New use for graphene sounds great

Recently knighted Sirs Andre Geim and Konstantin Novoselov must feel a bit like The Beatles. Not because they have legions of adoring screaming fans (well, they might, but science isn’t as sexy as rock music), but because you could probably draw parallels between the influences of the Liverpudlian quartet on music and the isolation of graphene on materials science.

Graphenemania doesn’t seem to be abating any time soon either. The latest episode of this incredible craze sees Tian-Ling Ren and his team at Tsinghua University in Beijing taking advantage of single-layer graphene’s (SLG) very low heat capacity per unit area (one of its many remarkable properties) to use it as a sound-emitting material.

Device structure of the grapene "speaker".

The researchers created a device using electrodes deposited onto two ends of a sheet of SLG, which itself is placed on an anodic aluminium oxide substrate. When an electric sound-frequency signal is applied to the graphene, sound is produced through the thermoacoustic effect. In short, when electricity passes through the graphene, the heat produced is transferred to the air around the device surface. The fluctuations in this heat as the current itself fluctuates causes the air to vibrate, producing sound.

Although a previous piece of work has already used graphene in a thin and transparent sound-emitting device, it was merely used as electrodes. Significantly, this is the first time that the material has been demonstrated to actually be able to produce sound itself.

The team found that SLG has a sound pressure level of about 95 dB, which puts it on a par with that experienced when standing a metre from a disco speaker. This makes it ideal for uses such as speakers and earphones, perfect for science’s own ‘Fab Two’ to use to listen to Sergeant Pepper’s Lonely Hearts Club Band.

Read more about this ‘rocking’ new application for graphene here.

Single-layer graphene sound-emitting devices: experiments and modeling
He Tian, Dan Xie, Yi Yang, Tian-Ling Ren, Yu-Feng Wang, Chang-Jian Zhou, Ping-Gang Peng, Li-Gang Wang and Li-Tian Liu
Nanoscale, 2012, DOI: 10.1039/C2NR11572G

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Call for papers: Metallic clusters themed issue

Nanoscale themed issue: Metallic Clusters

Guest Editors: Rongchao Jin (Carnegie Mellon University), Sang-Kee Eah (Rensselaer Polytechnic Institute), Yong Pei (Xiangtan University, China)

We are delighted to announce a high-profile themed issue on “Metallic Clusters”, to be published in the exciting new high-impact journal Nanoscale in 2012. We invite you to contribute to this themed issue.

The aim of this issue is to address the fascinating field and recent discoveries in metallic nanoclusters. The themed issue will include high quality articles on metal nanocluster synthesis, properties (experimental and theoretical work), and applications.

Deadline for Submission: 29th February 2012

  • Submissions for the themed issue should be high quality manuscripts of original, unpublished research.
  • Both Communications and Full Papers can be submitted for consideration.
  • All submissions to the journal are subject to rigorous, fair peer review against our usual very high standards, and if accepted for publication will benefit from high exposure.
  • Manuscripts for this Nanoscale themed issue can be submitted in any reasonable format via our website. Please indicate upon submission that your manuscript is intended for this themed issue.

It is anticipated that the themed issue will be published in June 2012. Accepted papers will be published online as soon as they are ready, to avoid any delay.follow us on twitter

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Nanoscale Issue 2 of 2012 out now!

The latest issue of Nanoscale is now online. You can read the full issue here:




The outside front cover features an article on High-throughput ultrasensitive characterization of chemical, structural and plasmonic properties of EBL-fabricated single silver nanoparticles by Tao Huang, Wei Cao, Hani E. Elsayed-Ali and Xiao-Hong Nancy Xu .






Atomically thin layers of MoS2 via a two step thermal evaporation–exfoliation method is the article highlighted on the inside front cover by Sivacarendran Balendhran, Jian Zhen Ou, Madhu Bhaskaran, Sharath Sriram, Samuel Ippolito, Zoran Vasic, Eugene Kats, Suresh Bhargava, Serge Zhuiykov and Kourosh Kalantar-zadeh.



Issue 2 contains the following high-profile Reviews and Feature Articles:

Fancy submitting an article to Nanoscale? Then why not submit to us today!

