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ISI “fast-breaking” papers in Nanoscale and Energy & Environmental Science!

Articles from both Nanoscale and Energy & Environmental Science are listed as Thomson Reuters ISI fast-breaking papers this month.

Each month, ScienceWatch tracks which papers are ‘Fast Breaking’, i.e. have the highest percentage increase in citations, and for April both Nanoscale and Energy & Environmental Science papers are top in the Chemistry and Environmental fields, respectively.

Surprisingly, both papers are also by the same author, Frederik Krebs – so our congralutions go out to Professor Krebs!

April’s ISI fast-breaking papers

Field: Chemistry

Upscaling of polymer solar cell fabrication using full roll-to-roll processing
Frederik C. Krebs, Thomas Tromholt and Mikkel Jørgensen
Nanoscale, 2010, 2, 873-886

Field: Environment/Ecology

Manufacture, integration and demonstration of polymer solar cells in a lamp for the “Lighting Africa” initiative

Frederik C. Krebs, Torben D. Nielsen, Jan Fyenbo, Mads Wadstrøm and Marie S. Pedersen
Energy Environ. Sci., 2010, 3, 512-525

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Silver nanoplates made on commercially available copper foil

Nanoscale ‘HOT’ Communicationread it today!

Silver nanoplates on commercial copper foil were prepared by a reproducible and cost-effective wet chemical method and those can be used as a reliable surface-enhanced Raman spectroscopy substrate.

silver nanoplates

Silver nanoplates prepared by modified galvanic displacement for surface-enhanced Raman spectroscopy
Yongchao Lai, Wenxiao Pan, Dongju Zhang and Jinhua Zhan
Nanoscale, 2011, DOI: 10.1039/C0NR01030H

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Top Ten most-read Nanoscale articles in February

The latest top ten most accessed Nanoscale articles

See the most-read papers of February 2011 here:

Karla K. Cotí, Matthew E. Belowich, Monty Liong, Michael W. Ambrogio, Yuen A. Lau, Hussam A. Khatib, Jeffrey I. Zink, Niveen M. Khashab and J. Fraser Stoddart, Nanoscale, 2009, 1, 16-39
DOI: 10.1039/B9NR00162J
 
Junyan Xiao and Limin Qi, Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00814A
 
Yi Zhang, Biao Chen, Liming Zhang, Jie Huang, Fenghua Chen, Zupei Yang, Jianlin Yao and Zhijun Zhang, Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00776E
 
Hualan Wang, Qingli Hao, Xujie Yang, Lude Lu and Xin Wang, Nanoscale, 2010, 2, 2164-2170
DOI: 10.1039/C0NR00224K
 
Xiaoliang Fang, Cheng Chen, Zhaohui Liu, Pengxin Liu and Nanfeng Zheng, Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00893A
 
Wolfgang Schärtl, Nanoscale, 2010, 2, 829-843
DOI: 10.1039/C0NR00028K
 
Ping Wang, Yueming Zhai, Dejun Wang and Shaojun Dong, Nanoscale, 2011, Advance Article
DOI: 10.1039/C0NR00714E
 
Nicole M. Schaeublin, Laura K. Braydich-Stolle, Amanda M. Schrand, John M. Miller, Jim Hutchison, John J. Schlager and Saber M. Hussain, Nanoscale, 2011, 3, 410-420
DOI: 10.1039/C0NR00478B
 
Idalia Bilecka and Markus Niederberger, Nanoscale, 2010, 2, 1358-1374
DOI: 10.1039/B9NR00377K
  
Fabio Variola, John B. Brunski, Giovanna Orsini, Paulo Tambasco de Oliveira, Rima Wazen and Antonio Nanci, Nanoscale, 2011, 3, 335-353
DOI: 10.1039/C0NR00485E
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Nanoscale Issue 3 Highlights

outside coverIssue 3 of Nanoscale is now out and we’d like to share some of the highlights with you…

The front cover features the work of Nguyen T. K. Thanh and colleagues on magnetic CoPt nanoparticles as MRI contrast agents for the detection transplanted neural stem cells. The inside front cover highlights the sonochemical formation of metal sponges by Daria V. Andreeva and co-workers.

