In this hot article the authors describe the synthesis of enantiomerically enriched titanium complexes. The compounds are chiral at the metal center but also chemically rigid towards racemization:
Optically active bis(β-diketonate) complexes of titanium
Natcharee Kongprakaiwoot, Jack B. Armstrong, Bruce C. Noll and Seth N. Brown
Dalton Trans., 2010, Advance Article
DOI: 10.1039/C0DT00828A, Paper
READ NOW! Free to access until the 6th of October.