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Cleaning cadmium from blood: Nanoscale article featured in Chemistry World

With the development of modern industries, heavy metal pollution in humans is on the rise, say researchers in China, who have now designed a supermagnetic nanocomposite to effectively remove one of the pollutants – cadmium ions – from blood.

Removal of cadmium ions from a human blood sample with a magnet

The nanocomposite binds to cadmium ions in the blood and a magnet is used to attract the resulting complex for removal

Cadmium ions damage organs and are carcinogenic. Materials currently being studied to clear them from human blood don’t possess all the required properties for this purpose.

They either have good selectivity, high saturation magnetisation or good water dispersibility, but not all three. The new composite, made by Jun Jin and Jiantai Ma from Lanzhou University and colleagues, combines all of these properties.

The team built up the nanocomposite – PAD-PEG-Fe3O4@PEI – from four components. The first was magnetic iron oxide nanoparticles, chosen for their low toxicity. The team coated them with polyethylenimine (PEI), which binds to cadmium ions. The coating also reduces the chances of nanoparticle uptake by red blood cells, maximising their circulation time in the blood. Polyethylene glycol (PEG) was grafted onto this as an anchor for negatively charged 2,2′-(phenylazanediyl) diacetic acid (PAD), which counteracts interactions between the nanoparticles and plasma proteins or white blood cells.

Interested to know more? Read the full article in Chemistry World here…

 Read the paper from Nanoscale:

2, 2′-(phenylazanediyl) diacetic acid modified Fe3O4@PEI for selective removal of cadmium ions from blood
Jun Jin, Fang Yang, Fengwei Zhang, Wuquan Hu, Shao-bo Sun and Jiantai Ma
Nanoscale, 2012, Advance Article
DOI: 10.1039/C2NR11481J

Fancy submitting an article to Nanoscale? Then why not submit to us today!

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Exciting graphene research in Nanoscale

journal cover imageWe would like to share with you some of the latest exciting research on graphene published in Nanoscale.

You can browse our recent reviews listed below, or read some high impact graphene research papers in our themed collection on graphene.

Nanoscale publishes community-spanning research across the fields of nanoscience and nanotechnology. The journal will get its first full Impact Factor in June 2012 and it’s expected to be very high.

On behalf of the Editors-in-Chief Chunli Bai (NCNST, Beijing), Jie Liu (Duke), Wei Lu (Michigan), Markus Niederberger (ETH Zurich), and Francesco Stellacci (EPFL), we invite you to submit your research today.

Graphene: nanoscale processing and recent applications
László P. Biró, Péter Nemes-Incze and Philippe Lambin
DOI: 10.1039/C1NR11067E

Excitonic properties of graphene-based materials
Min Wang and Chang Ming Li
DOI: 10.1039/C1NR10885A

Inorganic nanostructures grown on graphene layers
Won Il Park, Chul-Ho Lee, Jung Min Lee, Nam-Jung Kim and Gyu-Chul Yi
DOI: 10.1039/C1NR10370A

Graphene edges: a review of their fabrication and characterization
Xiaoting Jia, Jessica Campos-Delgado, Mauricio Terrones, Vincent Meunier and Mildred S. Dresselhaus
DOI: 10.1039/C0NR00600A

2D materials: to graphene and beyond
Rubén Mas-Ballesté, Cristina Gómez-Navarro, Julio Gómez-Herrero and Félix Zamora
DOI: 10.1039/C0NR00323A

Effect of N/B doping on the electronic and field emission properties for carbon nanotubes, carbon nanocones, and graphene nanoribbons
Shan-Sheng Yu and Wei-Tao Zheng
DOI: 10.1039/C0NR00002G

Cu2ZnSnS4 nanocrystals and graphene quantum dots for photovoltaics
Jun Wang, Xukai Xin and Zhiqun Lin
DOI: 10.1039/C1NR10425J

Low-toxic and safe nanomaterials by surface-chemical design, carbon nanotubes, fullerenes, metallofullerenes, and graphenes
Liang Yan, Feng Zhao, Shoujian Li, Zhongbo Hu and Yuliang Zhao
DOI: 10.1039/C0NR00647E

Making silica nanoparticle-covered graphene oxide nanohybrids as general building blocks for large-area superhydrophilic coatings
Liang Kou and Chao Gao
DOI: 10.1039/C0NR00609B

Liquid-phase exfoliation, functionalization and applications of graphene
Xu Cui, Chenzhen Zhang, Rui Hao and Yanglong Hou
DOI: 10.1039/C1NR10127G

Why not check out Issue 1 of Nanoscale in 2012 today.

