Author Archive

RSC Supramolecular Chemistry Award for Editor-in-Chief Mike Ward

Each year the Royal Society of Chemistry presents prizes and awards to chemical scientists who have made a considerable contribution in their area of research, in industry and academia. This year, we are delighted to announce that RSC Advances Editor-in-Chief, Professor Mike Ward of the University of Sheffield, UK, has been awarded the 2016 RSC Supramolecular Chemistry Award, for his leading contributions to the synthesis, characterisation, host-guest chemistry and functional properties of self-assembled coordination cages.

The Supramolecular Chemistry Award is awarded biennially and recognises studies leading to the design of functionally useful supramolecular species.

In celebration of the 2016 RSC Prizes and Awards, we have collected together some of the research recently published by the winners. This collection showcases articles authored by the winners from across the Royal Society of Chemistry’s journals portfolio, which are free to access for a limited period. A full list of 2016 winners and more information about RSC Prizes and Awards can be found here.

Please join us in congratulating Mike on this achievement!

We would like to highlight the RSC Advances themed collection, Supramolecular chemistry: self-assembly and molecular recognition, Guest Edited by Mike Ward.

The articles in this issue cover many aspects of the formation of, and molecular recognition with, non-covalent self-assembled systems. Systems studied span the range of supramolecular assemblies from MOFs to gels, and potential applications or functional behaviour that are on display here include host/guest chemistry, spin crossover, molecular sensors, and extraction/separation. This collection of articles powerfully illustrates the diversity and increasing importance of supramolecular chemistry.

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Supramolecular cages for chemical weapons

The research of RSC Advances Chief Editor Mike Ward focussing on the development of supramolecular cages that trap chemical weapon stimulants, has been highlighted in Chemistry World.

Mike and his team at Sheffield University have developed new supramolecular cages that exploit the hydrophic effect and bind alkyl phosphonates inside. These phosphonates are very similar to organophosphorous chemical weapons. Cobalt or cadmium dications form the cage vertices and bis(pyrazolyl-pyridine) ligands run along each edge, forming a hydrophobic centre lined with CH groups. So, in water, the phosphonate hydrophobic alkyl tails are attracted to the inside of the cage. Whats more, the cage is luminescent and this luminescence reduces when alkyl phosphonate enters, meaning that the cages can also be used to signal the presence of chemical weapons.

The supramolecular structure

To find out more, read the full Chemistry World article based on this paper:

Binding of chemical warfare agent simulants as guests in a coordination cage: contributions to binding and a fluorescence-based response
Christopher G. P. Taylor, Jerico R. Piper and Michael D. Ward
Chem. Commun., 2016
DOI: 10.1039/C6CC02021F

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Magnetic leathers

Leather is a natural, durable and flexible material that has been prepared and used by humans for millennia. Now, scientists in India have developed magnetic leathers that can make this material evermore versatile.

Made from animal hide, leather is largely made of a chromium-collagen matrix and is paramagnetic. Despite this, it does not interact effectively with magnetic fields. Introducing ferromagnetic properties to leather could enable this material to be used in smart or intelligent garments, electromagnetic interference shielding, adhesive-free wall covering and even in energy harvesting from human motion. As such, a team lead by Dr Krishbaraj Kaliappa at the Central Leather Institute in Chennai, added iron oxide nanoparticles to leather that show significant magnetic behaviour.

The team prepared leather samples using conventional finishing techniques. During this process, they applied a coating of  iron oxide nanoparticles produced by co-precipitation, or a commercially available magnetic pigment. The presence of Fe3O2 in both samples was confirmed by X-ray diffraction analysis. When compared to the paramagnetic control leather, magnetic hysteresis revealed considerable ferromagnetic behavior in the two samples. In addition, the leathers show significant response to permanent magnets. Further tests revealed that particle incorporation leaves other physical properties of the leather, largely unchanged.

Investigations in to the applications of these magnetic leathers have already shown them to be promising adhesive-free wall tiles. The team also demonstrate that their properties may also enable application in electromagnetic energy generation from human motion.

Digital images of the control leather , that with iron oxide nanoparticles and that with the commercially available magnetic pigment added during finishing.

Read the full article:

Magnetic leathers
P. Thanikaivelan, R. Murali and K. Krishnaraj
RSC Adv., 2016,6, 6496-6503 DOI: 10.1039/C5RA21909D

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Canine tea time

Researchers in China have manufactured dog food containing tea polyphenols. They have shown that when dogs are fed tea polyphenol containg food, antioxidant and antimicrobial effects, similar to those observed in humans, are demonstrated.

Fang Zhong and colleagues also wanted to test the foods palpability to find out if the dogs would actually enjoy eating it. Following a five day trial, it emerged that dogs actually preferred eating food that contained 0.5% tea polyphenols. The dogs’ diet was then restricted to either tea polyphenol containing food or the control food. Subsequent tests revealed higher levels of antioxidant activity in the dogs on the tea polyphenol diet, along with lower levels of fecal bacteria in their stool.

To find out more, read the full Chemistry World article.

Quantitative optimization and assessments of supplemented tea polyphenols in dry dog food considering palatability, levels of serum oxidative stress biomarkers and fecal pathogenic bacteria,
Maoshen Chen, Xuemei Chen, Wenli Cheng, Yue Li, Jianguo Ma and Fang Zhong
RSC Adv., 2016,6, 16802-16807
DOI: 10.1039/C5RA22790A

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Introducing the organic chemistry collection

This organic chemisty collection has been collated by Editorial Board member Professor Russell Cox (Leibniz University Hannover, Germany). It brings together articles with the continued aim of inspiring new authors to submit their best work to the journal, and also to highlight great work by regular authors. These articles are already among the most highly cited works in the journal, illustrating their impact.

The subject areas of the articles include those traditionally regarded as organic, such as synthesis, catalysis, heterocyclic and organometallic chemistry, natural products chemistry and method development. In addition, the collection also includes articles from overlapping areas, such as green chemistry, fuel production, ionic solvents and materials chemistry, where there is a strong organic and biological component. Underpinning all are theoretical and computational studies. Finally, emerging areas, including photovoltaics and chemical biology, have strong organic chemistry foundations and also find a natural home in this RSC Advances collection.

This selection aims to illustrate the breadth, depth and impact of papers published in RSC Advances in the area of organic chemistry and stimulate new submissions in these and allied areas.

The collection contains reviews, communications and full papers, all of which can be found here.

Credit: Recent advances in 4(3H)-quinazolinone syntheses, 10.1039/C4RA00351A

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