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Positioning Metal Organic Frameworks

23 May 2014

Surface functionalization by microcontact printing

Metal organic frameworks (MOFs) are remarkable materials which have great potential for different applications where an accessible surface area is a critical feature. However, the ability to control the position of MOFs is also crucial for their use in many devices. Paolo Falcaro et al from the CSIRO, Australia present a review on the current technologies that enable precise positioning of MOFs onto different platforms.

To access the full review for free* click the link below:

MOF positioning technology and device fabrication
Paolo Falcaro, Raffaele Ricco, Cara M. Doherty, Kang Liang, Anita J. Hill and Mark J. Styles
DOI: 10.1039/C4CS00089G

Similar reviews can be found in our metal organic frameworks themed collection.

*Access is free until 20^th June through a registered RSC account – click here to register

Not only does this review demonstrate examples of devices in which the control of MOF position and functionalization will play a major technological role, but the authors have also provided video material clearly demonstrating the various techniques. The growth of MOFs can be controlled on different substrate with the intention of providing protocols suitable for MOF-based device fabrication. Watch the video’s for demonstrations of each technique. The full collection of videos can be viewed on our related content page.

Gel-Layer approach

Electrochemical method proposed by Ameloot et al

The formation of crystals within confined columns

Patterns produced by direct conversion from zinc oxide precursor films

Inkjet printing

Spray coating

Photolithography technique

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The ins and outs of enzyme immobilisation: a Tutorial Review

14 May 2013

Great attention is focused on the burgeoning role of biocatalysis in industrial processes. Enzymes offer a mild, efficient and “green” process that can save money, conserve energy and cut down on waste compared to conventional chemistry. However, despite their advantages, the implementation of enzymatic processes in industry suffers from a number of limitations. Enzymes are often unstable to the industrial or storage conditions, and can be difficult to recover and re-use.

Enzyme immobilisation is one way to combat these drawbacks. In addition to facilitating the storage, recovery and re-use of an enzyme, immobilisation also affords the more convenient handling of the enzyme as well as reducing its toxicity in cases. As part of Chem Soc Rev‘s upcoming ‘Enzyme Immobilisation’ themed issue, Professor Roger A. Sheldon and Dr. Sander van Pelt of Delft University of Technology have produced a Tutorial Review shedding light on the role of this key application in biocatalysis.

Enzyme Immobilization: Why, What and How | Roger A. Sheldon

The Tutorial Review – which is accompanied by additional PDF slides in the electronic supplementary information (ESI) – highlights a number of key learning points, including the advantages and limitations of the various approaches to enzyme immobilisation. The types of immobilisation are discussed in detail, from binding to a carrier, to entrapment and cross-linking, including cross-linked enzyme aggregates (CLEAs). Helpfully, Sheldon and von Pelt also clarify immobilisation terminology, which is often confusing and inconsistent.

Given the potential of this technology, especially in the chemical industry, it is essential that we gain more insight into the performance and application of immobilised enzymes. This Tutorial Review is a step towards that objective and offers an enlightening overview of this fascinating subject.

For more, read this Chemical Society Reviews article today:

Enzyme immobilisation in biocatalysis: why, what and how
Roger A. Sheldon and Sander van Pelt
Chem. Soc. Rev., 2013, Advance Article
DOI:10.1039/C3CS60075K

Ruth Gilligan is a guest web-writer for Chem Soc Rev. She has recently completed her PhD in the group of Prof. Matthew J. Gaunt at the University of Cambridge, focusing on the development and application of C–H functionalisation methodology.

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Spotting Quantum Mechanics at Work in Biological Systems

22 Feb 2013

Quantum mechanical predictions reduce to those of classical mechanics in the macroscopic world; otherwise absurd situations would result such as Schrödinger’s cat being both dead and alive in the box. But does quantum mechanics play a specific role in the functions of complex biological systems?

An advance in the study of the photosynthetic light-harvesting process demonstrated that the electronic energy transfer might not follow the classical hopping mechanism but involve quantum-coherent energy transfer. This discovery relied on the development of new ultrafast spectroscopic techniques and these form the basis of this Tutorial Review by Elisabetta Collini from the Department of Chemical Sciences at the University of Padova.

a) Hopping and b) quantum coherent energy transfer mechanisms.

The state-of-the-art techniques, and their limitations, for the detection of quantum-coherent energy transfer in light-harvesting complexes are discussed. They include; pump-probe anisotropy, two-time anisotropy decay and 2D photon echo techniques.

Although the review focuses on photosynthetic energy transfer, quantum effects have been posited in other processes including; olfaction, magnetic sensing and even consciousness. The extent to which quantum mechanics affect these processes in physiological conditions has often been seen as a negligible curiosity.

This Tutorial Review explores the techniques, including the debate surrounding their use, for the experimental verification of the role of quantum effects in biological processes. It is therefore a must read for those who wish to experimentally explore quantum mechanical effects in other biological processes.

Related slides on “Energy Transfer in the Weak and Strong Coupling Regimes” are also available as electronic supplementary information (ESI) – these are free to access.

For more, read this Chem Soc Rev article today:

Spectroscopic signatures of quantum-coherent energy transfer

Elisabetta Collini
Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS35444J

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Archive for the ‘Electronic supplementary information’ Category

Positioning Metal Organic Frameworks

The ins and outs of enzyme immobilisation: a Tutorial Review

Spotting Quantum Mechanics at Work in Biological Systems

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