Archive for 2012

New HOT articles on by-product formation potentials in wastewater effluents and exposure to benzene in urban and rural areas

The first HOT paper this week comes from Yuefeng Xie and colleagues at The Pennsylvania State University. They investigated the effect that treatment at watewater treatment plants (WWTPs) had on disinfection by-product (DBP) precursors. Eight different WWTPs were studied, and an additional plant that carries out two biological treatment processes was also investigated as a comparative study. The level of DBP precursors was established in the wastewater of each WWTP, and this was then compared to the levels after the processing had occurred. Amongst other results, they found that WWTPs that removed the most organic matter and accomplished better nitrification resulted in lower disinfection by-product formation potentials in the effluent. They state the study can be used by water and wastewater professionals to ‘better control wastewater-derived DBPs in downstream potable water supplies’.

Disinfection by-product formation potentials in wastewater effluents and their reductions in a wastewater treatment plant
Hao L. Tang, Yen-Chih Chen, John M. Regan and Yuefeng F. Xie
DOI: 10.1039/C2EM00015F

The second HOT paper comes from Tomei Gianfranco and co-workers at the University of Rome. They measured blood benzene and two urinary acid levels in traffic policemen, police drivers and roadmen. Benzene exposure was higher for urban workers than the general population and comparable in non-smoker traffic policemen and police drivers, and was increased in (non-smoker) urban workers when compared to rural workers. There was significant correlation in the levels of airborne benzene and blood benzene in non-smoker urban workers.

Environmental and biological monitoring of benzene in traffic policemen, police drivers and rural outdoor male workers
Ciarrocca Manuela, Tomei Francesco, Caciari Tiziana, Capozzella Assunta, Scimitto Lara, Nardone Nadia, Andreozzi Giorgia, Scala Barbara, Fiaschetti Maria, Cetica Carlotta, Di Giorgio Valeria, Schifano Maria Pia, Tomei Gianfranco and Sancini Angela
DOI: 10.1039/C2EM30120B

Both these papers are free to access for 4 weeks following a simple registration for individual users.

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Struggling for acceptance? Top ten tips to get published

Ever wondered what makes a successful submission? A little preparation and some simple changes may make all the difference. Harp Minhas, Editor of the Journal of Environmental Monitoring, shares his top ten tips for getting published:

1. Ensure your work has novelty and advances existing knowledge

  • This is the main criterion for publication in most journals

2. Provide a clear statement of novelty/impact

  • A lack of clarity about the relevance of your work could mean rejection

3. Provide a cover letter

  • The cover letter should include a summary of the work, a novelty statement (with possible implications or applications) and a statement of article type, e.g., review, paper, communication, etc.

4. Read and follow the Guidelines for Authors

  • Ensure your work is appropriate for the journal of your choice, sometimes the Guidelines for Authors are out of date so look at the journal content –  does it match your paper?

5. Perform a thorough literature search

  • References can tell Editors & Reviewers a lot about your knowledge of the field, make sure you have included all the relevant references to previously published works

6. Keep the language simple; short sentences

  • No matter what your native language is, short simple sentences help to maintain clarity and simplicity in explanation

7. Proof read before submission

  • Many small and minor errors are frustrating for reviewers as they read and assess your work, get a friend or colleague to read before submission

8. Write a clear, logical and concise story

  • The relevant sections of the paper should follow in a clear and logical manner, stick to the facts and do not over-claim the novelty/advances

9. On revision, address all the reviewer comments

  • Make sure you address ALL the reviewer comments, both in your responses and within the revised manuscript. It is OK to disagree with reviewers as long as you justify and explain why in your responses

10. If rejected, learn from the experience

  • Try to learn from negative publishing experiences, and try to improve for your next submission accordingly

The above list is not intended to give you all the information you will require to write papers, but may help set you upon the right path and could be helpful as a check list when preparing your work for submission to a journal. Many other factors are also important, for example, reading the Ethical Guidelines is essential if you are presenting experiments that involve animals; as is the declaration of in-press papers, if these are not declared up front, they will inevitably lead to delays in the publication of your work.

