Welcome to Issue 10 of Organic Chemistry Frontiers in 2019

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Welcome to issue 10 of Organic Chemistry Frontiers for 2019 ! The latest OrgChemFront issue is published online now.

The front cover story, Functionalisable acyclic cucurbiturils is contributed by Stefan Kubik and co-authors. The inside cover features a story on Tunable enforced cavities inside self-assembled capsules  by Takeharu Haino and co-authors.

 

 

 

 

 

 

 

Follow review type article is included in current issue:

Diffusion NMR for the characterization, in solution, of supramolecular systems based on calixarenes, resorcinarenes, and other macrocyclic arenes
Yoram Cohen and Sarit Slovak
Org. Chem. Front., 2019,6, 1705-1718
https://doi.org/10.1039/C9QO00329K

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Hot Article in April 2019

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Organic Chemistry Frontiers is delighted to share with you the HOT article of April 2019!

You can access this publication for free till 30 June 2019 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org)

 

Palladium-catalyzed dearomative arylphosphorylation of indoles
Jian-Quan Weng, Ling-Ling Xing, Wen-Ren Hou, Ren-Xiao Liang and Yi-Xia Jia
Org. Chem. Front., 2019, Advance Article
http://dx.doi.org/10.1039/C9QO00246D

Visible-light-mediated hydrodehalogenation and Br/D exchange of inactivated aryl and alkyl halides with a palladium complex
Zhao-Zhao Zhou, Jia-Hui Zhao, Xue-Ya Gou, Xi-Meng Chen and Yong-Min Liang
Org. Chem. Front., 2019, Advance Article
http://dx.doi.org/10.1039/C9QO00240E

A pore-expanded supramolecular organic framework and its enrichment of photosensitizers and catalysts for visible-light-induced hydrogen production
Meng Yan, Xu-Bo Liu, Zhong-Zheng Gao, Yi-Peng Wu, Jun-Li Hou, Hui Wang, Dan-Wei Zhang, Yi Liu and Zhan-Ting Li
Org. Chem. Front., 2019, Advance Article
http://dx.doi.org/10.1039/C9QO00382G

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Welcome to Issue 9 of Organic Chemistry Frontiers in 2019

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Welcome to issue 9 of Organic Chemistry Frontiers for 2019 ! The latest OrgChemFront issue is published online now.

Graphical abstract: Front coverThe front cover story, One-pot sequential synthesis of Graphical abstract: Inside front cover3-carbonyl-4-arylbenzo[f]indole and 3-carbonyl-4-arylnaphthofuran fluorophores is contributed by  J. Tummatorn and co-authors. The inside cover features a story on Chemoselective N-arylation of aminobenzene sulfonamides via copper catalysed Chan–Evans–Lam reactions bu Liang Xu, Xin Jia and co-authors.

 

 

 

Follow review type article is included in current issue:

Gold-catalyzed heterocyclic syntheses through α-imino gold carbene complexes as intermediates

Enrique Aguilar and Javier Santamaría
Org. Chem. Front., 2019,6, 1513-1540
http://dx.doi.org/10.1039/C9QO00243J

 

Follow highlight type article is included in current issue:

19F-GEST NMR: studying dynamic interactions in host–guest systems
Liat Avram and Amnon Bar-Shir
Org. Chem. Front., 2019,6, 1503-1512
http://dx.doi.org/10.1039/C9QO00311H

 

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Welcome to Issue 8 of Organic Chemistry Frontiers in 2019

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Welcome to issue 8 of Organic Chemistry Frontiers for 2019 ! The latest OrgChemFront issue is published online now.

Journal cover: Front coverThe front cover story, Asymmetric synthesis of highlyJournal cover: Inside front cover functionalized furanones via direct Michael reactions mediated by a bulky primary amine, is contributed by  Huicai Huang and co-authors. The inside cover features a story on Spirocyclic cladosporicin A and cladosporiumins I and J from a Hydractinia-associated Cladosporium sphaerospermum SW67 by Christine Beemelmanns and co-authors.

