Hot Article: Tuning from blue to magenta

Nanoscale Hot article, just published

Tuning from blue to magenta the up-converted emissions of YF3:Tm3+/Yb3+ nanocrystals

Marta Quintanilla, Nuria O. Núñez, Eugenio Cantelar, Manuel Ocaña and Fernando Cussó

Nanoscale, 2011, Advance Article, DOI: 10.1039/C0NR00676A

Quintanilla and co-workers synthesise monodisperse YF3:Tm3+/Yb3+ nanocrystals to explore the visible up-converting properties under near infrared (975 nm) excitation. The nanoparticles exhibit intense red up-converted emissions, in addition to the characteristic UV and blue Tm3+-bands. The authors demonstrate that, by carefully selecting Tm3+ and Yb3+ contents, the relative intensity of the different emissions can be changed producing an overall emission colour that can be tuned from blue to magenta.

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International Conference on Nanoscience and Technology

International Conference on Nanoscience and Technology

ChinaNANO 2011

September 7-9 2011, Beijing

ChinaNANO 2011 is an international conference intended to stimulate discussions on the forefront of research in nanoscience and nanotechnology. The conference will focus on inorganic nanomaterials and MOFs, carbon nanomaterials, organic and polymeric nanomaterials, nanocomposites and applications, nanodevices and nanosystem, nanobiotechnology and nanomedicine, characterization and standards of nanostructures, nano-optics and plasmonics, as well as modeling and simulation of nanostructures.

Abstract submission deadline: 30 April 2011

Registration deadline: 30 June 2011

For information, please visit the conference website.


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Electro-netting, nano-nets and trimethylamine sensing

Communication, hot off the press

Electro-netting: Fabrication of two-dimensional nano-nets for highly sensitive trimethylamine sensing
Xianfeng Wang, Bin Ding, Jianyong Yu, Yang Si, Shangbin Yang and Gang Sun
Nanoscale, 2011, DOI: 10.1039/C0NR00783H, Communication

A facile electro-netting process is used to prepare 2D polyacrylic acid nano-nets that comprise interlinked ultrathin nanowires with diameters of 10–30 nm. The versatile nano-nets create enhanced interconnectivity and additional surface area and facilitate the diffusion of analytes into the membranes, which significantly boost the gas diffusion coefficient and sensing properties.

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Top Ten most-read Nanoscale articles in October

The latest top ten most accessed Nanoscale articles

See the most-read papers of October 2010 here:

Rubén Mas-Ballesté, Cristina Gómez-Navarro, Julio Gómez-Herrero and Félix Zamora, Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00323A
 
Benjamin Weintraub, Zhengzhi Zhou, Yinhua Li and Yulin Deng, Nanoscale, 2010, 2, 1573-1587
DOI: 10.1039/C0NR00047G
 
M. B. Avinash, K. S. Subrahmanyam, Y. Sundarayya and T. Govindaraju, Nanoscale, 2010, 2, 1762-1766
DOI: 10.1039/C0NR00024H
 
Wolfgang Schärtl, Nanoscale, 2010, 2, 829-843
DOI: 10.1039/C0NR00028K
 
Wufeng Chen and Lifeng Yan, Nanoscale, 2010, 2, 559-563
DOI: 10.1039/B9NR00191C
 
Poulomi Roy, Doohun Kim, Kiyoung Lee, Erdmann Spiecker and Patrik Schmuki, Nanoscale, 2010, 2, 45-59
DOI: 10.1039/B9NR00131J
 
Yugang Sun, Nanoscale, 2010, 2, 1626-1642
DOI: 10.1039/C0NR00258E
 
Idalia Bilecka and Markus Niederberger, Nanoscale, 2010, 2, 1358-1374
DOI: 10.1039/B9NR00377K
 
Hualan Wang, Qingli Hao, Xujie Yang, Lude Lu and Xin Wang, Nanoscale, 2010, Advance Article
DOI: 10.1039/C0NR00224K
 
