Archive for the ‘Hot articles’ Category

Hot Articles in June 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of June 2018!

You can access these publications for free till 31st August 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Photoexcited perylene diimide radical anions for the reduction of aryl halides: a bay-substituent effect

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00445E

Graphical abstract: Photoexcited perylene diimide radical anions for the reduction of aryl halides: a bay-substituent effect

 

Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00401C

Graphical abstract: Visible-light photocatalytic trifluoromethylthiolation of aryldiazonium salts: conversion of amino group into trifluoromethylthiol group

 

Diastereoselectivity in a cyclic secondary amine catalyzed asymmetric Mannich reaction: a model rationalization from DFT studies

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00424B

Graphical abstract: Diastereoselectivity in a cyclic secondary amine catalyzed asymmetric Mannich reaction: a model rationalization from DFT studies

 

Facile synthesis of macrocyclic peptide toxins of GpTx-1 and its analogue

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00415C

Graphical abstract: Facile synthesis of macrocyclic peptide toxins of GpTx-1 and its analogue

 

Chemical synthesis and biological evaluation of penta- to octa- saccharide fragments of Vi polysaccharide from Salmonella typhi

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00471D

Graphical abstract: Chemical synthesis and biological evaluation of penta- to octa- saccharide fragments of Vi polysaccharide from Salmonella typhi

 

Dysohonin A, a meroditerpenoid incorporating a 6,15,6-fused heterotricyclic ring system from Dysoxylum hongkongense

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00469B

Graphical abstract: Dysohonin A, a meroditerpenoid incorporating a 6,15,6-fused heterotricyclic ring system from Dysoxylum hongkongense

 

Access to sulfonylated furans or imidazo[1,2-a]pyridines via a metal-free three-component, domino reaction

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00443A

Graphical abstract: Access to sulfonylated furans or imidazo[1,2-a]pyridines via a metal-free three-component, domino reaction

 

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00507A

Graphical abstract: Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

 

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00496J

Graphical abstract: Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

 

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Hot Articles in May 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of May 2018!

You can access these publications for free till 31th July 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Efficient catalytic vicinal diamination of arylene diimides
Michael Kremer, Maximilian Kersten and Sigurd Höger
Org. Chem. Front., 2018,5, 1825-1829
http://dx.doi.org/10.1039/C8QO00222C

Graphical abstract: Efficient catalytic vicinal diamination of arylene diimides

 

Azidoheteroarylation of unactivated olefins through distal heteroaryl migration
Min Wang, Zhen Wu, Bo Zhang and Chen Zhu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00301G

Graphical abstract: Azidoheteroarylation of unactivated olefins through distal heteroaryl migration

 

Selective formation of phthalimides from amines, aldehydes and CO by Pd-catalyzed oxidative C–H aminocarbonylation
Renyi Shi, Fan Liao, Huiying Niu and Aiwen Lei
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00282G

Graphical abstract: Selective formation of phthalimides from amines, aldehydes and CO by Pd-catalyzed oxidative C–H aminocarbonylation

 

Selenium dioxide-promoted selective synthesis of mono- and bis-sulfenylindoles
Samuel Thurow, Filipe Penteado, Gelson Perin, Diego Alves, Claudio Santi, Bonifacio Monti, Carl H. Schiesser, Thiago Barcellos and Eder J. Lenardão
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00360B

Graphical abstract: Selenium dioxide-promoted selective synthesis of mono- and bis-sulfenylindoles

 

Highly enantioselective Ir/f-amphox-catalyzed hydrogenation of ketoamides: efficient access to chiral hydroxy amides
Yang Hu, Xuguang Yin, Ziyi Chen, Xiu-Qin Dong and Xumu Zhang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00307F

Graphical abstract: Highly enantioselective Ir/f-amphox-catalyzed hydrogenation of ketoamides: efficient access to chiral hydroxy amides

 