 

 

 

 

Follow review type article is included in current issue:

Progress in the synthesis of perylene bisimide dyes
Agnieszka Nowak-Król and Frank Würthner
Org. Chem. Front., 2019,6, 1272-1318
http://dx.doi.org/10.1039/C8QO01368C

Follow highlight type article is included in current issue:

Neglected sulfur(VI) pharmacophores in drug discovery: exploration of novel chemical space by the interplay of drug design and method development
U. Lücking
Org. Chem. Front., 2019,6, 1319-1324
http://dx.doi.org/10.1039/C8QO01233D

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Hot Article in March 2019

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Organic Chemistry Frontiers is delighted to share with you the HOT article of March 2019!

You can access this publication for free till 31 May 2019 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org)

 

Quantification of the hydrophobic effect using water-soluble super aryl-extended calix[4]pyrroles
Luis Escobar and Pablo Ballester
Org. Chem. Front., 2019, Advance Article
http://dx.doi.org/10.1039/C9QO00171A

 

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Welcome to Issue 7 of Organic Chemistry Frontiers in 2019

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Welcome to issue 7 of Organic Chemistry Frontiers for 2019 ! The latest OrgChemFront issue is published online now.

The front cover story, A concise approach for determining the relative configuration of H-7 and H-8 in 8,4′-oxyneolignans by 1H NMR spectroscopy, is contributed by  Pei-Cheng Zhang and co-authors.

The inside cover features a story on Guest-mediated chirality transfer in the host–guest complexes of an atropisomeric perylene bisimide cyclophane host by Frank Würthner and co-authors.

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Organic chemistry research for asymmetric synthesis

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We are delighted to share with you a collection of articles from Organic Chemistry Frontiers to showcase the recent development in asymmetric synthesis.

You can read these articles for free until 30th April.

Reviews articles

Multi-catalyst promoted asymmetric relay reactions
Qiu-Ju Liang, Yun-He Xu and Teck-Peng Loh
Org. Chem. Front., 2018,5, 2765-2768
http://dx.doi.org/10.1039/C8QO00604K

Total synthesis of natural products via iridium catalysis
Changchun Yuan and Bo Liu
Org. Chem. Front., 2018,5, 106-131
http://dx.doi.org/10.1039/C7QO00664K

Lu’s [3 + 2] cycloaddition of allenes with electrophiles: discovery, development and synthetic application
Yin Wei and Min Shi
Org. Chem. Front., 2017,4, 1876-1890
http://dx.doi.org/10.1039/C7QO00285H

Catalytic asymmetric synthesis of hetero-substituted oxindoles
Renato Dalpozzo
Org. Chem. Front., 2017,4, 2063-2078
http://dx.doi.org/10.1039/C7QO00446J

Research articles

Asymmetric Diels–Alder cycloadditions of benzofulvene-based 2,4-dienals via trienamine activatio
Jing-Fei Yue, Guang-Yao Ran, Xing-Xing Yang, Wei Du and Ying-Chun Chen
Org. Chem. Front., 2018,5, 1284-1287
http://dx.doi.org/10.1039/C8QO00653A

Diastereoselectivity in a cyclic secondary amine catalyzed asymmetric Mannich reaction: a model rationalization from DFT studies
Siwei Shu, Zhao Liu, Yukui Li, Zhuofeng Ke and Yan Liu
Org. Chem. Front., 2018,5, 2148-2157
http://dx.doi.org/10.1039/C8QO00424B

Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates
Hui Leng Sang, Songjie Yu and Shaozhong Ge
Org. Chem. Front., 2018,5, 1284-1287
http://dx.doi.org/10.1039/C8QO00167G