Yinxi Huang, Xiaochen Dong, Yumeng Shi, Chang Ming Li, Lain-Jong Li and Peng Chen, Nanoscale, 2010, 2, 1485-1488
DOI: 10.1039/C0NR00142B
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Structure and photoelectrochemistry of a virus capsid–TiO2 nanocomposite

Hot Article, out now

Pair distribution function (PDF) analysis from total X-ray scattering has been used to determine the structure of TiO2 nanoparticles grown within an icosahedral virus capsid. The protein–TiO2 composites are similar to nanocrystalline anatase and show photocatalytic activity. PDF analysis is ideally suited to the study of protein–inorganic nanocomposites, and may be able to provide information about the hard/soft interface. Read the whole article now



Structure and photoelectrochemistry of a virus capsid–TiO2 nanocomposite

Craig Jolley, Michael Klem, Richard Harrington, John Parise and Trevor Douglas
Nanoscale, 2011, DOI: 10.1039/C0NR00378F


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Hot: Biodegradation of carbon nanotubes

Hot communication:


Oxidative biodegradation of single- and multi-walled carbon nanotubes

Julie Russier, Cécilia Ménard-Moyon, Enrica Venturelli, Edmond Gravel, Gabriele Marcolongo, Moreno Meneghetti, Eric Doris and Alberto Bianco

Nanoscale, 2011, DOI: 10.1039/C0NR00779J


In this study, the authors compare the biodegradation of SWCNTs and MWCNTs using two different oxidative conditions. They demostrate  that treating oxidized multi-walled carbon nanotubes with horseradish peroxidase in the presence of hydrogen peroxide, degrades the MWCNT almost to completeness.

With an increasing industrial production and presence of CNTs, the exploration of their biodegradation is of fundamental importance, especially for biomedical applications.

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Biomineralisation: Crystalline Calcium Carbonate

Tooth and claw

Biological structures such as teeth and bone are produced by a process called biomineralisation. The shape and structure of biominerals are controlled in an extremely precise way, from the nanoscale right up to the macroscopic level. The spontaneous formation of a tooth, claw, spine or shell is a truly amazing piece of chemistry, and unlocking the secrets of this could prove vital for materials scientists in their quest to engineer ever more complex nanostructures.

Biomineralisation of calcium carbonate

In  Nanoscale, we have recently published some papers on the formation of crystalline calcium carbonate (calcite) by biomineralisation. Yang et al., in their paper entitled ‘Biomineral nanoparticles are space filling’, present a study of biomineralisation in sea urchins, which contain spicules, spines and teeth (pictured left) all composed of calcium carbonate. They discuss the formation of crystalline biominerals through amorphous precursors, where one can imagine hydrated amorphous calcium carbonate nanoparticulate building blocks being able to flow and morph into the intricate shape of the final biomineral, followed by a period of dehydration and crystallization which forms the solid product. This process of dehydration and crystallization is discussed further by Rodriguez-Blanco et al., who used time-resolved X-ray diffraction in order to study the changes in crystal structure which occur when amorphous calcium carbonate crystallizes. They discovered that, under certain conditions, crystallization from the amorphous form to calcite occurs via another crystalline form, known as vaterite.

In November’s themed issue of Nanoscale, entitled Crystallization and Formation Mechanisms of Nanostructures, we published some other work on calcium biominarlisation, including studies of the formation and stability of amorphous calcium carbonate by Jiang et al. and Sommerdijk et al., and of calcium phosphate crystals by Mann et al., Taubert et al., Zhai et al., and Ibsen and Birkedal, which discussed the use of structure directing agents and organic additives to control crystal growth and morphology.

Papers like these are prime examples of how the study of natural processes can provide vital insight into the synthetic mechanisms which scientists are developing to produce new nanomaterials.

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Advances in Semiconductor Nanowires Research

Nanoscale is delighted to be collaborating with the International Conference on Materials for Advanced Technologies (ICMAT 2011) and will be publishing a collection of papers resulting from the high-quality research presented at the meeting on ‘Advances in Semiconductor Nanowires Research’.