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Controlling termites with nanoparticles: Nanoscale article featured in Chemistry World

Scientists in Australia have found that mesoporous silica nanoparticles (MSNs) can store and deliver biocides in a controlled fashion over time, which could be beneficial to the timber industry with regards to termites.

C2NR11691J

Termites pose a significant threat to the industry throughout the tropics and subtropics. The conventional solution to this problem is to use agrochemical biocides such as dichloro-diphenyl-trichloroethane (DDT), aldrin, dieldrin, chlordane and heptachlor.

But these compounds cause environmental damage via bioaccumulation, threatening the existence of some species, particularly large predators at the top of the food chain. And attempts to destroy entire terminte colonies using them have been unsucessful. 

Now, Zhang Qiao and colleagues at the University of Queensland, have used the pore structure of mesoporous silica nanoparticles to adsorb biocides. They found that the nanoparticles released the biocide in a controlled manner. This slow release is important as the termintes will feed on and transfer the particles to other termites, eventually leading to colony destruction. 

The team chose four different types of MSN to test, using the agricultural biocide imidacloprid as a model. They found that MCM-48 particles had the highest adsorption capacity. ‘We can effectively load the biocide into MSNs and release it over 48 hours,’ says Qiao. ‘However, it is difficult to control the release because of the biocide’s water solubility and fast mass transport.’ 

Andrea O’Connor, an expert in nano and biomolecular engineering at the University of Melbourne, Australia, agrees that more control over release rates is needed. This would ‘minimise the early burst release and extend biocide delivery over biologically relevant time periods and dose rates’, she says. However, she adds that the system is simple and delivers the nanoparticles in a suspension into the site of an infestation ‘rather than relying on diffusion of released biocide through the environment, where it may be degraded or have undesirable adverse effects.’ 

Qiao adds that to effectively deliver the biocide over a period of about seven days, the MSNs need to be coated with other chemicals. The team is investigating a biodegradable polymer coating. 

Carl Saxton – Chemistry World 

Read the paper from Nanoscale: 

Adsorption and release of biocides with mesoporous silica nanoparticles
Amirali Popat, Jian Liu, Qiuhong Hu, Michael Kennedy, Brenton Peters, Gao Qing (Max) Lu and Shi Zhang Qiao
Nanoscale, 2012, Advance Article
DOI: 10.1039/C2NR11691J 

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Nanoscience: Removing cadmium from blood

Researchers at Lanzhou University, China, have designed a nanocomposite to effectively remove cadmium ions from human blood.

Previous materials designed for this purpose have either had good selectivity, high saturation magnetisation or good water dispersibility, but the new material has all three properties. And, the composite is highly supermagnetic, making subsequent removal of the nanoparticles easier.

Removing cadmium (which is produced during industrial processes) from the blood is important because they bind to proteins in the body, affecting their functions.

The nanocomposite consists of four components; The first is magnetic iron oxide nanoparticles, chosen for their low toxicity. They are coated with polyethylenimine to increase the amino groups on the particles’ surface to bind Cd2+, but also to lower nanoparticle uptake by red blood cells, maximising the circulation time of the composites in the blood. Polyethylene glycol is grafted onto this as an anchor for negatively charged 2,2’-phenylazanediyl, which counteracts the hydrophobic and electrostatic interactions between the nanoparticles and plasma proteins or white blood cells.