Review
Pitfalls in the characterization of nanoporous and nanosized materials

Claudia Weidenthaler
Nanoscale, 2011, 3, 792

inside coverFeature article
Multi-scale theoretical investigation of hydrogen storage in covalent organic frameworks

Emmanuel Tylianakis, Emmanouel Klontzas and George E. Froudakis
Nanoscale, 2011, 3, 856

Communication
An enzyme-sensitive probe for photoacoustic imaging and fluorescence detection of protease activity

Xiaohu Xia, Miaoxin Yang, L. Kyle Oetjen, Yu Zhang, Qingge Li, Jingyi Chen and Younan Xia
Nanoscale, 2011, 3, 950

HOT paper
Tuning from blue to magenta the up-converted emissions of YF3:Tm3 /Yb3 nanocrystals

Marta Quintanilla, Nuria O. Núñez, Eugenio Cantelar, Manuel Ocaña and Fernando Cussó
Nanoscale, 2011, 3, 1046

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Hot article – Giving cancer the brush off

A molecular brush based on conjugated polyelectrolyte (CPE) grafted with dense poly(ethylene glycol) (PEG) chains was successfully complexed with an anticancer agent, cisplatin, to form cisplatin-loaded nanoparticles (CPE-PEG-Pt), say scientists from Singapore and China.

The nanoparticles have high far-red/near-infrared fluorescence and are able to release the drug in a continuous and slow manner.

Read this exciting Nanoscale article today – hot off the press!

Reference
D Ding et al, Nanoscale, 2011, DOI: 10.1039/c0nr00950d

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Nanoscale junctions for next generation memory

From stochastic single atomic switch to nanoscale resistive memory device

Attila Geresdi, András Halbritter, András Gyenis, Péter Makk and György Mihály

Nanoscale, 2011, DOI:10.1039/C0NR00951B

Scientists from Hungary have published some important work in Nanoscale regarding the use of solid state ionic conductors as atomic-sized junctions in non-volatile computer memory devices. By varying the size of the junctions from single-atom-sized to 10 nm, the group concluded that there is a lower size limit of 3 nm for reliable ionic nano-switches, a size which is well below the resolution of recent lithographic techniques.

In this work, Garesdi et al. created the junctions by gently touching a silver thin film with an electrochemically sharpened tungsten tip. Exposure of the silver film to air established the ionic conductor surface layer, and the nanoscale ‘point-contact’ geometry was sufficient to form a reliable switching device above the 3 nm threshold. Below this value, the switching process was much less reliable. The storage density here, even with the 3 nm limit, would be higher than current NAND flash devices and similar to the proposed bit size threshold of magnetic media which arises due to the superparamagnetic limit.

The authors provide a detailed analysis of the physical properties of the nano-junctions, as well as an explanation of the underlying mechanisms. They conclude that their ionic conductor-based devices are good candidates for non-volatile memory cells.

To read this article, click here.

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From stochastic single atomic switch to nanoscale resistive memory device

Attila Geresdi, András Halbritter, András Gyenis, Péter Makk and György Mihály

Nanoscale

DOI:10.1039/C0NR00951B

Scientists from Hungary have published some important results in Nanoscale regarding the use of solid state ionic conductors as atomic-sized junctions in non-volatile computer memory devices. By varying the size of the junctions from single-atom-sized to 10 nm, the group concluded that there is a lower size limit of 3 nm for reliable ionic nano-switches, a size which is well below the resolution of recent lithographic techniques.

In this work, Garesdi et al. created these junctions by gently touching a silver thin film with an electrochemically sharpened tungsten tip. Exposure of the silver film to air established the ionic conductor surface layer, and the nanoscale ‘point-contact’ geometry was sufficient to form a reliable switching device above the 3 nm threshold. Below this value, the switching process was much less reliable. The storage density here, even with the 3 nm limit, would be higher than current NAND flash devices and similar to the proposed bit size limit of magnetic media which arises due to the superparamagnetic limit.

The authors provide a detailed analysis of the physical properties of the nano-junctions, as well as an explanation of the underlying mechanisms. They conclude that their ionic conductor-based devices are good candidates for non-volatile memory cells.

To read this article, click here.

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New nanocomposites as strong as bone

Scientists in China have made a synthetic bone material using a new technique for creating polymer nanocomposites incorporated with inorganic nanoparticles.

Yuandong Dou, Kaili Lin and Jiang Chang, Nanoscale, 2011, DOI: 10.1039/C1NR10028A

Fluorescent images of the composite films

Fluorescent images of the composite films

Jiang Chang and colleagues created this material after coming up with a new approach to making the  nanocomposites,  allowing them to control both the spatial distribution and orientational organisation of the nanocomponents, a known limitation of current methods of fabrication.

Their method involves using electrospinning and hot pressing techniques. They firstly homogeneously dispersed the nanoparticles within a polymer matrix solution, which was then electrospun into a patterned “nanofibrous mat” using a specifically designed “collector”. This mat was then placed between two sheets of non-woven polymer nanofibre and hot pressed to create the nanocomposite.