Abstract submission deadline for ICMAT 2011: 15 January 2011

Deadline for submissions to the Nanoscale issue: 1 August 2011

Please indicate upon submission that your paper is from this conference. All articles will be subject to rigorous peer-review according to the journal’s usual standards.

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Hot article: DNA hybridization quantitative sensing

Hot Article – out now

Read about how the application of a combined approach of evanescent nanometry and force spectroscopy using magnetic tweezers helps quantify the degree of hybridization of a single synthetic single-stranded DNA oligomer to a resolution approaching a single-base.

Quantitative high-resolution sensing of DNA hybridization using magnetic tweezers with evanescent illumination
Piercen M. Oliver, Jin Seon Park and Dmitri Vezenov
Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00479K

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Taking inspiration from the origin of life

On the origin of life

Professor Tony Ryan of the University of Sheffield visited the Royal Society of Chemistry in London to deliver a fascinating talk on Materials Chemistry and the Origin of Life. Professor Ryan described the origin of life in a ‘primordial soup’, fundamentally a mixture of organic building blocks such as sugars, fatty acids, amino acids and nucleotides, created by chemical reactions between methane, water, carbon dioxide and hydrogen cyanide (so the theory goes).

Watch the lecture now online: Materials Chemistry and the Origin of Life

Although it is not altogether clear how, from this soup sprung life, starting off as simple cells and eventually evolving into life as we know it today. Unimaginably complex molecules, structures, cells and organisms self-assemble from a simple list of ingredients, and give rise to the complex flora and fauna that is life on Earth. Professor Ryan went on to describe cell biology as ‘nanotechnology that works’, and indeed the internal workings of a cell are as a complex ‘nanosystem’ as we could ever hope to construct. He also discussed how, in his work, he has taken inspiration from the chemical basis of the ‘origin of life’, and used it directly in his materials chemistry research, a field which he refers to as ‘Soft Nanotechnology’.

From the bottom up

Current research in nanotechnology is striving towards heightened control and understanding of how to assemble complex and useful nanostructures. Just like the complex structures of living organisms self-assemble, we desire to be able to induce assembly of intricately designed and functional nanomaterials. In the decades since ‘bottom-up’ nanoparticle synthesis was pioneered, much attention has turned to the growth of anisotropic nanostructures. There has been a plethora of such structures reported in the literature, including tetrapods, wires, stars, nets and cages, amongst many others.

This month’s issue of Nanoscale, entitled ‘Crystallization and Formation Mechanisms of Nanostructures’, is a themed collection of papers which explore the various developments in solution-based crystal nucleation and growth mechanisms. In their editorial piece, Fiona Meldrum (University of Leeds, UK) and Helmut Cölfen (University of Konstanz, Germany) describe the synthesis of crystalline nanomaterials with well-defined sizes, morphologies and hierarchical structures as “one of the grand challenges of nanoscience and nanotechnology today”, but qualify this statement by explaining that “understanding of how these structures develop remains poor”. However, the works collected in this themed issue represent the state-of-the-art in our understanding of this field, and clearly illustrate that significant progress is being made in this fascinating, and fundamentally important, branch of science.

Meldrum and Cölfen go on to say that “it is also valuable to draw parallels between synthetic crystals, and their formation mechanisms, and crystals precipitated under biological control, namely biomaterials such as bones, teeth and seashells”. Again, inspiration can be taken from the complexity and beauty of these natural structures and used to shed further light on our studies in nanomaterial synthesis. The best efforts of synthetic chemists to control the growth, size and shape of nanomaterials pale in comparison with what occurs naturally in all living organisms. However, as we can presume we have only scratched the surface of possibilities here, one can anticipate that there remain many exciting discoveries and developments in this field of research.

Read the Nanoscale themed issue today for free: ‘Crystallization and Formation Mechanisms of Nanostructures

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