Synthesis of trans-disubstituted-2,3-dihydrobenzofurans by a formal [4 + 1] annulation between para-quinone methides and sulfonium salts
Ying Zhi, Kun Zhao, Carolina von Essen, Kari Rissanen and Dieter Enders
Org. Chem. Front., 2018,5, 1348-1351
http://dx.doi.org/10.1039/C8QO00008E

1,6-Conjugated addition-mediated [4 + 1] annulation: an approach to 2,3-dihydrobenzofurans
Yang Wang, Yan Qiao, Donghui Wei and Mingsheng Tang
Org. Chem. Front., 2018,5, 623-628
http://dx.doi.org/10.1039/C7QO00846E

Computational study on NHC-catalyzed enantioselective and chemoselective fluorination of aliphatic aldehydes
Lina Liu, Zhenbo Yuan, Rui Pan, Yuye Zeng, Aijun Lin, Hequan Yao and Yue Huang
Org. Chem. Front., 2017,4, 1987-1998
http://dx.doi.org/10.1039/C7QO00436B

Asymmetric synthesis of CF3– and indole-containing tetrahydro-β-carbolines via chiral spirocyclic phosphoric acid-catalyzed aza-Friedel–Crafts reaction
En Xie, Abdul Rahman and Xufeng Lin
Org. Chem. Front., 2017,4, 1407-1410
http://dx.doi.org/10.1039/C7QO00229G

Highly enantioselective nitro-Mannich reaction of ketimines under phase-transfer catalysis
Bin Wang, Tong Xu, Lei Zhu, Yu Lan, Jingdong Wang, Ning Lu, Zhonglin Wei, Yingjie Lin and Haifeng Duan
Org. Chem. Front., 2017,4, 1266-1271
http://dx.doi.org/10.1039/C7QO00124J

Asymmetric synthesis of trifluoromethyl-substituted 3,3′-pyrrolidinyl-dispirooxindoles through organocatalytic 1,3-dipolar cycloaddition reactions
Wei-Jie Huang, Qing Chen, Ning Lin, Xian-Wen Long, Wei-Gao Pan, Yan-Shi Xiong, Jiang Weng and Gui Lu
Org. Chem. Front., 2017,4, 472-482
http://dx.doi.org/10.1039/C6QO00723F

The synthesis of unsymmetric diamides through Rh-catalyzed selective C–H bond activation of amides with isocyanates
Xiaoli Yu, Duo-Sheng Wang, Zhaojun Xu, Bobin Yang and Dawei Wang
Org. Chem. Front., 2017,4, 1011-1018
http://dx.doi.org/10.1039/C6QO00793G

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Outstanding Reviewers for Organic Chemistry Frontiers in 2018

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We would like to highlight the Outstanding Reviewers for Organic Chemistry Frontiers in 2018, as selected by the editorial team, for their significant contribution to the journal. The reviewers have been chosen based on the number, timeliness and quality of the reports completed over the last 12 months.

We would like to say a big thank you to those individuals listed here as well as to all of the reviewers that have supported the journal. Each Outstanding Reviewer will receive a certificate to give recognition for their significant contribution.

 

Professor Xiaoming Feng, Sichuan University,https://orcid.org/0000-0003-4507-0478
Prof. Xuefeng Jiang, East China Normal University,https://orcid.org/0000-0002-1849-6572
Dr Feng Shi, Jiangsu Normal University,https://orcid.org/0000-0003-3922-0708
Prof. Huanfeng Jiang, South China University of Technology,https://orcid.org/0000-0002-4355-0294
Dr Junliang Zhang, Fudan University,https://orcid.org/0000-0002-4636-2846
Dr Ying-Chun Chen, Sichuan University,https://orcid.org/0000-0003-1902-0979
Dr Michal Szostak Rutgers, The State University of New Jersey ,https://orcid.org/0000-0002-9650-9690
Dr Takashi Koike, Tokyo Kogyo Daigaku,https://orcid.org/0000-0002-3737-7093
Dr Varma Saikam, Georgia State University,https://orcid.org/0000-0003-2500-9717
Dr Igor Alabugin Florida, Florida State University ,https://orcid.org/0000-0001-9289-3819

 

We would also like to thank the Organic Chemistry Frontiers board and the organic chemistry community for their continued support of the journal, as authors, reviewers and readers.

