clusters through substitution for photoluminescence enhancement
Yang, Yan-Yan; Hao, Rui-Chen; Wu, Qing-Qing; Luo, Peng; Xu, Jun; Dong, Xi-Yan; Zhang, Chuan-Xiang
Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu₄Br₄ cluster
Lu, Xin; Wu, Shao-Jie; Wang, Ya-Shu; Wei, Shan-Yue; Meng, Lingyi; Huang, Xi-He; Chen, Xu-Lin; Lu, Can-Zhong
Luminescent cyanide coordination polymer based on {Mo₆I₈} and {Ag₂(dppm)₂} clusters: exceptional stability and efficient scintillation
Litvinova, Yulia M.; Stass, Dmitri V.; Metlin, Mikhail T.; Korshunov, Vladislav M.; Ryzhikov, Maxim R.; Yarovoy, Spartak S.; Sukhikh, Taisiya S.; Mironov, Yuri V.; Taydakov, Ilya V.; Belikova, Daria E.; Tarasov, Alexey B.; Brylev, Konstantin A.; Gaifulin, Yakov M.
Enhancing electrocatalytic hydrogen evolution efficiency: tuning catalyst support pore size to optimize hydrogen adsorption-desorption kinetics
Zhou, Yong; Yang, Bin; Li, Bing; Liu, Xiaoyang
Unraveling active ensembles consisting of clusters and single atoms for oxygen reduction: a synergy of machine learning and DFT calculations
Li, Xinyi; Jiao, Dongxu; Zhao, Jingxiang; Zhao, Xiao
The chemical tug-of-war in carborane clusters: distinct tuning on different sides of the cluster
Buzsaki, Daniel; Gal, Dalma; Szathmari, Balazs; Holczbauer, Tamas; Udvardy, Antal; Szilagyine, Julia Kertesz; Kargin, Denis; Bruhn, Clemens; Pietschnig, Rudolf; Kelemen, Zsolt
Unprecedented lead-antimony oxohalide clusters with efficient capture of UO₂²⁺ ions
Luo, Jia-Hua; Ren, Yu-Wei; Yang, Lu; Wang, Jing; Xiao, Hao-Dan; Xian, Feng-Hua; Sun, Hai-Yan; Feng, Mei-Ling; Hu, Bing; Huang, Xiao-Ying
An artificial enzyme of a polyoxometalate-supported cobalt complex for the oxidation of isochromans to isochromanones by activating O₂
Ren, Xiangyu; Tian, Hongrui; Chen, Baokuan; Dai, Lingling; Bi, Yanfeng; Yang, Guoping
[²Fe-²S] clusters supported by N-heterocyclic carbene ligands
Ye, Yuwei; Jiang, Xuebin; Liu, Qing; Ye, Shengfa; Deng, Liang
Low-valent tantalum/gold clusters: oxidation, protonation, and C-H activation
Maiola, Michela L.; Buss, Joshua A.
Tunable luminescent lanthanide cluster-based hydrogel probe for ratiometric detection of ofloxacin, anti-counterfeiting, and magnetocaloric applications
Wang, Tian-Tian; Wang, Hao; Sun, Wen-Bin
Modulating ligand-to-metal charge transfer in titanium-oxo clusters enables efficient H₂O₂ activation and pollutant degradation
Wang, Zihang; Peng, Wenxin; Geng, Jintao; Wang, Hui; Zhang, Xiaodong; Xie, Yi
Polymetallic titanium chalcogenide clusters comprising {Eₙ}²⁻ ligands (E = S, Se; n = 1–3)
Bairagi, Subhash; Giri, Soumen; Chatterjee, Debipada; Chowdhury, Soham; Ghosh, Sundargopal
Supracluster assembly of an Al₄ precursor toward the study of enhanced optical properties
Yang, Fan; Chen, Rui-Yan; Wang, San-Tai; He, Yan-Ping; Fang, Wei-Hui; Zhang, Jian
Engineering geometric metamorphosis in {P₆M₂Mo₁₆O₇₃}-based high-nuclearity metal superclusters: from tetrahedral to square assemblies via topological transformations
Zhang, Xiaoyan; Li, Hui; Xu, Na; Liu, Xiaodong; Wang, Xiu-Li