A more reliable synthesis of a Gemini vitamin D analog, a potentially effective chemotherapeutic agent for the treatment of colorectal carcinomas
Hugo Santalla, Fátima Garrido, Generosa Gómez and Yagamare Fall
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00338F

Graphical abstract: A more reliable synthesis of a Gemini vitamin D analog, a potentially effective chemotherapeutic agent for the treatment of colorectal carcinomas

 

Three-component reaction to synthesize E-vinyl silyl anti-1,2-diols via sequential [1,4]-O-to-O/[1,4]-C-to-O silyl migrations
Qiang Pu, Xiaoxiao Tang, Lu Gao and Zhenlei Song
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00332G

Graphical abstract: Three-component reaction to synthesize E-vinyl silyl anti-1,2-diols via sequential [1,4]-O-to-O/[1,4]-C-to-O silyl migrations

 

Convergent syntheses of 2,3-dihydrobenzofurans via a Catellani strategy
Chenggui Wu, Hong-Gang Cheng, Ruiming Chen, Han Chen, Ze-Shui Liu, Jingyang Zhang, Yuming Zhang, Yuxin Zhu, Zhi Geng and Qianghui Zhou
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00348C

Graphical abstract: Convergent syntheses of 2,3-dihydrobenzofurans via a Catellani strategy

 

The iridium-catalysed reductive coupling reaction of tertiary lactams/amides with isocyanoacetates
Xiu-Ning Hu, Tai-Long Shen, Dong-Cheng Cai, Jian-Feng Zheng and Pei-Qiang Huang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00312B

Graphical abstract: The iridium-catalysed reductive coupling reaction of tertiary lactams/amides with isocyanoacetates

 

Asymmetric [4 + 2] cycloadditions with 3-furfural derivatives and α-cyano-α,β-unsaturated ketones
Chuan-Qi Duan, Xiao-Long He, Wei Du and Ying-Chun Chen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00351C

Graphical abstract: Asymmetric [4 + 2] cycloadditions with 3-furfural derivatives and α-cyano-α,β-unsaturated ketones

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Hot Articles in April 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of April 2018!

You can access these publications for free till 3oth June 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Enantioselective indium(I)-catalyzed [4 + 2] annulation of alkoxyallenes and β,γ-unsaturated α-keto esters
Sujia Li, Jian Lv and Sanzhong Luo
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00319J

Graphical abstract: Enantioselective indium(i)-catalyzed [4 + 2] annulation of alkoxyallenes and β,γ-unsaturated α-keto esters

 

The design of rigid cyclic tripyrrins: the importance of intermolecular interactions on aggregation and luminescence
Jun-Fei Wang, Yuhang Yao, Yingying Ning, Yin-Shan Meng, Chun-Liang Hou, Jing Zhang and Jun-Long Zhang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00313K

Graphical abstract: The design of rigid cyclic tripyrrins: the importance of intermolecular interactions on aggregation and luminescence

 

Iridium-catalysed conjugated alkynylation of α,β-unsaturated amide through alkene isomerization
Yun Chen, Zi-Xuan Wang, Qian Li, Li-Jin Xu and Bi-Jie Li
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00136G

Graphical abstract: Iridium-catalysed conjugated alkynylation of α,β-unsaturated amide through alkene isomerization

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Hot Articles in March 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of March 2018!

You can access these publications for free till 31st May 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Base-promoted [3 + 3] cyclization of cyclopropenones and cyclopropenethiones with amides for the synthesis of 6H-1,3-oxazin-6-ones and 6H-1,3-thiazin-6-ones
Ben Niu, Bo Jiang, Liu-Zhu Yu and Min Shi
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00091C

Graphical abstract: Base-promoted [3 + 3] cyclization of cyclopropenones and cyclopropenethiones with amides for the synthesis of 6H-1,3-oxazin-6-ones and 6H-1,3-thiazin-6-ones

 