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Latest HOT articles on passive water sampling of antibiotics and the recovery of sulfate saturated soils in the Plynlimon catchments

The first HOT article this week comes from Kevin Jones and colleagues at Lancaster University, who have developed a novel passive sampler using diffusive gradients in thin films (DGT) for organics in the aquatic environment. The sampler can measure quantitatively without field calibration.

The team indicate that the sampler could be used to investigate bioavailability and interactions of organic compounds (including pharmaceutical antibiotics) in soils and sediments.

A novel passive water sampler for in situ sampling of antibiotics
Chang-Er Chen, Hao Zhang and Kevin C. Jones
DOI: 10.1039/C2EM30091E

The second HOT article comes from Steven Hughes and colleagues, who investigated the recovery of sulfate saturated soils in the Plynlimon catchments in mid-Wales, following the reduction between the 1980s and 2011 in atmospheric S inputs.

The team investigated sulfate adsorption and desorption isotherms of stagnopodzol, brown podzolic soil, gleyed podzol and stagnohumic gley B-horizon soils from soil samples collected from sites in the Plynlimon catchments in the 1980s. Additionally, samples collected  in 2002 and from 2010 to 2011 from selected sites that were revisited were also analysed for comparison. Some of the soil samples from 2002 were further investigated to study the effects of increasing concentrations of dissolved organic carbon on sulfate adsorption.

Recovery of sulfate saturated soils in the Plynlimon catchments, mid-Wales following reductions in atmospheric S inputs from the 1980s to 2011
Steven Hughes, Brian Reynolds, David A. Norris, Sarah A. Brittain, Ashlee L. Dere, Clive Woods, Linda K. Armstrong, Sarah A. Harman and Heather D. Wickham
DOI: 10.1039/C2EM30070B

Both these papers are free to access for 4 weeks following a simple registration for individual users.

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Have you seen our Environmental Digest? A monthly roundup of the most important environmental research and legislation

At Journal of Environmental Monitoring we are committed to advancing understanding of the issues affecting our environment, and we know that your research is dependent on being up to date on all the developments in this complex field.

So did you know that with every issue we publish a news article written by consultant Mike Sharpe which summarises everything you need to know about the latest environmental legislation, quality control and health issues, research activities and chemical hazards? And, best of all, these articles are FREE to access!*

Here’s a sample of the great content in the latest articles:

Pesticides linked to decline of bees

Pesticides linked to decline of bees

Researchers have raised concern over the affect of low-dose pesticides on bees. Systemic insecticides, a common way to protect crops, can seriously damage the bees’ ability to navigate, scientists say. The new research strongly links the pesticides to the serious decline in honey bee numbers in the US and UK – a drop of around 50% in the last 25 years. The significance of the new work, published in Science, is that it is the first carried out in realistic, open-air conditions. Read more

Nuclear fall predicted as climate warnings growNuclear fall predicted as climate warnings grow

The Fukushima disaster could lead to a 15% fall in world nuclear power generation by 2035, while over the same period power demand could rise by 3.1% a year, according to the International Energy Agency’s 2011 World Energy Outlook. It is the latest of a series of dour predictions on the future of nuclear energy and came amid warnings that global climate indicators continue to move in the wrong direction. Read more

Stroke risk from air pollution ‘rises in hours’Stroke risk from air pollution ‘rises in hours’

Air pollution, even at levels generally considered safe by federal regulations, increases the risk of stroke by 34%, US researchers have found.

