Archive for the ‘Chemistry World’ Category

Deft defecators done in 12 seconds

From a 4kg cat to a 4000kg elephant, any animal takes only around 12 seconds to ‘do their business’. This is what a team of US scientists found after thoroughly studying the process of defecation in over 40 animal species. They then developed a theoretical fluid dynamics model that shows how viscosity changes in faecal mucus ease excretion.

Source: © RSC
The relationship between body mass and defecation time


Despite being extensively studied from a clinical and medical perspective, the physics of pooing has until now escaped extensive exploration.

Inspired by a slow motion video of a defecating elephant obtained during their previous work on urination, David Hu and his team from Georgia Institute of Technology acquired similar videos of other mammals ranging from dogs to giant pandas. They found that despite obvious differences in animals’ size and diet, defecation time averaged to around 12 (±7) seconds across all of the species they looked at.

Read the full story by Charlie Quigg in Chemistry World.


This article is free to access until 21 June 2017

P J Yang et al, Soft Matter, 2017, DOI: 10.1039/C6SM02795D

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Tiny bubbles made easier

Researchers in Canada have shrunk bubbles to single-micrometre diameters, suitable for use in ultrasound.

Source: Royal Society of Chemistry
Bubbles shrink down to 1–7µm in diameter as they flow through the device’s serpentine microchannel

Microbubbles are commonly used in ultrasound imaging as they improve the visual distinction between blood and surrounding tissues. Bubbles are injected intravenously, and under ultrasound they are excited at their resonant frequency. This resonance means they scatter a much higher proportion of the ultrasound than the surrounding tissues, allowing clear imaging of blood vessels.

The bubbles needed for ultrasound are around 2µm in diameter. Current microfluidic techniques cannot produce bubbles this small, and the techniques used to generate these microbubbles generally use physical agitation or shearing. The bubbles produced often have a large size distribution, and filtration is needed to separate out those suitable for use.


Read the full story by Laura Fisher in Chemistry World.


This article is free to access until 24 May 2017

V Gnyawali et al, Soft Matter, 2017, DOI: 10.1039/C7SM00128B

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Nanotubes make Kevlar armour smarter

Chinese scientists have used conducting carbon nanotubes and impact-responsive polymers to create a smart Kevlar composite with enhanced ballistic and stab resistance. Body armour made from this material could sense the force and location of impacts, and detect when it has been pierced.

Flexible, lightweight and durable, Kevlar has been a key component in personal armour for decades. It has excellent stab and cut resistance, making it the primary component in police stab vests, also offering limited protection against small arms fire.

 

Source: © Royal Society of Chemistry
Scanning electron microscopy images showing regular Kevlar (a, b) and the improved version with different shear-stiffening polymer/Kevlar ratios (c: 4.8 weight% polymer; f: 84 weight% polymer)

The problem with Kevlar’s flexibility is that when it stops a bullet, the energy is still transferred directly to the wearer at the point of impact, which causes trauma – imagine being punched at the speed of a bullet! For military applications, where Kevlar would not stand up to high-velocity rifle rounds, it is often combined with heavier steel or ceramic plates to spread the impact over a larger area.


Read the full story by Will Bergius in Chemistry World.


This article is free to access until 17 May 2017.

S Wang et al, Soft Matter, 2017, DOI: 10.1039/c7sm00095b

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Shape memory polymers get a grip

Researchers in the US have developed a new way to curl polymer sheets to create a variety of 3D structures.

Shape memory polymers change shape in response to external stimuli such as light and heat. Chemists add active materials to polymer sheets, which then deform on stimulation. Usually the active materials are placed in regions where curvature is desired, but Michael Dickey, Jan Genzer and their colleagues at North Carolina State University have now shown they can deform regions adjacent to the active materials.

 

Source: © Royal Society of Chemistry



Read the full story by Laura Fisher in Chemistry World.


This article is free to access until 14 April 2017.

A M Hubbard et al, Soft Matter, 2017, DOI: 10.1039/c7sm00088j

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Cracking theory helps understand paint ageing

New model could benefit art conservators and geologists

Source: © Royal Society of Chemistry / Image courtesy of Mauritshuis Museum.

Understanding how cracking patterns develop in desiccated surfaces like old oil paintings or dried mud is surprisingly difficult. Now a Chilean scientist has established the first mathematical model of cracked surfaces that could help conservators preserve old paintings or give geologists information about the thickness of cracked clay or salt layers, and the stress they’ve been subjected to.

In oil paintings, the varnish becomes less flexible with age and when the canvas shrinks and expands in response to humidity and temperature changes, the paint starts to crack. As the cracks are hard to forge, art experts often use them, among other factors, to determine a painting’s authenticity. ‘Crack networks are like fingerprints,’ says JC Flores from the University of Tarapacá, who has developed a series of equations that give a theoretical insight into cracking patterns.

Read the full story by Kat Kramer in Chemistry World.


This article is free to access until 10 March 2017.

J C Flores, Soft Matter, 2017, DOI: 10.1039/c6sm02849g

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How to not make a splash

Study adds to understanding of droplet behaviour

New research by a scientist in the US can better explain how a droplet splash is dictated by the smoothness of a surface, as well as the surrounding air pressure.

Source: © Royal Society of Chemistry


Scientists already knew that two aspects were involved in this seemingly simple process; one related to the surrounding air, and the other to how the liquid spreads on the substrate. ‘If we were forced to guess, we’d probably assume that decreasing the ambient pressure around the drop would make the splash bigger. After all, we’re decreasing air resistance,’ explains Andrzej Latka, at the University of Chicago, who performed the new research.

Read the full story and watch the video showing the splash in Chemistry World.



This article is free to access until 28 February 2017.

Andrzej Latka, Soft Matter, 2017. DOI: 10.1039/C6SM02321E

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