Research Article Isolation and biosynthesis of labdanmycins: four new labdane diterpenes from endophytic Streptomyces
Zi-Jun Xiong, Jianping Huang, Yijun Yan, Li Wang, Zhiyan Wang, Jing Yang, Jianying Luo, Jie Li and Sheng-Xiong Huang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00085A

Graphical abstract: Isolation and biosynthesis of labdanmycins: four new labdane diterpenes from endophytic Streptomyces

 

Efficient access to chiral benzo[c]chromenes via asymmetric transfer hydrogenation of ketals
Yangshan Li, Miao Wan, Shutao Sun, Zhongjun Fu, Haofei Huang and Lei Liu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00096D

Graphical abstract: Efficient access to chiral benzo[c]chromenes via asymmetric transfer hydrogenation of ketals

 

Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates
Hui Leng Sang, Songjie Yu and Shaozhong Ge
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00167G

Graphical abstract: Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates

 

Total synthesis of teixobactin and its stereoisomers
L. Liu, S. Wu, Q. Wang, M. Zhang, B. Wang, G. He and G. Chen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00145F

Graphical abstract: Total synthesis of teixobactin and its stereoisomers

 

Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3
Bin Xu, Decai Wang, Yonghong Hu and Qilong Shen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00115D

Graphical abstract: Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3

 

Research Article Catalyst-controlled synthesis of 4-amino-isoquinolin-1(2H)-one and oxazole derivatives
Ben Niu, Ruixing Liu, Yin Wei and Min Shi
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00125A

Graphical abstract: Catalyst-controlled synthesis of 4-amino-isoquinolin-1(2H)-one and oxazole derivatives

 

Mechanistic insights into the different chemoselectivities of Rh2(II)-catalyzed ring expansion of cyclobutanol-substituted aryl azides and C–H bond amination of cyclopentanol-substituted aryl azides: a DFT study
Dafang Gao and Xiaoguang Bao
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00113H

Graphical abstract: Mechanistic insights into the different chemoselectivities of Rh2(ii)-catalyzed ring expansion of cyclobutanol-substituted aryl azides and C–H bond amination of cyclopentanol-substituted aryl azides: a DFT study

 

Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes
Jianxiang Yan, Jian Xu, Yao Zhou, Jinglong Chen and Qiuling Song
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00147B

Graphical abstract: Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes

 

Asperones A–E, five dimeric polyketides with new carbon skeletons from the fungus Aspergillus sp. AWG 1–15
Guo-Ping Yin, Ya-Rong Wu, Chao Han, Xiao-Bing Wang, Hong-Liang Gao, Yong Yin, Ling-Yi Kong and Ming-Hua Yang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00070K

Graphical abstract: Asperones A–E, five dimeric polyketides with new carbon skeletons from the fungus Aspergillus sp. AWG 1–15

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Hot Articles in February 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of February 2018!

You can access these publications for free till 30th Apr 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites
Zheng Gu, Ji Zhou, Guo-Fang Jiang and Yong-Gui Zhou
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01158J

A concise synthesis of indene-based polycyclic compounds via FeCl3-catalyzed cascade cyclization
Xiang Su, Panpan Wu, Wenfeng Liu and Chao Chen
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00004B

nBu4NOTf-promoted radical self-hydrogen transferring isomerization under transition metal-free conditions
Hong-Xing Zheng, Chuan-Zhi Yao, Jian-Ping Qu and Yan-Biao Kang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01138E

A general and efficient Mn-catalyzed acceptorless dehydrogenative coupling of alcohols with hydroxides into carboxylates
Zhihui Shao, Yujie Wang, Yaqian Liu, Qian Wang, Xiaoling Fu and Qiang Liu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C8QO00023A

Syntheses and structures of [7]helicene and double helicene based on dithieno[2,3-b:2′,3′-d]thiophene
Xinming Liu, Huiliang Sun, Wan Xu, Shisheng Wan, Jianwu Shi, Chunli Li and Hua Wang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01049D

Isolation, structural elucidation, and synthetic study of salviyunnanone A, an abietane derived diterpenoid with a 7/5/6/3 ring system from Salvia yunnanensis
Fan Xia, Da-Wei Zhang, Chun-Yan Wu, Hui-Chun Geng, Wen-Dan Xu, Yu Zhang, Xing-Wei Yang, Hong-Bo Qin and Gang Xu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01140G

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Hot Articles in January 2018

Organic Chemistry Frontiers is delighted to share with you the HOT articles of January 2018!