Researchers studied more than 1700 stroke patients in the Boston area over a 10-year period. They found exposure to ambient fine particulate matter (PM2.5), generally from vehicle traffic, was associated with a significantly higher risk of ischaemic strokes on days when the EPA’s air quality index for particulate matter was yellow instead of green. Read more

The road to Rio + 20The road to Rio + 20

The countdown to the UN Conference on Sustainable Development (UNCSD) has begun in earnest with the publication of the first draft of the negotiating text to be discussed by governments. The conference, to be held in Rio de Janeiro, Brazil, in June will aim to set a framework for global environmental governance and comes twenty years after the first such conference held in the city in 1992 (hence, the moniker ‘Rio + 20’). Although focusing heavily on the green economy concept, the draft stresses this is merely a means to achieve sustainable development, “which must remain our overarching goal”. Read more

Sign up for our e-alerts to receive an email when issues and news articles are published, you can also keep up with us through the blog RSS and Twitter.

* Articles are free to access through a simple registration process for an RSC Publishing Personal Account.

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Fukushima fallout on this month’s cover

The article on the cover this month is from R. Nelson and colleagues, who have looked at trace levels of radioactivity in air, water, and milk samples in the United States over several weeks following the disaster at the Fukushima Daiichi nuclear power plant in March last year.

The article found that while levels of certain cadmium, technetium and iodide radionucleotides were elevated, these levels were still ‘well below any level of public and environmental concern’. As with all our cover articles, this one is free to access* for 6 weeks:

Radioactive fallout in the United States due to the Fukushima nuclear plant accident
P. Thakur, S. Ballard and R. Nelson
J. Environ. Monit., 2012, DOI: 10.1039/C2EM11011C

Also in this issue is our regular news feature from Mike Sharpe, who this month has news on the direction of the EU’s future environmental policy, new additions to the US EPA National Priorities List of Superfund sites, continued discussions from the nuclear industry, and much, much more.

View the rest of the issue here

*Following a simple registration for individual users

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Latest hot articles on polycyclic aromatic hydrocarbons in sediments from Loch Leven and Gene-TEQ

Two new HOT articles for you this week – the first comes from Lynda Webster and colleagues at Marine Scotland Science and the University of Brighton. They have investigated the fate of polycyclic aromatic hydrocarbons (PAHs) released from an aluminium smelter (from 1907 to 2000) into Loch Leven in Scotland. Using a monitoring programme that ran from 2004 to 2008, they found no evidence of recovery of PAH levels, which they predict may be due to mixing of the sediments in the basins and persistence of the hydrocarbons. In the upper basin of the loch, they found that the levels of all the PAHs investigated (apart from naphthalene) were above the Effects Range Low values, indicating there is a risk of chronic effects to marine life in the loch.

Long-term fate of polycyclic aromatic hydrocarbons (PAH) in sediments from Loch Leven after closure of an aluminium smelter
A. D. McIntosh, R. J. Fryer, L. Webster and A. B. Cundy
DOI: 10.1039/C2EM11006G

The second comes from Christopher Faßbender and colleagues at the University of Heidelberg and RWTH Aachen University. In their paper, they introduce Gene-TEQs – genotoxicity equivalent factors that can be used to directly compare environmental samples from different studies. Three directly acting and three indirectly acting genotoxic compounds were investigated for their cytotoxic and genotoxic concentration-response profiles. One of the tested compounds was selected as the reference compound, and the effects of other substances were calculated as percentages of the maximum reference compound’s effect, allowing relative Gene-TEQs to be provided. The method was also used to compare the effects of sediment samples from the upper Danube River in the same way. The group predict that the Gene-TEQ could also be used for comparing in vitro and in vivo data, increasing our understanding of the bioavailability of pollutants.

Gene-TEQ—a standardized comparative assessment of effects in the comet assay using genotoxicity equivalents
Christopher Faßbender, Thomas Braunbeck and Steffen H. Keiter
DOI: 10.1039/C2EM10947F

Both these papers are free to access for 4 weeks following a simple registration for individual users.