Combination of dimensional reduction and active site addition strategies for preparing unique {RE₉}-cluster-based MOFs: efficient CO₂ fixation and Knoevenagel condensation
Zhao, Ying; Wu, Dan; Qiao, Yidan; Yang, Guo-Ping; Ma, Lu-Fang; Wang, Yao-Yu
A long-range synergistic effect between Ptₙ clusters and Zn₁ single atoms for efficient selective hydrogenations
Wei, Haisheng; Li, Jing; Yan, Xiaorui; Liu, Tiantian; Li, Kairui; Feng, Dan; Ren, Yujing
UN@C₂(13)-C₈₄: a diatomic cluster with a U=N triple bond inside a C₈₄ fullerene cage
Meng, Qingyu; Rosello, Yannick; Shen, Yi; Yao, Yang-Rong; Poblet, Josep M.; Rodriguez-Fortea, Antonio; Chen, Ning
The effect of the large cation matrix and delocalization of electronic density on the switchable behaviour of heterotrimetallic cyanido-bridged FexMn₉₋xW₆ clusters
Kobylarczyk, Jedrzej; Koziel, Marcin; Dziedzic-Kocurek, Katarzyna; Michalik, Jan M.; Pinkowicz, Dawid; Fitta, Magdalena; Sieklucka, Barbara; Podgajny, Robert
Magneto-optical response and luminescence properties of lanthanide-titanium-oxo clusters
Liu, Wei-Dong; Xu, Han; Li, Chong-Yang; Long, La-Sheng; Zheng, Lan-Sun; Kong, Xiang-Jian
Highly dispersed Ru cluster-embedded nitrogen-doped hollow carbon spheres with tunable electronic properties for efficient catalytic reductive amination of biomass-derived furfural
Wu, Jun; Pan, Gang; Jin, Ming; Bai, Jiahao; Shi, Tailong; Li, Yong
Ionothermal synthesis of a stable three-dimensional [Cu₄I₄] cluster scintillator with near-unity quantum efficiency and weak thermal quenching
Zou, Qing-Hua; Yang, Wen-Hao; Wu, Ling-Kun; Jiang, Lu-Lu; Wang, Shuai-Hua; Liu, Lang; Li, Ren-Fu; Ye, Heng-Yun; Li, Jian-Rong
An unprecedented Cu₆ cluster-based bimetallic MOF with multiple open sites for high CO₂ capture and efficient CO₂ conversion
Yu, Xueyue; Gu, Jiaming; Tang, Baobing; Xu, Tong; Li, Guanghua; Chang, Zhiyong; Liu, Yunling
Polyoxoniobates with the long-sought feature of face-sharing octahedra stabilized by Te(Ⅳ): a synthetic analogue of natural minerals
Zhen, Ni; Li, Run-Han; Xue, Binghui; Liu, Jingjing; Xu, Shan; Zhang, Chao; Lei, Peng; Dong, Jing; Chi, Yingnan; Yin, Panchao; Lan, Ya-Qian; Hu, Changwen
Enhanced reactive oxygen species generation and pollutant adsorption in advanced oxidation processes via Ru cluster-oxygen vacancy synergy on a BiOCl (110) facet
Zhang, Wensheng; Ding, Bo; Liang, Zhishan; Huang, Youlin; Qin, Dongdong; Han, Dongxue
A bis-aromatic MOF system constructed with a copper iodine cluster and porphyrinic ligand for enhancing near-infrared photothermal conversion
Cao, Man; Wang, Qian-You; Li, Run-Meng; Dai, Fangfang; Wang, Shan; Luo, Peng; Hu, Jia-Hua; Dong, Xi-Yan; Huang, Ren-Wu
Near-unity room-temperature phosphorescence quantum yield induced by halogen-halogen interaction in chiral hybrid copper(Ⅰ) iodide clusters
Qin, Yanjing; Wei, Jianwu; Li, Jing; Li, Xianli; Luo, Binbin; Chen, Peican; Zhou, Liya; Zhang, Jin Zhong; Pang, Qi
Distinct roles of fast, slow, and unobservable relaxation regimes controlling proton transport barriers in lanthanide metal-organic coordination polymers featuring hexameric water clusters
Wu, Xingru; Xie, Fengxia; Wan, Chengan; Chen, Bingtang; Jia, Yifeng; Ji, Hejia; Li, Pingping; Zhang, Feng; Feng, Lei; Wen, Chen; Liang, Xiaoqiang