You can access these publications for free till 31st Mar 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Radical rearrangement of N-sulfonyl-N-aryl propynamides: proceeding with homolytic N–SO2 bond cleavage and 6-endo-dig cyclization toward 3-sulfonyl-2(1H)-quinolinones
Bingbing Wang, Shengnan Jin, Song Sun and Jiang Cheng
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01048F

Copper-catalyzed three-component phosphorylation–peroxidation of alkenes
Yan Chen, Yuanjin Chen, Shenglin Lu and Zhiping Li
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01045A

Rhodium(III)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation
Guangfan Zheng, Miaomiao Tian, Youwei Xu, Xiaohong Chen and Xingwei Li
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01033H

ortho-Amino group functionalized 2,2′-bipyridine based Ru(II) complex catalysed alkylation of secondary alcohols, nitriles and amines using alcohols
Bivas Chandra Roy, Subhankar Debnath, Kaushik Chakrabarti, Bhaskar Paul, Milan Maji and Sabuj Kundu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01061C

Racemic trinorsesquiterpenoids from the Beihai sponge Spongia officinalis: structure and biomimetic total synthesis
Dong-Yu Sun, Guan-Ying Han, Na-Na Yang, Le-Fu Lan, Xu-Wen Li and Yue-Wei Guo
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01091E

Iron/zinc-catalyzed benzannulation reactions of 2-(2-oxo-alkyl)benzketones leading to naphthalene and isoquinoline derivatives
Changyuan Zhang, Lianfen Chen, Kai Chen, Huanfeng Jiang and Shifa Zhu
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01152K

N-Heterocyclic carbene promoted enantioselective desymmetrization reaction of diarylalkane-bisphenols
Shoulei Li, Bin Liu, Li Chen, Xin Li and Jin-Pei Cheng
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01083D

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Hot Articles in December 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of December 2017!

You can access these publications for free till 28th February 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Visible-light-induced tandem phosphorylation cyclization of vinyl azides under mild conditions
Yonghong Li, Yuanyuan Zhu and Shang-Dong Yang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO01004D

The hexameric resorcinarene capsule as an artificial enzyme: ruling the regio and stereochemistry of a 1,3-dipolar cycloaddition between nitrones and unsaturated aldehydes
Pellegrino La Manna, Margherita De Rosa, Carmen Talotta, Carmine Gaeta, Annunziata Soriente, Giuseppe Floresta, Antonio Rescifina and Placido Neri
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00942A

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Hot Articles in November 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of November 2017!

You can access these publications for free till 31st January 2018 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

An effective approach to aryl-substituted propanoic acids via the Pd-catalyzed hydrocarboxylation of stilbenes
Jie Dai, Wenlong Ren, Jingfu Li and Yian Shi
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00726D

Nickel-catalyzed direct difluoromethylation of aryl boronic acids with BrCF2H
Jie Sheng, Hui-Qi Ni, Kang-Jie Bian, Yan Li, Yi-Ning Wang and Xi-Sheng Wang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00934H

Enantioselective palladium-catalyzed C–H functionalization of pyrroles using an axially chiral 2,2′-bipyridine ligand
Hong-Qiang Shen, Cong Liu, Ji Zhou and Yong-Gui Zhou
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00815E

Thiazolium salt-catalyzed [3 + 2 + 1] cyclization for the synthesis of trisubstituted 2-pyrones using arylglyoxals as a carbonyl source
Li-Chen Xu, Peng Zhou, Jia-Zhuo Li, Wen-Juan Hao, Shu-Jiang Tu and Bo Jiang
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00899F

Synthesis of pyridine trans-tetrafluoro-λ6-sulfane derivatives via radical addition
Prajwalita Das, Masahiro Takada, Etsuko Tokunaga, Norimichi Saito and Norio Shibata
Org. Chem. Front., 2018, Advance Article
http://dx.doi.org/10.1039/C7QO00994A

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Hot Articles in September 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of September 2017!