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Top ten most accessed articles in March

This month sees the following articles in the Journal of Environmental Monitoring that are in the top ten most accessed:

Quantitation of persistent organic pollutants adsorbed on plastic debris from the Northern Pacific Gyre’s “eastern garbage patch”
Lorena M. Rios, Patrick R. Jones, Charles Moore and Urja V. Narayan
J. Environ. Monit., 2010, 12, 2226-2236
DOI: 10.1039/C0EM00239A

Determination of butyl-, phenyl-, octyl- and tributylmonomethyltin compounds in a marine environment (Bay of Bengal, India) using gas chromatography-inductively coupled plasma mass spectrometry
R. Babu Rajendran, H. Tao, A. Miyazaki, R. Ramesh and S. Ramachandran
J. Environ. Monit., 2001, 3, 627-634
DOI: 10.1039/B106009K

PET bottle use patterns and antimony migration into bottled water and soft drinks: the case of British and Nigerian bottles
Aminu Tukur, Liz Sharp, Ben Stern, Chedly Tizaoui and Hadj Benkreira
J. Environ. Monit., 2012, 14, 1237-1247
DOI: 10.1039/C2EM10917D

Characterization and environmental implications of nano- and larger TiO2 particles in sewage sludge, and soils amended with sewage sludge
Bojeong Kim, Mitsuhiro Murayama, Benjamin P. Colman and Michael F. Hochella
J. Environ. Monit., 2012, 14, 1129-1137
DOI: 10.1039/C2EM10809G

Impact of agglomeration and different dispersions of titanium dioxide nanoparticles on the human related in vitro cytotoxicity and genotoxicity
Zuzana Magdolenova, Dagmar Bilaničová, Giulio Pojana, Lise M Fjellsbø, Alexandra Hudecova, Katarina Hasplova, Antonio Marcomini and Maria Dusinska
J. Environ. Monit., 2012, 14, 455-464
DOI: 10.1039/C2EM10746E

The antibacterial effects of engineered nanomaterials: implications for wastewater treatment plants
Ndeke Musee, Melusi Thwala and Nomakhwezi Nota
J. Environ. Monit., 2011, 13, 1164-1183
DOI: 10.1039/C1EM10023H

Seasonal distribution, source investigation and vertical profile of phenolic endocrine disrupting compounds in Dianchi Lake, China
Bin Wang, Bin Huang, Wei Jin, Yu Wang, Shimin Zhao, Farong Li, Ping Hu and Xuejun Pan
J. Environ. Monit., 2012, 14, 1275-1282
DOI: 10.1039/C2EM10856A

Polyfluoroalkyl compounds in the aquatic environment: a review of their occurrence and fate
Lutz Ahrens
J. Environ. Monit., 2011, 13, 20-31
DOI: 10.1039/C0EM00373E

Monitoring bacterial community structure and variability in time scale in full-scale anaerobic digesters
Sang-Hoon Lee, Hyun-Jin Kang, Young Haeng Lee, Taek Jun Lee, Keumsuk Han, Youngjun Choi and Hee-Deung Park
J. Environ. Monit., 2012, Advance Article
DOI: 10.1039/C2EM10958A

Occurrence, distribution and bioaccumulation of antibiotics in the Haihe River in China
Lihong Gao, Yali Shi, Wenhui Li, Jiemin Liu and Yaqi Cai
J. Environ. Monit., 2012, 14, 1248-1255
DOI: 10.1039/C2EM10916F

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to JEM? Then why not submit to us today or alternatively email us your suggestions.

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Painting the mountains blue

Vera Thoss tells Elinor Richards about her bluebell business and research, using her car in her experiments and analysing whale vomit

Vera Thoss lying in bluebell fieldVera Thoss is an environmental chemistry lecturer at Bangor University, UK. Her research is based on ecological chemistry, which addresses processes mediated through specific compounds within ecosystems and environmental chemistry, which is concerned with the impact of human activities on the environment.

What inspired you to become a scientist?

