Titanium falls flat in an eight-membered boron ring
Researchers in China and the US have predicted the first two-dimensional material to contain completely planar octacoordinate transition metal atoms – TiB4. If scientists can make it, the monolayer would contain edge-sharing wheels of eight-membered boron rings with a central titanium atom.
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Two-dimensional TiB4 Monolayer Exhibits Planar Octacoordinate Ti
Xin Qu, Jian Lv, Yanchao Wang, Jinghai Yang, Zhongfang Chen and Yanming Ma
Nanoscale, 2017, Accepted Manuscript
http://dx.doi.org/10.1039/C7NR05688E