Read the Nanoscale article now:

2, 2′-(phenylazanediyl) diacetic acid modified Fe3O4@PEI for selective removal of cadmium ions from blood
Jun Jin, Fang Yang, Fengwei Zhang, Wuquan Hu, Shao-bo Sun and Jiantai Ma
Nanoscale, 2012
DOI: 10.1039/c2nr11481j

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Top Ten most-read Nanoscale articles in November

This month sees the following articles in Nanoscale that are in the top ten most accessed for November:

Multifunctional composite core-shell nanoparticles 
Suying Wei, Qiang Wang, Jiahua Zhu, Luyi Sun, Hongfei Lin and Zhanhu Guo 
Nanoscale, 2011, 3, 4474-4502 
DOI: 10.1039/C1NR11000D 

Gold nanoparticles: preparation, properties, and applications in bionanotechnology
 
Yi-Cheun Yeh, Brian Creran and Vincent M. Rotello 
Nanoscale, 2012, Advance Article 
DOI: 10.1039/C1NR11188D 

Nano active materials for lithium-ion batteries 
Yonggang Wang, Huiqiao Li, Ping He, Eiji Hosono and Haoshen Zhou 
Nanoscale, 2010, 2, 1294-1305 
DOI: 10.1039/C0NR00068J 

Graphene edges: a review of their fabrication and characterization 
Xiaoting Jia, Jessica Campos-Delgado, Mauricio Terrones, Vincent Meunier and Mildred S. Dresselhaus 
Nanoscale, 2011, 3, 86-95 
DOI: 10.1039/C0NR00600A

3D-patterned polymer brush surfaces 
Xuechang Zhou, Xuqing Liu, Zhuang Xie and Zijian Zheng 
Nanoscale, 2011, 3, 4929-4939 
DOI: 10.1039/C1NR11238D 

The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices 
Xin Zhao, Beatriz Mendoza Sánchez, Peter J. Dobson and Patrick S. Grant 
Nanoscale, 2011, 3, 839-855 
DOI: 10.1039/C0NR00594K 

Highly dispersed Fe3O4 nanosheets on one-dimensional carbon nanofibers: Synthesis, formation mechanism, and electrochemical performance as supercapacitor electrode materials 
Jingbo Mu, Bin Chen, Zengcai Guo, Mingyi Zhang, Zhenyi Zhang, Peng Zhang, Changlu Shao and Yichun Liu 
Nanoscale, 2011, 3, 5034-5040 
DOI: 10.1039/C1NR10972C 

Li ion battery materials with core?shell nanostructures 
Liwei Su, Yu Jing and Zhen Zhou 
Nanoscale, 2011, 3, 3967-3983 
DOI: 10.1039/C1NR10550G 

Graphene: nanoscale processing and recent applications
 
László P. Biró, Péter Nemes-Incze and Philippe Lambin 
Nanoscale, 2012, Advance Article 
DOI: 10.1039/C1NR11067E 

2D materials: to graphene and beyond 
Rubén Mas-Ballesté, Cristina Gómez-Navarro, Julio Gómez-Herrero and Félix Zamora 
Nanoscale, 2011, 3, 20-30 
DOI: 10.1039/C0NR00323A 

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Nanoscale? Then why not submit to us today!

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Nanoparticles detect food poisoning bug

imageHOT Nanoscale Communication

Scientists in China have developed a sensitive method for detecting the bacteria Staphylococcus aureus which is a major cause of food poisoning as well as community- and hospital-acquired infections.

The researchers functionalized gold nanoparticles with phenylboronic acid which could react with the cis-diol groups found on the bacteria’s surface, causing a detectable colour change.

Using this method they could detect the bacteria down to a concentration of 50 cells per mL.

Read the full exciting Nanoscale communication now:

Phenylboronic acid functionalized gold nanoparticles for highly sensitive detection of Staphylococcus aureus
Jine Wang, Jingqing Gao, Dianjun Liu, Dongxue Han and Zhenxin Wang
DOI: 10.1039/C2NR11657J

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Bionanotechnology conference: register today

NanoscaleBionanotechnology III: from biomolecular assembly to applications
4—6 January 2012
Robinson College, Cambridge, UK

Nanoscale is delighted to be supporting this conference organised by the Biochemical Society.

This meeting, the third in the series, brings together an international set of speakers who will discuss a broad range of topics in bionanotechnology from different perspectives and with different technical approaches.

Topics:

  • Large natural and designed assemblies
  • Single-molecule studies
  • Nanomaterials and devices in vitro
  • Nanomaterials and devices in vivo
  • Biomolecular self-assembly

Registration is now open.

For more information see the Biochemical Society website.

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