It all started when I was 13 and I had my first chemistry lesson. I instantly took to the subject and from then my mind was made up. I was also curious and wanted to ‘understand the world’.

What attracted you to environmental science?

As a chemist, the choice was between synthetic and analytical chemistry. I chose analytical chemistry because it allows you to follow the environmental fate of natural or man-made compounds. Being allowed to spend time in the woods was a big bonus!

What projects are you working on?

Currently, my group is working on oil pollution, composting and plant-derived products. It seems a bit of a stretch but it is all part of carbon cycling: plants build precious molecules, most of the time these remain intact but may transfer into air, water or soil. Crude oil is the remnants of sunken forests. So in the end, all the chemistry comes from plants photosynthesising and creating complex fragrances, tastes and colours. It is fascinating.

What will be the next big breakthrough in your field?

To chemically separate plant material into multiple useable compounds, with environmentally benign techniques, using as little energy as possible and ideally producing no waste at all.

Which achievements are you most proud of?

My beautiful daughter.  Last year I organised the first ‘Plants as Providers of Fine Chemicals’ conference, which was very successful.  I also managed to measure picogram amounts of monoterpenes in three-week-old Scots pine seedlings before they were eaten by slugs.

You own a farm from which you run a business selling bluebells called Vera Bluebell. How did this come about?

I was always concerned about the availability of clean drinking water, and moving to a mountain farm near Snowdon in Wales was a strategic choice (it does rain a lot!). Realising that there was abundance of bluebells on the land was a chance discovery after a fire. I was aware of their unusual chemistry though and that was the starting point for Vera Bluebell. Bluebells are protected, which means a license is needed to work with them. There was a demand for wild bluebells as well. We have now been sustainably managing a wild bluebell population for over six years and it has been an interesting journey. I would love to see a bluebell derived extract being used in a commercial product.

What discoveries have you made during your research on bluebells?

Bluebell seeds have a high oil content and the oil has an unusual composition. Even though this is the first chemical assessment of Hyacinthoides non-scripta oil, the chemistry is not earth-shattering. The ecology aspects gave room for more discoveries, for example we found seed stores on the site, meaning that possibly voles or shrew have collected the seeds for storage. This has never been reported before.

Tell us about your bluebell conservation efforts and how your research can help.

We are hoping to show that bluebell seeds can be a source of fine chemicals. We obtain an oil of unusual composition from the seeds. The residue contains iminosugars, which may be of use in future medicines. I am hoping that the compounds isolated from bluebell seeds will be of commercial value, which in turn means that the conservation of bluebells pays for itself. We are hoping to paint the mountains and woodlands blue again.

You’re involved with projects called BEACON and PROBECO. What are these and what is your role in both projects?

BEACON is all about biorefining, obtaining different compounds from the same plant feedstock. There are different feedstocks investigated in BEACON ranging from perennial rye grass to ivy. My role is to analyse whole plant composition and organise the ‘ Plants as Providers of Fine Chemicals ‘  conference. The PROBECO project was about the influence of monoterpenes on ecosystem processes in Caledonian Scots pine forests. These are very rare ecosystems. Individual pine trees smell different and the forest served as a study site to investigate the role of specific monoterpenes. I was the scientist analysing the smell of thousands of pine trees and we came up with the chemodiversity hypothesis.

In 2007, you worked with Welsh company Used Tyre Distillation Research to produce novel products from used tyres, in particular oil for fuelling cars. What was your role in the research? I read that your car was used to test the fuel. What was the result?

Again my role was to analyse the products. The oil was a complex mixture and we did see some interesting compounds in it. The tyre oil was noticeably energy dense, giving faster acceleration to the car, which has survived the experiment well!

In 2008, you had an odd request to analyse what was thought to be whale vomit (ambergris) on a North Wales beach. Why is whale vomit so important and what did you find?