If you would like to become a reviewer for our journal, just email us (OrgChemFrontiersED@rsc.org) with details of your research interests and an up-to-date CV or résumé.  You can find more details in our author and reviewer resource centre

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Welcome to Issue 6 of Organic Chemistry Frontiers in 2019

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Welcome to issue 6 of Organic Chemistry Frontiers for 2019 ! The latest OrgChemFront issue is published online now. 

 

Journal cover: Front coverThe front cover story, Selective carbonylation of benzene to Journal cover: Inside front coverbenzaldehyde using a phosphorus–nitrogen PN3P–rhodium(I) complex, is contributed by Huang Kuo-Wei and co-authors.

The inside cover features a story on Deciphering the exceptional selectivity of semipinacol rearrangements in cis-fused β-lactam diols using high-level quantum chemical methods by Abdulkader Baroudi and Amir Karton.

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Congratulations to the SupraChem 2019 Award Winners!

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SupraChem 2019 was recently held at the Julius-Maximilians-Universität in Würzburg, Germany and organised by Florian Beuerle and Organic Chemistry Frontiers Associate Editor Frank WürthnerOrganic Chemistry Frontiers was proud to support and sponsor the meeting, alongside Chemical Science and Materials Chemistry Frontiers.

This free-to-attend meeting brought together supramolecular chemists from Germany and neighbouring countries and covered a range of topics from supramolecular machinery to materials and analytical techniques to host-guest chemistry and sensing. Keynote lectures were given by world-renowned supramolecular chemists Vivian W. W. Yang, J. Fraser Stoddart and, new Chemical Science Editor-in-Chief, Andrew I. Cooper. These speakers helped generate some great discussion alongside the additional 27 presentations and led to a very successful meeting.

Chemical Science Deputy Editor Jeremy Allen was in attendance to meet with the delegates and represent the Royal Society of Chemistry. He also helped present some poster prizes on behalf of Chemical Science and Organic Chemistry Frontiers:

  • Chemical Science poster prize winner: Jonas Matern (Universität Münster) for “Insights into the complex self-assembly pathways of a chiral, oligophenyleneethynylene (OPE) based Pd(II) complex”
  • Organic Chemistry Frontiers poster prize winner: Julia Bartl (TU Kaiserslautern) for “A cyclopeptide-derived molecular cage for anion encapsulation”

Jeremy Allen presenting poster prizes to Jonas Matern (Left) and Julia Bartl (Right)

There were a further 5 poster prizes awarded from other journals and publishing houses, these went to:

  • Meike Sapotta (Universität Würzburg) for “A water-soluble perylene bisimide cyclophane as a molecular probe for the recognition of aromatic alkaloids”
  • Irene Regeni (TU Dortmund) for “Self-assembled [Pd2L4] coordination cages based on well-known organic dyes”
  • Oleksandr Shyshov (Universität Ulm) for “Supramolecular chemistry of all-cis hexafluorocyclohexane and its derivatives”
  • Hendrik V. Schröder (FU Berlin) for “Accordion-like motion in electrochemically switchable crown ether/ammonium oligorotaxanes”
  • Sebastian M. Kopp (Universität Würzburg) for “Toward singlet fission: chromophore multiplication in pentacene derivatives with adamantyl bridges”

(Left to right) Markus Albrecht, Jeremy Allen, Irene Regeni, Oleksandr Shyshov, Julia Bartl, Meike Sapotta, Jonas Matern, Diane Smith, Sebastian Kopp, Hendrik Schröder, Frank Würthner, Florian Beuerle

Congratulations to all the poster prize winners!

SupraChem 2019 delegates

The next SupraChem meeting will be held in 2021 in Mainz, Germany

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