You can access these publications for free till 30th November 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Asymmetric SN2′-type C–H functionalization of arenes with propargylic alcohols
Shangze Wu, Xin Huang, Chunling Fu and Shengming Ma
Org. Chem. Front., 2017,4, 2002-2007
http://dx.doi.org/10.1039/C7QO00588A

Comparative investigation of the reactivities between catalysts [Cp*RhCl2]2 and [Cp*IrCl2]2 in the oxidative annulation of isoquinolones with alkynes: a combined experimental and computational study
Chaoyue Zhao, Qingmei Ge, Baiquan Wang and Xiufang Xu
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00586E

Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions
Benjamin Laroche and Bastien Nay
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00633K

Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
Yao-Liang Sun, Yin Wei and Min Shi
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00512A

A redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[5]arene-based host–guest recognition
Yujuan Zhou, Kecheng Jie and Feihe Huang
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00736A

Rearranged limonoids with unique 6/5/6/5 tetracarbocyclic skeletons from Toona ciliata and biomimetic structure divergence
Jun Luo, Wan-Sha Huang, Sheng-Mou Hu, Pan-Pan Zhang, Xu-Wei Zhou, Xiao-Bing Wang, Ming-Hua Yang, Jian-Guang Luo, Chen Wang, Chang Liu, He-Quan Yao, Can Zhang, Hong-Bin Sun, Yi-Jun Chen and Ling-Yi Kong
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00678K

Gold-catalyzed diversified synthesis of 3-aminosugar analogues of digitoxin and digoxin
Jing Zeng, Guangfei Sun, Ruobin Wang, Shuxin Zhang, Shuang Teng, Zhiwen Liao, Lingkui Meng and Qian Wan
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00648A

Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes
Hongjie Gao, Jianhong Su, Pengfei Xu and Xin Xu
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00718C

A copper(I)-catalyzed asymmetric Mannich reaction of glycine Schiff bases with isatin-derived ketimines: enantioselective synthesis of 3-substituted 3-aminooxindoles
Jing-Yan Zhu, Wu-Lin Yang, Yang-Zi Liu, Shao-Jing Shang and Wei-Ping Deng
Org. Chem. Front., 2017, Advance Article
http://dx.doi.org/10.1039/C7QO00691H

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Hot Articles in August 2017

Organic Chemistry Frontiers is delighted to share with you the HOT articles of August 2017!

You can access these publications for free till 31st October 2017 by logging into your free Royal Society of Chemistry publishing personal account (http://pubs.rsc.org).

Photoredox meets gold Lewis acid catalysis in the alkylative semipinacol rearrangement: a photocatalyst with a dark side
M. Zidan, T. McCallum, L. Thai-Savard and L. Barriault
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00590C, Research Article


Palladium catalyzed C(sp3)–H acetoxylation of aliphatic primary amines to γ-amino alcohol derivatives
Kang Chen, Ding Wang, Zhao-Wei Li, Zheng Liu, Fei Pan, Yun-Fei Zhang and Zhang-Jie Shi
Org. Chem. Front., 2017, Advance Article
DOI: 10.1039/C7QO00432J, Research Article

Garciyunnanimines A–C, novel cytotoxic polycyclic polyprenylated acylphloroglucinol imines from Garcinia yunnanensis
Dan Zheng, Hong Zhang, Chang-Wu Zheng, Yuan-Zhi Lao, Dan-Qing Xu, Lian-Bo Xiao and Hong-Xi Xu
Org. Chem. Front., 2017, Advance Article
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