I’ve had a few requests for the analysis of beach finds. Ambergris is sought after in the perfume industry, but we have yet to get our hands on some. Most samples were waxes or plastic, which possibly fell overboard, just aged in the sea.

What other odd things have you been asked to analyse?

Another nice in-house example for analysis was to trace a smell in the corridor back to its origin: we sampled air in the corridor outside my office and the terrible smell was found to be due to demolition work going on next door. If it stinks don’t automatically blame the chemists!

What do you do in your spare time?

I love gardening, farming and generally just being outdoors. I am an amateur bee keeper and enjoy spending time with my family.

Read the original article at Chemistry World, or Vera’s recent paper in the journal RSC Advances:

Triacylglycerol composition of British bluebell (Hyacinthoides non-scripta) seed oil
Vera Thoss, P J Murphy, Ray John Marriott and Thomas Wilson
DOI: 10.1039/C2RA20090B

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Dioxin 2012 Symposium

Cairns convention centre This year’s International Symposium on Halogenated Persistent Organic Pollutants will be held in Cairns, Australia, at the Cairns Convention Centre. The conference runs from 26-31 August 2012.

Each year, the International Dioxin Symposium provides an excellent opportunity for the presentation and discussion of the most current scientific research on POPs (Persistent Organic Pollutants) across all disciplines, including analytical and environmental chemistry, molecular biology, human health, risk assessment and risk management.

This year’s Symposium Chairs are Jochen Mueller and Caroline Gaus, from the National Research Centre for Environmental Toxicology (Entox) at the University of Queensland.

Cairns at nightA wide range of core topics on analytical and environmental chemistry, environmental and human toxicology, epidemiology, exposure assessment, as well as regulation, risk assessment and management will be covered. Dioxin 2012 will also feature discussion on important global and current regional issues, focusing on topics such as emerging contaminants, marine and eco-toxicology, and chemical regulation and policy. For more information on this exciting conference and details of how to register, please see the website.

In attendance at the conference will be Professor Beate Escher, Editorial Board Member and Associate Editor for the Journal of Environmental Monitoring. I’m sure she’d be delighted to meet you.

Important dates for your diaries:

Abstract submission opens – 7 March 2012
Registration – Now open
Abstract submission deadline – 14 May 2012
Notifications to submitters – 15 June 2012
Early bird registration closes – 22 June 2012

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Latest hot articles on understanding Cr(VI) generation in drinking water and the effect of organic matter on nanoparticle stabilisation

Dana Lindsay and colleagues at Manhattan College, USA, have conducted a study to better understand the rate and extent of carcinogenic CrVI generation following the disinfection of drinking water with chlorine.  Trace amounts of CrIII may be present in water supplies, but the extent to which this is oxidised to CrVI is poorly understood.  Lindsay and colleagues found that oxidation occurred within a matter of hours, and therefore could occur during water treatment plants, but plateaued at less than 100% conversion, even with relatively high doses of chlorine.

Oxidation of CrIII to CrVI during chlorination of drinking water
Dana R. Lindsay ,  Kevin J. Farley and Richard F. Carbonaro
J. Environ. Monit., 2012, Advance Article
DOI: 10.1039/C2EM00012A

Understanding the fate and transport of engineered nanoparticles in the environment is a key issue, this paper Jeffery Nason et al. have investigated the effect of natural organic matter on the stabilisation of nanoparticles in aquatic environments.  Their findings indicate that both the type and concentration of the organic matter, along with the ionic strength of the aquatic system are important factors in determining colloidal nanoparticle stability.

Effects of natural organic matter type and concentration on the aggregation of citrate-stabilized gold nanoparticles
Jeffrey A. Nason ,  Shannon A. McDowell and Ty W. Callahan
J. Environ. Monit., 2012, Advance Article
DOI: 10.1039/C2EM00005A

Both these papers are free to access for 4 weeks following a simple registration for individual users.

Dana R. Lindsay
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