Because bone tissue is, generally speaking, structurally similar to these composites (they involve mineral particles preferentially oriented in a collagen matrix), the researchers tested their new fabrication method by creating an synthetic bone material by incorporating calcium silicate hydrate nanowires into a polyvinyl butyral matrix.  Their artificial material showed remarkable mechanical properties, particularly when compared with the pure polymer (for instance, the bending strength of the researchers’ material reached 188 MPa, as compared to the 86 MPa of the polymer), which also matched those of real cortical bone tissue.

You can find out more about this work by reading the article here.

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New Nanoprobes: Silica capped green fluorescent protein

Encapsulated enhanced green fluorescence protein in silica nanoparticle for cellular imaging

Zhengwei Cai, Zhangmei Ye, Xiaowei Yang, Yanli Chang, Haifang Wang, Yuanfang Liu and Aoneng Cao
Nanoscale DOI:10.1039/C0NR00956C

Scientists in China have developed a simple method of capping green fluorescent protein (GFP) in silica, which is a vital step in improving the versatility of fluorescent proteins for use as imaging probes.

Cai et al. at Shanghai University developed a covalent attachment route, which means the capping precursors are chemically bonded to the protein, rather than just providing passive encapsulation. The silica shell is then grown from the precursor layer to provide a solid and stable shell. A simple reverse emulsion method was used, and the group achieved a very high encapsulation efficiency and high protein loading. Their characterisation results suggest that encapsulating GFP in silica significantly increases its fluorescence and stability as the capping provides an effective barrier from external interference, such as protease attack, denaturants, and excessive heating.

Fluorescent probes are widely used to image biological structures and processes, both in vivo and in vitro. The main concerns in the design of these probes are their optical properties and the way they interact with their environment. For example, you may have a probe which exhibits excellent optical properties, but is toxic and therefore adversely affects the things you are trying to image. Conversely, you could have a probe which is non-toxic, but is unstable and loses its fluorescence too quickly under excitation. Traditional organic dyes suffered from various problems, including a lack of stability, broad emission profiles and toxicity issues. These have gradually been replaced with modern ‘nanoprobes’ which consist of either fluorescent nanoparticles or nanoparticulate coatings for fluorescent molecules. Of all the nanoprobes developed, fluorescent quantum dots exhibit the best optical properties, however, as they generally contain heavy metals such as cadmium, there are toxicity concerns in many applications.

The silica encapsulated fluorescent protein nanoparticles developed in this work may prove to be an exciting new probe which exhibits excellent optical and stability properties whilst avoiding problems such as toxicity and instability,

To read this article, click here.

Nanoscale DOI:10.1039/C0NR00956C

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Nanoscale Editor-in-Chief confirmed as CAS President

Chunli BaiThe Chinese State Council announced yesterday that they have appointed Chunli Bai as the next president of the Chinese Academy of Sciences (CAS).

Professor Bai has been the executive vice president of CAS since 2004, and will take over from former CAS President Lu Yongxiang.

The Nanoscale team would like to congratulate Professor Bai and we wish him all the best in his new role!

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Chickpeas grow taller with carbon nanotubes

Carbon nanotubes can enhance plant growth without damaging plant cells, say scientists from India

Chickpeas grow taller with carbon nanotubes

Sabyasachi Sarkar and colleagues from the Indian Institute of Technology in Kanpur treated chickpea plants with up to 6ug/ml of water soluble carbon nanotubes. They found that the nanotubes increased the growth rate in every part of the plant – in the roots, shoots and branches.

Sarkar thought that the channels could be replicated by carbon nanotubes. ‘We followed Thomas Edison’s recipe to make carbonised filament from bamboo or wood wool in his electric bulb to get the carbon nanotubes,‘ he adds. ‘Of course, we had to derivatise them to make them water soluble.’ The team achieved this by attaching carboxylic acid groups to the surface of the tubes.

The work seems to support the positive effect of carbon nanotubes,’ says Xiaohong Fang, an expert in the use of carbon nanotubes as molecular transporters in plants at the Chinese Academy of Sciences in China. However, she points out that the biological effects on plants may differ depending on the materials’ chemical and physical properties, plant type and cultivation conditions.

Read the rest of the Chemistry World story by Elinor Richards

View the Nanoscale article in full:

Growth stimulation of gram (Cicer arietinum) plant by water soluble carbon nanotubes
Shweta Tripathi, Sumit Kumar Sonkar and Sabyasachi Sarkar
Nanoscale,
2011, DOI: 10.1039/c0nr00722f

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