Pt single atom and atomic cluster-enhanced TiO₂ Janus micromotors for efficient bubble propulsion and photocatalytic environmental remediation
Lv, Chang; Wang, Tao; Fang, Yeting; Ying, Yulong; Ji, Lvlv; Liu, Lei; Wang, Sheng
A coordination polymer based on tetranuclear Tb³⁺ clusters exhibiting dual turn-on/off fluorescence sensing of long- and short-chain polyfluoroalkyl substances
Long, Chanreingam; Chen, Zhonghang; Ye, Jiayin; Ma, Shixuan; Xu, Enting; Qiao, Yuchen; Gao, Min; Zhou, Xuequan; Zheng, Fangrui; Yang, Xuemei; Ren, Peng
Tailoring supertetrahedral cadmium/tin selenide clusters into a robust framework for efficient elimination of Cs⁺, Co²⁺, and Ni²⁺ ions
Wang, Kai-Yao; Li, Meng-Yu; Cheng, Lin; Hao, Xin; Wang, Cheng
Significant adsorption enhancements driven by pore microenvironment tuning for efficient C₂H₂/C₂H₄ separation in a chemically stable Ni₇-cluster-based framework
Wang, Yunli; Zhang, Rizhao; Xue, Jin-Peng; Chai, Yuqiao; Li, Bao; Li, Jia
Two X-shaped {Eu₆}-embedded water-soluble heterometallic polyoxotungstates based on {Eu₆M₄WSe₄(GeW₁₀)₄} (M = Cr, Al) clusters with resistance-switching
Cao, Yun-Fei; Chen, Ju-Ning; Shen, Xiao-Min; Sun, Yan-Qiong; Zheng, Shou-Tian
Reversible formation of yttrium planar cyclo-P₄ clusters and their selective conversion: access to mixed Pⱽ/Pᴵᴵᴵ cyclo-P₄ units
Han, Keyu; You, Qing; Ye, Zihao; Li, Kunhua; Li, Yunmeng; Duan, Sujiao; Zhang, Junliang; Zhou, Xigeng; Zhang, Jie
Linker-cluster cooperativity in confinement of proline-functionalized Zr-based metal-organic frameworks and its effect on the organocatalytic aldol reaction
Dilruba, Zarfishan; Yeganeh, Ardeshir D.; Kolin, Sofia; Noor, Sadia; Shatla, Hassan; Wieland, Carl; Yu, Bo-Hung; Gugeler, Katrin; Zens, Anna; Kaestner, Johannes; Estes, Deven P.; Pluhackova, Kristyna; Krause, Simon; Laschat, Sabine
A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C₂H₆/C₂H₄ separation
Feng, Meng; Li, Jiantang; Wang, Xirong; Wang, Jingyu; Wang, Dongmei; Chen, Banglin
Unleashing the power of directed electron transfer: unraveling the potential of {PV₄}²⁻ in heterogeneous photocatalysis
Su, Xin; He, Yuzan; Li, Kunhong; Wang, Miao; Tang, Wei; Zhang, Shihao; Ma, Pengtao; Niu, Jingyang; Wang, Jingping
A 3D-printed pre-filter with a crystal violet-gold nanocluster hybrid for a reusable visible-light-activated antimicrobial air filtration system
Shin, Jae Hak; Kim, So Yeong; Kang, Hyun Sung; Kim, In Ho; Park, Joon Young; Heo, Ki Joon; Hwang, Gi Byoung; Jung, Jae Hee
Sulfur-induced structural and electronic engineering of Ru nanoclusters for highly efficient hydrogen evolution
Li, Xinyu; Li, Jing; Yin, Jingwen; Zhou, Guangyao; Chen, Lei; Xu, Lin; Tang, Yawen
Cobalt-promoted Zn encapsulation within silicalite-1 for oxidative propane dehydrogenation with CO₂ by microwave catalysis at low temperature
Nie, Fangui; Sun, Hongyang; Li, Tianyi; You, Zhimin; Zhou, Jicheng; Xu, Wentao
Self-assembly of a high-nuclearity fullerene-like heteropolyoxometalate cage
Wu, Shuangxue; Sun, Chunyi; Wang, Xinlong; Shao, Kuizhan; Qin, Chao; Su, Zhongmin
