In this Catalysis Science & Technology Hot article, a recyclable copper nanopowder catalyst in ionic liquid is used to form a carbon-sulphur bond.
The formation of such bonds is important in organic chemistry, and various transition metal catalysed cross-coupling reactions have been investigated before, however this new method achieves excellent yields, is easily recyclable and easy to use.
This work is part of the authors research into organochalcogen derivatives for biological and asymmetric transformations.
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C–S cross-coupling of thiols with aryl iodides under ligand-free conditions using nano copper oxide as a recyclable catalyst in ionic liquid
Ricardo S. Schwab, Devender Singh, Eduardo E. Alberto, Paulo Piquini, Oscar E. D. Rodrigues and Antonio L. Braga
Catal. Sci. Technol., 2011, DOI: 10.1039/C1CY00091H